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Synthesis and X-ray crystal structure analysis of Fe2(CO)6(μ3-S)2Pd(bipy)

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Abstract

The reaction of Fe2(CO)6(μ-S2),1 withbis(dibenzylideneacetone)-palladium, Pd(dba)2, in the presence of 2,2′-bipyridine yielded the new compound Fe2(CO)6(μ 3-S)2Pd(bipy),2 in good yield (66%). Compound2 was characterized by IR,1H NMR and single-crystal X-ray diffraction analyses. Compound2 contains a Pd(bipy) group that has been inserted into the S-S bond of1. Crystal data for2: space group P21/n,a=10.019(2) Å,b=25.414(5) Å,c=7.714(2) Å,β=90.26(2)°,Z=4, 1436 reflections,R=0.023.

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References

  1. R. D. Adams,in D. F. Shriver, H. D. Kaesz, and R. D. Adams (eds.),The Chemistry of Metal Cluster Complexes (VCH Publishers, New York, 1990), Chap. 3.

    Google Scholar 

  2. K. H. Whitmire (1988).J. Coord. Chem. 17, 95.

    Article  CAS  Google Scholar 

  3. R. D. Adams (1985).Polyhedron 4, 2003.

    Article  CAS  Google Scholar 

  4. D. A. Roberts and G. L. Geoffroy,in S. G. Wilkinson, F. G. A. Stone, and E. W. Abel (eds.),Comprehensive Organometallic Chemistry (Pergamon, Oxford, England, 1982), Chap. 40.

    Google Scholar 

  5. R. D. Adams, J. E. Babin, J.-G. Wang, and W. Wu (1989).Inorg. Chem. 28, 703.

    Article  CAS  Google Scholar 

  6. R. D. Adams, T. A. Wolfe, and W. Wu (1991).Polyhedron 10, 447.

    Article  CAS  Google Scholar 

  7. R. D. Adams, I. T. Horvath, and P. Mathur (1984).J. Am. Chem. Soc. 106, 6292.

    Google Scholar 

  8. M. Cowie, R. L. DeKock, T. R. Wagenmaker, D. Seyferth, R. S. Henderson, and M. K. Gallagher (1989).Organometallics 8, 119.

    Article  CAS  Google Scholar 

  9. N. S. Nametkin, V. D. Tyurin, and M. A. Kukina (1978).J. Organomet. Chem. 149, 355.

    Article  CAS  Google Scholar 

  10. T. Ukai, H. Kawazura, Y. Isii, J. J. Bonnet, and J. A. Ibers (1974).J. Organomet. Chem. 65, 253.

    Article  CAS  Google Scholar 

  11. International Tables for X-Ray Crystallography, Vol. IV (Kynoch Press, Birmingham, England, 1975), Table 2.2B, pp. 99–101.

  12. International Tables for X-Ray Crystallography, Vol IV (Kynoch Press, Birmingham, England, 1975), Table 2.3.1, pp. 149–150.

  13. V. W. Day, D. A. Lesch, and T. B. Rauchfuss (1982).J. Am. Chem. Soc. 104, 1290.

    Article  CAS  Google Scholar 

  14. C. H. Wei and L. F. Dahl (1965).Inorg. Chem. 4, 1.

    Article  CAS  Google Scholar 

  15. P. M. Maittis, P. Espinet, and M. J. H. Russell,in S. G. Wilkinson, F. G. A. Stone, and E. W. Abel (eds.),Comprehensive Organometallic Chemistry (Pergamon, Oxford, England, 1982), Chap. 38.

    Google Scholar 

  16. T. Ukai, H. Kawazura, and Y. Ishii (1974).J. Organomet. Chem. 65, 253.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, University of South Carolina, 29208, Columbia, South Carolina

    Richard D. Adams, Mingsheng Huang & Wengan Wu

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  1. Richard D. Adams
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  2. Mingsheng Huang
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  3. Wengan Wu
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Adams, R.D., Huang, M. & Wu, W. Synthesis and X-ray crystal structure analysis of Fe2(CO)6(μ3-S)2Pd(bipy). J Clust Sci 8, 115–122 (1997). https://doi.org/10.1007/BF02764132

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