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Journal of Cluster Science

, Volume 8, Issue 1, pp 115–122 | Cite as

Synthesis and X-ray crystal structure analysis of Fe2(CO)63-S)2Pd(bipy)

  • Richard D. Adams
  • Mingsheng Huang
  • Wengan Wu
Article

Abstract

The reaction of Fe2(CO)6(μ-S2),1 withbis(dibenzylideneacetone)-palladium, Pd(dba)2, in the presence of 2,2′-bipyridine yielded the new compound Fe2(CO)6(μ 3-S)2Pd(bipy),2 in good yield (66%). Compound2 was characterized by IR,1H NMR and single-crystal X-ray diffraction analyses. Compound2 contains a Pd(bipy) group that has been inserted into the S-S bond of1. Crystal data for2: space group P21/n,a=10.019(2) Å,b=25.414(5) Å,c=7.714(2) Å,β=90.26(2)°,Z=4, 1436 reflections,R=0.023.

Key words

Sulfido ligand mixed metal cluster palladium iron 

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • Richard D. Adams
    • 1
  • Mingsheng Huang
    • 1
  • Wengan Wu
    • 1
  1. 1.Department of Chemistry and BiochemistryUniversity of South CarolinaColumbia

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