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Journal of Cluster Science

, Volume 29, Issue 2, pp 313–317 | Cite as

Synthesis, Crystal Structure, and Properties of a 2D Cu(I) Coordination Polymer Based on Cu3I3 Chains Linked by 1,3-Di-(1,2,4-Triazole-4-yl)Benzene

  • Shao-Bin Miao
  • Chun-Ying Xu
  • Dong-Sheng Deng
  • Bao-Ming Ji
Original Paper

Abstract

A new copper(I) iodide coordination polymer, [(CuI)3(dtb)] n (1) (dtb = 1,3-di-(1,2,4-triazole-4-yl)benzene) has been synthesized solvothermally and structurally characterized by single crystal and powder X-ray diffractions, elemental analysis, IR, and thermogravimetric analysis. Overall, 1 exhibits a 2D hybrid structure containing dtb as structure-directing agents (SDAs) and 1D Cu3I3 chain as inorganic moiety. The copper-iodide chain can be regarded as two Cu2I2 rhomboids are connected by CuI fragments via Cu–I bonds. Dtb act as bridging ligands regularly link the Cu3I3 chains along both sides through Cu–N bonds to give the final 2D network. Moreover, solid state luminescent property of 1 has been investigated at room temperature.

Keywords

Coordination polymer Copper iodide Crystal structure Luminescence 

Notes

Acknowledgements

We are grateful to the Natural Science Foundation of China (Grant No. 21372112) for financial support.

Supplementary material

10876_2018_1333_MOESM1_ESM.pdf (54 kb)
CCDC 1583584 contains the supplementary crystallographic data for 1. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data_request/cif. (PDF 54 kb)
10876_2018_1333_MOESM2_ESM.pdf (32 kb)
Supplementary material 2 (PDF 32 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Shao-Bin Miao
    • 1
  • Chun-Ying Xu
    • 1
  • Dong-Sheng Deng
    • 1
  • Bao-Ming Ji
    • 1
  1. 1.College of Chemistry and Chemical EngineeringLuoyang Normal UniversityLuoyangPeople’s Republic of China

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