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Crystal Structure and Magnetic Property of a 2-D Hexa-Circular Ring Cu(II)/Na(I)-Substituted Sandwich-Type Arsenotungstate

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Abstract

A new compound H8[NaCu5Cl(H2O)3(B-α-AsW9O33)2] 24H2O (1) is synthetized by the reaction of the CuCl2 2H2O and Na27[NaAs4W40O140] 60H2O in aqueous solution, which is constructed from a {Cu5Na} hexagon moiety sandwiched by two trilacunary [B-α-AsW9O33]9− units. The structure is determined by single-crystal X-ray diffraction technique and further characterized by IR spectroscopy. Single-crystal X-ray diffraction analysis reveals that 1 is built by two trilacunary [B-α-AsW9O33]9− units incorporating a {Cu5Na} hexagon moiety and further linked to each other to form an infinitely extended 2-D network via Cu–O–W bridges. Notably, magnetic measurement demonstrates that the occurrence of intramolecular ferromagnetic Cu–Cu interactions within {Cu5Na} hexagon moiety.

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Acknowledgments

This work was financially supported by the Natural Science Foundation of China, Special Research Fund for the Doctoral Program of Higher Education, Innovation Scientists and Technicians Troop Construction Projects of Henan Province, the Foundation of Education Department of Henan Province and Natural Science Foundation of Henan Province.

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Authors and Affiliations

  1. Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, People’s Republic of China

    Jiai Hua, Xiang Ma, Pengtao Ma, Jingping Wang & Jingyang Niu

Authors
  1. Jiai Hua
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  2. Xiang Ma
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  3. Pengtao Ma
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  4. Jingping Wang
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  5. Jingyang Niu
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Corresponding authors

Correspondence to Jingping Wang or Jingyang Niu.

Additional information

Jiai Hua and Xiang Ma contributed equally to this study.

Appendices

Appendices

CSD 423754 contains the supplementary crystallographic data for compound 1. Further details of the crystal structure investigation(s) may be obtained from Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666; e-mail: crysdata@fiz-karlsruhe.de, http://www.fiz-karlsruhe.de/request_for_deposited_data.html) on quoting the appropriate CSD number.

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Hua, J., Ma, X., Ma, P. et al. Crystal Structure and Magnetic Property of a 2-D Hexa-Circular Ring Cu(II)/Na(I)-Substituted Sandwich-Type Arsenotungstate. J Clust Sci 24, 689–700 (2013). https://doi.org/10.1007/s10876-012-0536-1

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  • DOI: https://doi.org/10.1007/s10876-012-0536-1

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