Abstract
A theory of heat conduction in rigid heat conductors based entirely on mechanical concepts is proposed and compared with the traditional thermodynamic theories.
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Notes
Coleman and Noll [4].
Curiously enough, though energy balance is a general law of physics, its position in classical continuum mechanics has never been clear. For example, in the theory of elasticity this law is ignored or, rather, is used to characterize the subclass of the hyperelastic materials. This was done by Truesdell and Noll [47], in spite of their mentioning energy balance among the “axioms of continuum physics” (ibid., Sect. 1), and claiming the necessity of its introduction as “an additional physical principle ...if definite problems are to be solved” (ibid., Sect. 45).
For the recoverable part, the name free energy would be appropriate. Unfortunately, this term is generally used to denote the Helmholtz free energy, which is the recoverable part of the internal energy only in the special case of isothermal processes, see Remark 4.4 below. Therefore, denoting here by “free energy” the overall recoverable energy may generate confusion.
The dissipative part of the internal energy is specified by the dissipation function, and the dissipation potential is the time derivative of that function.
“... le comportement d’un milieu continu se trouve décrit essentiellement par deux fonctions à valeurs réelles ...un potentiel thermodynamique d’une part, une fonction des dissipations - ou plus généralement un quasi-potentiel des dissipations - d’autre part,” Germain [15], Introduction to Chapter VII. In his autobiographic paper [18], the same author says that what led him to this reformulation were Ziegler’s description of the different transpositions of Rayleigh’s dissipation function to viscoelasticity and to plasticity [49], Moreau’s enunciation of the lois de résistance and fonctions de résistance for friction, plasticity and viscosity [28], and Kestin’s “deep understanding of what may be an extension of thermostatics to thermodynamics” [25].
Halphen and Nguyen [22].
This deduction is by no means trivial. I was not able to find anywhere the assertion that the equation of virtual power is a consequence of energy conservation. On the contrary, that this equation has been proposed as the main axiom of continuum mechanics [16, 17] suggests that equation of virtual power and energy conservation are usually considered as independent concepts.
See, e.g., Truesdell [46], p. 154.
In fact, the assumption of differentiability of \(\chi \) is too restrictive, since it was clear from the beginning [28] that there are at least two types of dissipation potentials, one differentiable, and one with only directional derivatives. Examples of the two cases are viscosity and plasticity, respectively. In plasticity, \(\chi \) is not differentiable at the origin, and this leads to evolutions governed by an activation condition and by a flow rule, see, e.g., [9, 10]. In the viscous-like response assumed here the evolutions go on smoothly, without activation conditions and flow rules. Note that, while the potential \(\varphi \) is a function of state, the dissipation potential is not, because the integral in (5) is path-dependent.
Note that \(\delta \vartheta \) is a perturbation of \({\dot{\vartheta }}_t\) and not of \(\vartheta _t\). This is essential to establish the form of the virtual power associated with both a “viscous” and a “plastic” dissipation potential. For the latter, see the paper [9].
The cut principle excludes, for example, the presence of different surface effects at the physical boundary and at the interior surfaces. Note that while the contact actions s at the boundary of \(\Omega \) are accessible and, at least in principle, can be measured, the contact actions \(s_{\partial \Pi }\) at the interior points are inaccessible and therefore cannot be measured.
\(\mathscr {V}\) is the vector space associated with \(\mathscr {E}\).
This parallels the situation met in classical continuum mechanics, in which the mechanical contact action \(s_{\partial \Pi }(x)\) is a vector and the right-hand side of (11) becomes equal to \(T(x)\,n\), with T the stress tensor. In that context, the first equality in (11) was assumed by Cauchy and proved subsequently by Noll ([30], Theorem IV). The second equality is the thesis of Cauchy’s “tetrahedron theorem.” For more details, see [8], Sect. 4, and [10], Sect. 6.2.
Due to the minus sign in (11), the flux is positive when q points inward \(\Pi \).
This inequality states that the direction of the heat vector is opposite to the direction of the temperature gradient. It is preserved if, more in general, we take \(\chi \) independent of \(\nabla \dot{\vartheta }\) and \(\varphi (\vartheta ,\,\cdot \,)\) convex, nonnegative, and null at \(\nabla \vartheta =0\). Indeed, from the monotonicity of the gradient of a convex function, we have
$$\begin{aligned} \big (\varphi _{\,\nabla \vartheta }(\vartheta ,\nabla \vartheta ) -\varphi _{\,\nabla \vartheta }(\vartheta ,\nabla \vartheta _0)\big )\cdot \big (\nabla \vartheta -\nabla \vartheta _0\big )\ge 0, \end{aligned}$$and in particular for \(\nabla \vartheta _0=0\), we get \(\varphi _{\,\nabla \vartheta }(\vartheta ,\nabla \vartheta )\cdot \nabla \vartheta \ge 0\). On the other hand, \(\varphi _{\,\nabla \vartheta }(\vartheta ,\nabla \vartheta )\) is equal to \(-q\) by (13)\(_2\) with \(\chi \) independent of \(\nabla \dot{\vartheta }\), whence inequality (18) follows.
The terms involving \(k_0\) and \(c_0\) are necessary for reasons of physical plausibility. Indeed, for \(k_0=0\) the recoverable energy of a spatially uniform temperature field \(\nabla \vartheta =0\) would be zero at all temperatures. That is, the recoverable energy would be insensitive to uniform heating or cooling. Also, for \(c_0=0\) there would be no dissipation in a uniform change in temperature \(\nabla \dot{\vartheta }=0\).
Straughan [44], Equation (1.37).
The elimination of this term was not conveniently justified.
See Straughan’s book [44].
See Bargmann et al. [1], Sect. 6.
Truesdell [45], Lecture 1.
From comparison with (35) it is clear that, just like the internal energy, the entropy is determined to within an additive constant.
See, e.g., [21] or [41]. According to [41], Eq. (1.7), the entropy imbalance consists in assuming the existence of a lower bound D for the entropy rate \(\dot{H}\). This implies the non-negativeness of the entropy production\(\varDelta =\dot{H}-D\). Comparing with Eq. (38) above, in which \(\varDelta \) is called \(\Gamma \), we see that D corresponds to \(Q/\varTheta \). By Eq. (1.9) and assumption (1.14) of [41], \(D=Q/\varTheta \) takes the form (41). The same Eq. (41) can be deduced from [21], Eqs. (27.7) to (27.14). For the assumption (1.14) of [41] about the form of the volume density of D, see the next Section 3.3.
For the first equation, we recall that in a rigid conductor the mechanical working is zero.
The Gibbs relation is usually considered a constitutive assumption, see, e.g., (Truesdell and Toupin [48], eq. (247.5)). The deduction of the relations (45) from the Clausius–Duhem inequality is considered an example of application of the Coleman–Noll procedure [4] for the formulation of constitutive equations and dissipation inequalities compatible with the two basic axioms.
See [13], eq. (75).
Truesdell [45], p. 20.
Gurtin et al. [21], Sect. 27.2.
This does not exclude the dependence of \(\varphi \) and \(\chi \) on supplementary internal state variables, that is, on variables which do not appear in the external power. An example is classical plasticity, which involves an internal state variable, the plastic deformation. For more on this subject, see the paper [9].
Gurtin et al. [21], Sect. 39.
A “virtual power format for thermomechanics” was proposed by Podio Guidugli [39], see also [41] Chapter 4. His approach differs from the present one by the fact that in the expression (1) of the external power, the temperature rate \(\dot{\vartheta }_t\) is replaced by the time derivative \(\dot{\alpha }_t =\vartheta _t\) of the thermal displacement.
Truesdell and Toupin [48], incipit of Chapter E.III.
“In equilibrium thermodynamics ... the state variables are usually independent of the space coordinates,” de Groot and Mazur [7], p. 3. See also Podio Guidugli [41], Sect. 1.7.1. In the language of Truesdell’s school, this notion of thermal equilibrium corresponds to the thermodynamics of homogeneous processes, see [48], Sect. 260, or [45], Sect. 1.
Gurtin et al. [21], incipit of Part V.
Noll [33].
Noll [34].
Truesdell and Toupin [48], Sect. 262.
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I thank Paolo Podio Guidugli for stimulating discussions, and for his comments and suggestions.
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Communicated by Andreas Öchsner.
Dedicated to the memory of Bernard D. Coleman
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Del Piero, G. A mechanical model for heat conduction. Continuum Mech. Thermodyn. 32, 1159–1172 (2020). https://doi.org/10.1007/s00161-019-00821-y
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DOI: https://doi.org/10.1007/s00161-019-00821-y