Abstract
Thermal behavior of crude palm oil (CPO) is important to determine the optimal fractionation process and product yield. In this study, the effects of repeated heating on thermal behavior of CPO were examined by differential scanning calorimetry. CPO was heated at 80°C for 5 min, and heating was repeated five times to simulate the common conditions experienced by an oil before reaching the refinery. The result revealed that the thermal behavior of CPO changed after heating. The change, however, occurred only in the behavior of the high-melting stearin peak but not in the low-melting olein peak. Overheating split the stearin peak at 17.30°C to two peaks at 18.88 and 17.30°C and formed a new peak at 11.28°C. Apparently, a new substance has been synthesized.
Similar content being viewed by others
References
Johansson, G., and P.O. Pehlergard, Aspects on Quality of Palm Oil, edited by D.A. Earp and W. Newall, in International Developments in Palm Oil. The Proceedings of the Malaysian International Symposium on Palm Oil Processing and Marketing, Kuala Lumpur, 17–19 June 1976, The Intercorporated Society of Planters, Kuala Lumpur, Malaysia, 1977, pp. 203–222.
Hampson, J.W., and H.L. Rothbart, Triglyceride Specific Heat Determined by Differential Scanning Calorimetry, J. Am. Oil Chem. Soc. 60:1102–1104 (1983).
Hagemann, J.W., and J.A. Rothfus, Polymorphism and Transformation Energetics of Saturated Monoacid Triglycerides from Differential Scanning Calorimetry and Theoretical Modeling, Ibid.:1123–1131 (1983).
deMan, L., J.M. deMan, and B. Blackman, Polymorphic Behavior of Some Fully Hydrogenated Oils and Their Mixtures with Liquid Oil, Ibid.:1777–1780 (1989).
D’Souza, V., L. deMan, and J.M. deMan, Polymorphic Behavior of High-Melting Glycerides from Hydrogenated Canola Oil, Ibid.:907–911 (1991).
Herrera, M.L., and M.C. Anon, Crystalline Fractionation of Hydrogenated Sunflowerseed Oil. II. Differential Scanning Calorimetry (DSC), Ibid.:799–803 (1991).
Busfield, W.K., and P.N. Proschogo, Thermal Analysis of Palm Stearine by DSC, Ibid.:171–175 (1990).
Busfield, W.K., and P.N. Proschogo, Hydrogenation of Palm Stearine: Changes in Chemical Composition and Thermal Properties, Ibid.:176–181 (1990).
Che Man, Y.B., and P.Z. Swe, Thermal Analysis of Failed-Batch Palm Oil by Differential Scanning Calorimetry, Ibid.:1529–1532 (1995).
Yap, P.H., deMan, J.M., and L. deMan, Polymorphism of Palm Oil and Palm Oil Products, Ibid.:693–697 (1989).
Kawamura, K., The DSC Thermal Analysis of Crystallization Behavior in Palm Oil I, Ibid.:753–758 (1979).
Kawamura, K., The DSC Thermal Analysis of Crystallization Behavior in Palm Oil, II, Ibid.:48–52 (1980).
Rossell, J.B., Differential Scanning Calorimetry of Palm Kernel Oil Products, Ibid.:505–511 (1975).
Taylor, A.M., The Crystallization and Dry Fractionation of Malaysian Palm Oil, Oleagineux 31:73–79 (1976).
Persmark, U., K.A. Melin, and P.O. Stahl, Palm Oil, Its Polymorphism and Solidification Properties, Rev. Ital. Del. Sos. Gra. 53:301–306 (1976).
Okiy, D.A., Interaction of Triglycerides and Diglycerides of Palm Oil, Oleagineux 33:625–628 (1978).
Swe, P.Z., Y.B. Che Man, and H.M. Ghazali, Polymorphic Study of High Melting Glycerides of Palm Olein Crystals, Mal. Oil Sci. Tech. 4:205–208 (1995).
Goh, S.H., Y.M. Choo, and A.S.H. Ong, Minor Components in Palm Oil, in PORIM International Oil Palm/Palm Oil Conference Technology, PORIM, Kuala Lumpur, Malaysia, 1988, pp. 95–101.
Wong, K.C., Oxidation of Some of the Components of Palm Oil, edited by D.A. Earp and W. Newall, in International Developments in Palm Oil. The Proceedings of the Malaysian International Symposium on Palm Oil Processing and Marketing, Kuala Lumpur, 17–19 June 1976, The Intercorporated Society of Planters, Kuala Lumpur, Malaysia, 1977, pp. 187–201.
Wong, C.Y., Survey of Malaysian Crude Palm Oil Quality Delivered to Refiners, Palm Oil in the Eighties, PORIM, Kuala Lumpur, 1983.
Author information
Authors and Affiliations
About this article
Cite this article
Haryati, T., Che Man, Y.B. & Swe, P.Z. Effect of repeated heating on thermal behavior of crude palm oil. J Amer Oil Chem Soc 74, 393–396 (1997). https://doi.org/10.1007/s11746-997-0096-y
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s11746-997-0096-y