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Assembly of a Two-Fold Interpenetrated Three-Dimensional Metal–Organic Framework by Using the Template Function of Keggin Anions

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Abstract

A metal–organic framework [Co2(btp)3(GeMo12O40)] (1) (btp = 1,3-bis-(1,2,4-triazol-1-yl)propane) has been constructed by using the template function of the Keggin anions GeMo12O404−. Single-crystal X-ray analysis reveals that the structure exhibits two-fold interpenetrated 3D host metal–organic framework constructed from cobalt(II) and btp linkers and the voids of which are occupied by Keggin anions. The optical band gap of 1 indicates that it is potential wide-gap semiconductive material. The photocatalytic activity of compound 1 in degradation of MB under visible light and UV light irradiation are also investigated.

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Acknowledgements

This work was supported by the Science and technology development plan of Jilin province (20150520006JH), Science and technology research project of Education Department of Jilin province (2016219), Natural Science Foundation of China (21501065, 21676115, 21607051, 51404108) and Science and technology development plan of Siping city (2013055).

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Authors and Affiliations

  1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun, 130103, People’s Republic of China

    Shi Zhou, Bo Liu, Yan-Hong Xu & Xiu-Yan Wang

  2. Department of Chemistry, Jilin Normal University, Siping, 136000, People’s Republic of China

    Shi Zhou, Bo Liu, Yan-Hong Xu & Xiu-Yan Wang

  3. Key Laboratory of Polyoxometalates Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Ya-Guang Chen

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  1. Shi Zhou
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  2. Ya-Guang Chen
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  3. Bo Liu
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  4. Yan-Hong Xu
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Correspondence to Ya-Guang Chen.

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Zhou, S., Chen, YG., Liu, B. et al. Assembly of a Two-Fold Interpenetrated Three-Dimensional Metal–Organic Framework by Using the Template Function of Keggin Anions. J Clust Sci 29, 417–423 (2018). https://doi.org/10.1007/s10876-018-1347-9

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  • DOI: https://doi.org/10.1007/s10876-018-1347-9

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