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Journal of Cluster Science

, Volume 26, Issue 5, pp 1811–1820 | Cite as

New Member of Organic Ligand Functionalized TMSP: Synthesis, Characterized and Properties of Na15[(MnII(COOH))3(AsW9O33)2]·15H2O

  • Qiong Wu
  • Hongping Ju
  • Jian Tao
  • Zihao Chen
  • Jun Li
  • Fuyan Wang
  • Qian Cai
  • Lifen Sun
  • Xinghua Pan
Original Paper

Abstract

Reaction of [Mn12(CH3COO)16(H2O)4O12]·2CH3COOH·4H2O and Na9[AsW9O33]·19.5H2O in aqueous solution leads to the isolation of a new carboxy group decorated TMSP, Na15[(MnII(COOH))3(AsW9O33)2]·15H2O (1). The structure of 1 was characterized by elemental analysis, thermometric analysis and single crystal X-ray diffraction (Crystal data for 1: Trigonal, P-3, a = 12.8804(4) Å, b = 12.8804(4) Å, c = 30.3501(19) Å, V = 4360.6(3) Å3, Z = 2). Structural analysis reveals that 1 represents the first example of carboxy group decorated arsenotungstate. Antitumor study indicates that compound 1 possesses high antitumor activity against Hela cells. In addition, the magnetic properties of 1 were also investigated.

Keywords

Polyoxometalate Arsenotungstate Organic ligand Antitumor activity Magnetic properties 

Notes

Acknowledgments

This work was supported by National Natural Science Foundation of China (21201090). Applied Basic Research Programs of Science and Technology Commission Foundation of Yunnan Province (2012FD045), Kunming university students funding innovative projects (No. S1109).

Supplementary material

10876_2015_880_MOESM1_ESM.doc (1.5 mb)
Supplementary material 1 (DOC 1576 kb)

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Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Qiong Wu
    • 1
    • 3
    • 4
  • Hongping Ju
    • 2
  • Jian Tao
    • 2
  • Zihao Chen
    • 5
  • Jun Li
    • 2
    • 3
  • Fuyan Wang
    • 1
  • Qian Cai
    • 1
  • Lifen Sun
    • 1
  • Xinghua Pan
    • 3
  1. 1.Department of Chemical Science and TechnologyKunming UniversityKunmingPeople’s Republic of China
  2. 2.Medical SchoolKunming UniversityKunmingPeople’s Republic of China
  3. 3.Stem Cell, Tissue and Organ Engineering Research CenterKunming General, Hospital of Chinese People’s Liberation ArmyKunmingPeople’s Republic of China
  4. 4.Center for Disease Control and PreventionKunmingPeople’s Republic of China
  5. 5.Hebei Medical UniversityShijiazhuangPeople’s Republic of China

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