Abstract
The diffraction of beams of X-rays from single crystals involves very specific geometries that form the basis for the measurement of intensities used in crystal structure analysis. In terms of the incident beam itself, the two key approaches available involve either a monochromatic beam or a polychromatic `Laue' white beam. Starting from Bragg's law and the Ewald reciprocal-space construction, the methods for the collection of diffraction data, i.e. reflection intensities, using commonly available apparatus are then described. Monochromatic beam measuring methods such as rotating/oscillating crystal, stills, Weissenberg, precession and four-circle diffractometry are covered. The mathematical relationships between the reciprocal-lattice point (relp) coordinates in reciprocal space and the corresponding diffraction spot positions at the detector (flat, cylindrical or V-shaped) are given in detail. These coordinate transformations represent an idealized situation of relps (i.e. as points) and of diffracted rays as lines. Deviations from ideality arise from practical considerations such as the incident beam spectral purity, its divergence or convergence to the sample from the source via the optics, as well as the crystal perfection (`mosaicity'), and of the point-spread factor of the detector. The reflection rocking curves and diffraction spot shapes and sizes are practical manifestations of these effects. This chapter is also available as HTML from the International Tables Online site hosted by the IUCr.
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© 2006 International Union of Crystallography
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Helliwell, J.R. (2006). Single-crystal X-ray techniques. In: Prince, E. (eds) International Tables for Crystallography Volume C: Mathematical, physical and chemical tables. International Tables for Crystallography, vol C. Springer, Dordrecht. https://doi.org/10.1107/97809553602060000577
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DOI: https://doi.org/10.1107/97809553602060000577
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-1900-5
Online ISBN: 978-1-4020-5408-2
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