Skip to main content
SpringerLink
Log in

Synthesis, Crystal Structure, and Properties of a 2D Cu(I) Coordination Polymer Based on Cu3I3 Chains Linked by 1,3-Di-(1,2,4-Triazole-4-yl)Benzene

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A new copper(I) iodide coordination polymer, [(CuI)3(dtb)] n (1) (dtb = 1,3-di-(1,2,4-triazole-4-yl)benzene) has been synthesized solvothermally and structurally characterized by single crystal and powder X-ray diffractions, elemental analysis, IR, and thermogravimetric analysis. Overall, 1 exhibits a 2D hybrid structure containing dtb as structure-directing agents (SDAs) and 1D Cu3I3 chain as inorganic moiety. The copper-iodide chain can be regarded as two Cu2I2 rhomboids are connected by CuI fragments via Cu–I bonds. Dtb act as bridging ligands regularly link the Cu3I3 chains along both sides through Cu–N bonds to give the final 2D network. Moreover, solid state luminescent property of 1 has been investigated at room temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. M. D. Allendorf, C. A. Bauer, R. K. Bhakta, and R. J. T. Houk (2009). Chem. Soc. Rev. 38, 1330.

    Article  CAS  Google Scholar 

  2. M. Kurmoo (2009). Chem. Soc. Rev. 38, 1353.

    Article  CAS  Google Scholar 

  3. J. R. Li, R. J. Kuppler, and H. C. Zhou (2009). Chem. Soc. Rev. 38, 1477.

    Article  CAS  Google Scholar 

  4. M. E. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keeffe, and O. M. Yaghi (2002). Science 295, 469.

    Article  CAS  Google Scholar 

  5. S. Kitagawa, R. Kitaura, and S. Noro (2004). Angew. Chem. Int. Ed. 43, 2334.

    Article  CAS  Google Scholar 

  6. J. J. Perry IV, J. A. Perman, and M. J. Zaworotko (2009). Chem. Soc. Rev. 38, 1400.

    Article  CAS  Google Scholar 

  7. J. P. Zhang, Y. Y. Lin, X. C. Huang, and X. M. Chen (2005). J. Am. Chem. Soc. 127, 5495.

    Article  CAS  Google Scholar 

  8. Y. H. Liu, J. F. Zhang, L. P. Gong, and C. Zhang (2016). J. Clust. Sci. 27, 1353.

    Article  CAS  Google Scholar 

  9. M. A. Tershansy, A. M. Goforth, L. Peterson Jr., M. C. Burns, M. D. Smith, and H. C. zur Loye (2009). Solid State. Sci. 9, 895.

    Article  Google Scholar 

  10. J. He, Y. G. Yin, T. Wu, D. Li, and X. C. Huang (2006). Chem. Commun. 27, 2845.

    Article  Google Scholar 

  11. S. Hu, F. Y. Yu, Y. Yan, Z. F. Hao, L. Yu, and M. L. Tong (2011). Inorg. Chem. Commun. 14, 622.

    Article  CAS  Google Scholar 

  12. H. H. Li, Z. R. Chen, Y. Liu, K. N. Ding, J. Q. Li, C. C. Huang, and L. Q. Guo (2007). J. Cluster. Sci. 18, 817.

    Article  CAS  Google Scholar 

  13. T. Wu, M. Li, D. Li, and X. C. Huang (2008). Cryst. Growth. Des. 8, 568.

    Article  CAS  Google Scholar 

  14. M. H. Bi, G. H. Li, J. Hua, Y. L. Liu, X. M. Liu, Y. W. Hu, Z. Shi, and S. H. Feng (2007). Cryst. Growth. Des. 7, 2066.

    Article  CAS  Google Scholar 

  15. L. Maini, D. Braga, P. P. Mazzeo, L. Maschio, M. Rérat, I. Manet, and B. Ventura (2015). Dalton. Trans. 44, 13003.

    Article  CAS  Google Scholar 

  16. J. Conesa-Egea, J. Gallardo-Martínez, S. Delgado, J. I. Martínez, J. Gonzalez-Platas, V. Fernández-Moreira, U. R. Rodríguez-Mendoza, P. Ocón, F. Zamora, and P. Amo-Ochoa (2017). Small 13, 1700965.

    Article  Google Scholar 

  17. X. C. Shan, F. L. Jiang, D. Q. Yuan, H. B. Zhang, M. Y. Wu, L. Chen, J. Wei, S. Q. Zhang, J. Pan, and M. C. Hong (2013). Chem. Sci. 4, 1484.

    Article  CAS  Google Scholar 

  18. M. S. Deshmukh, A. Yadav, R. Pant, and R. Boomishankar (2015). Inorg. Chem. 54, 1337.

    Article  CAS  Google Scholar 

  19. M. A. Tershansy, A. M. Goforth, J. M. Ellsworth, M. D. Smith, and H. C. zur Loye (2008). CrystEngComm 10, 833.

    Article  CAS  Google Scholar 

  20. H. Park, E. Kwon, H. Chiang, H. Im, K. Y. Lee, J. Kim, and T. H. Kim (2017). Inorg. Chem. 56, 8287.

    Article  CAS  Google Scholar 

  21. A. Bonnot, C. Strohmann, M. Knorr, and P. D. Harvey (2014). J. Clust. Sci. 25, 261.

    Article  CAS  Google Scholar 

  22. L. Li, H. Y. Li, Z. G. Ren, and J. P. Lang (2014). Eur. J. Inorg. Chem. 5, 824.

    Article  Google Scholar 

  23. S. L. Li, J. Wang, F. Q. Zhang, and X. M. Zhang (2017). Cryst. Grwoth Des. 17, 746.

    Article  CAS  Google Scholar 

  24. F. De Angelis, S. Fantacci, A. Sgamellotti, E. Cariati, R. Ugo, and P. C. Ford (2006). Inorg. Chem. 45, 10576.

    Article  Google Scholar 

  25. F. S. Wu, H. B. Tong, Z. Y. Li, W. Lei, L. Liu, W. Y. Wong, W. K. Wong, and X. J. Zhu (2014). Dalton. Trans. 43, 12463.

    Article  CAS  Google Scholar 

  26. D. Braga, F. Grepioni, L. Maini, P. P. Mazzeo, and B. Ventura (2011). New. J. Chem. 35, 339.

    Article  CAS  Google Scholar 

  27. J. A. Tompkins, J. L. Maxwell, and E. M. Holt (1987). Inorg. Chim. Acta. 127, 1.

    Article  CAS  Google Scholar 

  28. D. Sun, S. Yuan, H. Wang, H. F. Lu, S. Y. Feng, and D. F. Sun (2013). Chem. Commun. 49, 6152.

    Article  CAS  Google Scholar 

  29. H. Araki, K. Tsuge, Y. Sasaki, S. Ishizaka, and N. Kitamura (2005). Inorg. Chem. 44, 9667.

    Article  CAS  Google Scholar 

  30. W. V. Taylor, U. H. Soto, V. M. Lynch, and M. J. Rose (2016). Inorg. Chem. 55, 3206.

    Article  CAS  Google Scholar 

  31. S. B. Miao, Z. H. Li, B. M. Ji, D. S. Deng, C. Y. Xu, and L. Zhou (2014). J. Clust. Sci. 25, 1137.

    Article  CAS  Google Scholar 

  32. G. M. Sheldrick SHELXS-97 and SHELXL-97, Programs for Crystal Structure Refinement (University of Göttingen, Germany, 1997).

    Google Scholar 

  33. L. Yang, D. R. Powell, and R. P. Houser (2007). Dalton. Trans. 9, 955.

    Article  Google Scholar 

  34. T. Li and S. W. Du (2008). J. Clust. Sci. 19, 323.

    Article  CAS  Google Scholar 

  35. S. Hu and M. L. Tong (2005). Dalton. Trans. 7, 1165.

    Article  Google Scholar 

Download references

Acknowledgements

We are grateful to the Natural Science Foundation of China (Grant No. 21372112) for financial support.

Author information

Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, People’s Republic of China

    Shao-Bin Miao, Chun-Ying Xu, Dong-Sheng Deng & Bao-Ming Ji

Authors
  1. Shao-Bin Miao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chun-Ying Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dong-Sheng Deng
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Bao-Ming Ji
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Bao-Ming Ji.

Electronic supplementary material

Below is the link to the electronic supplementary material.

10876_2018_1333_MOESM1_ESM.pdf

CCDC 1583584 contains the supplementary crystallographic data for 1. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data_request/cif. (PDF 54 kb)

Supplementary material 2 (PDF 32 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Miao, SB., Xu, CY., Deng, DS. et al. Synthesis, Crystal Structure, and Properties of a 2D Cu(I) Coordination Polymer Based on Cu3I3 Chains Linked by 1,3-Di-(1,2,4-Triazole-4-yl)Benzene. J Clust Sci 29, 313–317 (2018). https://doi.org/10.1007/s10876-018-1333-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-018-1333-2

Keywords

Search

Navigation