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Reaction of 3-nitro-1,2,4-triazoles with alkylating agents. 7*. N-monoalkylation by monocyclic α-oxide polymers

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Chemistry of Heterocyclic Compounds Aims and scope

The N-monoalkylation of 3-nitro, 5-methyl-3-nitro, and 5-ethyl-3-nitro-1,2,4-triazoles by epichlorohydrin polymers and copolymers is nonselective in the presence of base. The reaction products are nitrotriazoles substituted by the polymeric chain in positions 1 or 2 of the heterocycle. The mass fraction of the 2-isomer is 9.6-11.3%. The degree of substitution of the chlorine by the nitrotriazole ring is 98.0-99.5%.

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Authors and Affiliations

  1. Institute of Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, Biysk, 659322, Russia

    A. G. Sukhanova & G. T. Sukhanov

  2. Federal Research and Production Center “Altai”, Biysk, 659322, Russia

    G. V. Sakovich

Authors
  1. A. G. Sukhanova
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  2. G. V. Sakovich
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  3. G. T. Sukhanov
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Corresponding author

Correspondence to A. G. Sukhanova.

Additional information

For Communication 6, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 603-609, April, 2010.

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Sukhanova, A.G., Sakovich, G.V. & Sukhanov, G.T. Reaction of 3-nitro-1,2,4-triazoles with alkylating agents. 7*. N-monoalkylation by monocyclic α-oxide polymers. Chem Heterocycl Comp 46, 478–483 (2010). https://doi.org/10.1007/s10593-010-0534-x

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  • DOI: https://doi.org/10.1007/s10593-010-0534-x

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