Skip to main content
SpringerLink
Log in

The Coordination Behaviour of the Peroxodisulfate Anion with Group XII Metal Ions: [Zn(H2O)(C12H8N2)2(S2O8)]·H2O and Related Compounds

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The title compound is monomeric with a Zn(II) hexacoordinated center. The coordination sphere is formed by four nitrogens from two phenanthroline molecules, one oxygen from a monodentate peroxodisulfate ion, and one oxygen from a water molecule. A non-coordinated water molecule completes the formula with an important role in the stabilization of the structure through the formation of two OHW–H···Opds bridges (acting as a donor) and one OCW–H···OHW bridge where it is an acceptor group (HW: hydration water; pds: peroxodisulfato; CW: coordinated water). The compound is triclinic, space group P-1 with a = 8.763 (3) Å, b = 9.068 (3) Å, c = 17.531 (6) Å, α = 96.48 (2)°, β = 103.94 (3)°, γ = 104.57 (3)°, V = 1286.0 (7) Å3 and Z = 2. The structure was solved by direct methods with a conventional R (on F) = 0.050 for 4534 reflections with Fo > 4σ(Fo). The compound is isomorphous with the Cd analogue (in Harvey et al. Aust J Chem 54:307, 2001). An eventual dependence of conformation and coordination mode of the peroxodisulfate anion on the ancillary organic ligand taking part in the coordination compounds analyzed is discussed.

Graphical Abstract

The crystal structure of [Zn(H2O)(C12H8N2)2(S2O8)]·H2O is reported. In addition, similarities in conformation and coordination mode of the peroxodisulfato anion in hybrid (organic–inorganic) complexes of group XII metal ions containing similar organic ligands are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Harvey MA, Baggio S, Garland MT, Burton G, Baggio R (2001) Aust J Chem 54:307

    Article  CAS  Google Scholar 

  2. Harvey MA, Baggio S, Garland MT, Baggio R (2001) Austr J Chem 54:711

    Article  CAS  Google Scholar 

  3. Harvey MA, Baggio S, Ibánez A, Baggio R (2004) Acta Cryst C 60:m375

    Article  Google Scholar 

  4. Díaz de Vivar ME, Harvey MA, Garland MT, Baggio S, Baggio R (2005) Acta Cryst C 61:m240

    Article  Google Scholar 

  5. Harvey MA, Baggio S, Garland MT, Baggio R (2008) Acta Cryst C 64:o489

    Article  Google Scholar 

  6. Allen FH (2002) Acta Cryst B 58:380

    Article  Google Scholar 

  7. Sheldrick GM (2008) Acta Cryst A 64:112

    Article  Google Scholar 

  8. Macrae CF, Edgington PR, McCabe P, Pidcock E, Shields GP, Taylor R, Towler M (2006) J Appl Cryst 39:453

    Article  CAS  Google Scholar 

  9. Brown ID (1994) Bond-length–bond-valence relationships in inorganic solids. In: Bürgi H-B, Dunitz JD (eds) Structure correlation, vol 2. VCH, Weinheim, pp 405–429

    Chapter  Google Scholar 

  10. Harvey MA, Baggio S, Baggio R (2006) Acta Cryst B 62:1038

    Article  Google Scholar 

  11. Yu Naumov D, Virovets AV, Podberezskaya NV, Novikov PB, Politov AA (1997) Zh Strukt Khim 38:922

    Google Scholar 

  12. Sivertsen BK, Sorum H (1969) Z Kristallogr Kristallgeom Kristallphys Kristallchem 130:449

    CAS  Google Scholar 

  13. Janiak C (2000) J Chem Soc Dalton Trans. 3885

Download references

Acknowledgements

We would like to thank the Spanish Research Council (CSIC) for providing us with a free-of charge license to the CSD system.

Author information

Authors and Affiliations

  1. Universidad Nacional de la Patagonia S.J.B. and Centro Nacional Patagónico, CONICET., Bvd. Alte. Brown 3700, 9120, Puerto Madryn, Chubut, Argentina

    Miguel A. Harvey, María E. Díaz de Vivar & Sergio Baggio

  2. Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina

    Ricardo Baggio

Authors
  1. Miguel A. Harvey
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. María E. Díaz de Vivar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ricardo Baggio
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Sergio Baggio
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Miguel A. Harvey.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Harvey, M.A., Díaz de Vivar, M.E., Baggio, R. et al. The Coordination Behaviour of the Peroxodisulfate Anion with Group XII Metal Ions: [Zn(H2O)(C12H8N2)2(S2O8)]·H2O and Related Compounds. J Chem Crystallogr 41, 1717–1721 (2011). https://doi.org/10.1007/s10870-011-0163-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-011-0163-y

Keywords

Search

Navigation