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Dirhenium Compounds Supported by N,N ′-Dimethylbenzamidinate: Formation of Linear Polymers via Axial Ligation

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Abstract

The reaction between Re2(DMBA)4Cl2 and NaN(CN)2 resulted in Re2(DMBA)4(N(CN)2)2 (1a), where DMBA is N,N′-dimethylbenzamidinate. Molecular compounds Re2(DMBA)4(ReO4)2 (1b) and Re2(DMBA)4(OP(O)(OH)Ph)2 (1c) were obtained through the reactions between Re2(DMBA)4(NO3)2 and the respective monoanion. The dirhenium(III) coordination polymers [Re2(DMBA)4(μ-O,O′-WO4)·2H2O]∞ (2a), [Re2(DMBA)4(μ-O,O′-MoO4)·2H2O]∞ (2b), and [Re2(DMBA)4(μ-O,O′-1,4-(O2C)2C6H4)·2H2O]∞ (2c) were similarly prepared through slow diffusion of Re2(DMBA)4(NO3)2 in acetonitrile into aqueous solution containing the respective dianion. All new compounds were characterized with single crystal X-ray diffraction, which revealed the retention of the essential structural features of Re2(DMBA)4 unit upon the formation of coordination polymers.

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References

  1. S. R. Batten and R. Robson (1998). Angew. Chem. Int. Ed. 37, 1460.

    Article  Google Scholar 

  2. S. Kitagawa, R. Kitaura, and S.-i. Noro (2004). Angew. Chem. Int. Ed. 43, 2334.

    Article  CAS  Google Scholar 

  3. S. Q. Ma and H. C. Zhou (2010). Chem. Commun. 46, 44.

    Article  CAS  Google Scholar 

  4. S. Horike, S. Shimomura, and S. Kitagawa (2009). Nat. Chem. 1, 695.

    Article  CAS  Google Scholar 

  5. F. A. Cotton, C. A. Murillo, R. A. Walton (Eds.) (2005) Multiple bonds between metal atoms, 3 edn. Springer Science and Business Media, Inc.: New York.

  6. F. A. Cotton, C. Lin, and C. A. Murillo (2001). Acc. Chem. Res. 34, 759.

    Article  CAS  Google Scholar 

  7. F. A. Cotton, C. Lin, and C. A. Murillo (2002). Proc. Natl. Acad. Sci. USA 99, 4810.

    Article  CAS  Google Scholar 

  8. R. H. Cayton, M. H. Chisholm, J. C. Huffman, and E. B. Lobkovsky (1991). J. Am. Chem. Soc. 113, 8709.

    Article  CAS  Google Scholar 

  9. R. H. Cayton, M. H. Chisholm, J. C. Huffman, and E. B. Lobkovsky (1991). Angew. Chem. Int. Ed. 30, 862.

    Article  Google Scholar 

  10. M.-C. Suen, G.-W. Tseng, J.-D. Chen, T.-C. Keng T-C, and J.-C. Wang (1999). Chem. Commun. 1185.

  11. M. H. Chisholm (2003). Dalton Trans. 3821.

  12. S.-M. Kuang, P. E. Fanwick, and R. A. Walton (2000). Inorg. Chem. 39, 2968.

    Article  CAS  Google Scholar 

  13. M. C. Barral, T. Gallo, S. Herrero, R. Jiménez-Aparicio, M. R. Torres, and F. A. Urbanos (2006). Inorg. Chem. 45, 3639.

    Article  CAS  Google Scholar 

  14. W.-Z. Chen, and T. Ren (2006). Inorg. Chem. 45, 9175.

  15. T. Ren (2008). Chem. Rev. 108, 4185.

    Article  CAS  Google Scholar 

  16. A. Petitjean, F. Puntoriero, S. Campagna, A. Juris, and J.-M. Lehn (2006). Eur. J. Inorg. Chem. 3878.

  17. M. A. Petrukhina, and L. T. Scott (2005). Dalton Trans. 2969.

  18. T. Ren (2005). Organometallics 24, 4854.

    Article  CAS  Google Scholar 

  19. J.-W. Ying, D. R. Sobransingh, G.-L. Xu, A. E. Kaifer, and T. Ren (2005). Chem. Commun. 357.

  20. J.-W. Ying, A. Cordova, T. Y. Ren, G.-L. Xu, and T. Ren (2007). Chem. Eur. J. 13, 6874.

    Article  CAS  Google Scholar 

  21. C.-F. Wang, J. L. Zuo, J.-W. Ying, T. Ren, and X.-Z. You (2008). Inorg. Chem. 47, 9716.

    Article  CAS  Google Scholar 

  22. J.-W. Ying, I. P.-C. Liu, B. Xi, Y. Song, C. Campana, J.-L. Zuo, and T. Ren (2010). Angew. Chem. Int. Ed. 49, 954.

    CAS  Google Scholar 

  23. M. Q. Dequeant, R. McGuire Jr, D. R. McMillin, and T. Ren (2005). Inorg. Chem. 44, 6521.

    Article  CAS  Google Scholar 

  24. W.-Z. Chen and T. Ren (2003). Inorg. Chem. 42, 8847.

    Article  CAS  Google Scholar 

  25. M. Q. Dequeant, P. M. Bradley, G. Xu, D. L. Lutterman, C. Turro, and T. Ren (2004). Inorg. Chem. 43, 7887.

    Article  CAS  Google Scholar 

  26. SAINT (1999). Bruker-AXS, Inc.

  27. SHELXTL (1998). Bruker-AXS Inc.

  28. G. M. Sheldrick (1990). SHELXS-90.

  29. G. M. Sheldrick (1993). SHELXL-93.

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Acknowledgment

This work was supported in part by the National Science Foundation (Grant No. CHE 0715404) and Purdue University.

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  1. Department of Chemistry, Purdue University, West Lafayette, IN, 47907, USA

    Michael Q. Dequeant & Tong Ren

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  1. Michael Q. Dequeant
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  2. Tong Ren
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Correspondence to Tong Ren.

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Dedicated to Professor Malcolm Chisholm, a good friend, teacher, and the maestro of cluster science, on the occasion of his 65th birthday.

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Dequeant, M.Q., Ren, T. Dirhenium Compounds Supported by N,N ′-Dimethylbenzamidinate: Formation of Linear Polymers via Axial Ligation. J Clust Sci 21, 291–300 (2010). https://doi.org/10.1007/s10876-010-0284-z

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  • DOI: https://doi.org/10.1007/s10876-010-0284-z

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