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Zn(II) and Cu(II) Complexes with the Cluster-based Ligand [Re6(μ 3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7-phosphaadamantane)

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Abstract

Zn(II) and Cu(II) complexes of the cluster-based ligand [Re6(μ 3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-triaza-7-phosphaadamantane), {Zn[Re6(μ 3-Se)8(PEt3)5(PTA)](NO3)3}(SbF6) (1) and {Cu[Re6(μ 3-Se)8(PEt3)5(PTA)](NO3)3}(SbF6) (2), were prepared and structurally characterized. They are the first N-coordinated Zn(II) and Cu(II) complexes wherein the PTA ligand displays an interesting and less-frequently observed P, N-coordination mode.

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Acknowledgements

This research was supported in part by the National Science Foundation (CHE-0750530). The X-ray diffractometer was purchased through an NSF grant (CHE-96103474). We thank Xiangjian Kong, Xia’men University, for crystallographic data collection of 2.

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  1. Department of Chemistry, The University of Arizona, Tucson, AZ, 85721, USA

    Xiaoyan Tu, Gary S. Nichol & Zhiping Zheng

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Tu, X., Nichol, G.S. & Zheng, Z. Zn(II) and Cu(II) Complexes with the Cluster-based Ligand [Re6(μ 3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7-phosphaadamantane). J Clust Sci 20, 93–103 (2009). https://doi.org/10.1007/s10876-008-0206-5

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