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Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation

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Abstract

A novel polyoxometalate-based compound, [H(atrz)]4[(atrz)2(Mo8O26)]·2H2O (1) (atrz = 3-amino-1,2,4-triazole), has been synthesized by traditional hydrothermal method, and characterized by means of elemental analysis, FT-IR spectroscopy, Powder X-ray diffraction and single-crystal X-ray. The compound 1 contains a 2D supramolecualr layer which is constructed from [(atrz)2(γ-Mo8O26)]4− units via intermolecular hydrogen-bonding interactions. Furthermore, the adjacent 2D layers are packed together through the aromatic π⋯π stacking interactions and exhibits a 3D supramolecular structure. The catalytic properties of 1 were investigated in olefin epoxidation with tert-butylhydroperoxide (t-BuOOH) as the oxidant. It was found that compound 1 could serve as active and stable heterogeneous catalyst for the epoxidation of cyclooctene and 1-octence. Besides, introducing copper ions into compound 1 could further improve the catalytic activity for olefin epoxidation.

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Acknowledgments

Financial support from the National Natural Science Foundation of China (No. 21173100) is gratefully acknowledged.

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Authors and Affiliations

  1. State Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry, Jilin University, Changchun, 130021, China

    Hongcheng Gao, Jiehui Yu, Huiling Niu, Jing Wang, Xiaojing Song, Wenxiang Zhang & Mingjun Jia

  2. College of Chemistry, Jilin Normal University, Siping, 136000, China

    Juan Du

Authors
  1. Hongcheng Gao
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  2. Jiehui Yu
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  3. Juan Du
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  4. Huiling Niu
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  5. Jing Wang
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  6. Xiaojing Song
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  7. Wenxiang Zhang
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  8. Mingjun Jia
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Correspondence to Mingjun Jia.

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Gao, H., Yu, J., Du, J. et al. Supramolecular Assembly Based on Octamolybdate and Triazole Derivative: Crystal Structure and Catalytic Application in Olefin Epoxidation. J Clust Sci 25, 1263–1272 (2014). https://doi.org/10.1007/s10876-014-0704-6

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  • DOI: https://doi.org/10.1007/s10876-014-0704-6

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