Abstract
Metallic glass (MG) with a long-range topological disorder structure exhibits some unique mechanical, physical, and chemical properties compared to its crystalline counterpart, such as high hardness and strength, large elastic limit as well as superior resistance to wear and corrosion. These features make MGs to be regarded as very promising materials. Recent studies indicate that patterned MG surface with micro-/nanostructures on it can hugely enhance its biological activity and compatibility, catalytic activity, and hydrophobicity, extending the application of MGs in biomedicine, waterproof material, industrial catalysis, sewage treatment, etc. This chapter summarizes the potential methods for patterning MGs firstly, mainly including mechanical machining, thermoplastic shaping, chemical etching, and laser irradiation. Then, the emphasis is on nanosecond pulsed laser patterning of MGs, and its recent achievement and development will be addressed. The surface structures patterned by single nanosecond pulsed laser irradiation as well as line laser irradiation under various experimental parameters and environmental atmospheres will be introduced, and their formation mechanisms will be discussed. Accordingly, a new surface patterning method of MGs, i.e., nanosecond pulsed laser irradiation inducing selective thermoplastic extrusion in nitrogen gas, will be provided. Furthermore, the effect of patterned microstructures on the surface hydrophobicity will be briefly discussed.
References
Bakkal M, Shih AJ, Scattergood RO (2004a) Chip formation, cutting forces, and tool wear in turning of Zr-based bulk metallic glass. Int J Mach Tools Manuf 44:915–925
Bakkal M, Liu CT, Watkins TR et al (2004b) Oxidation and crystallization of Zr-based bulk metallic glass due to machining. Intermetallics 12:195–204
Bloembergen N (1973) Role of cracks, pores, and absorbing inclusions on laser-induced damage threshold at surfaces of transparent dielectrics. Appl Opt 12:661–664
Brinksmeier E, Riemer O, Glabe R et al (2010) Submicron functional surfaces generated by diamond machining. CIRP Ann Manuf Technol 59:535–538
Bulgakova NM, Bulgakov AV (2001) Pulsed laser ablation of solids: transition from normal vaporization to phase explosion. Appl Phys A Mater Sci Process 73:199–208
Byrne CJ, Eldrup M (2008) Materials science – bulk metallic glasses. Science 321:502–503
Cassie ABD, Baxter S (1944) Wettability of porous surfaces. Trans Faraday Soc 40:546–551
Chen N, Frank R, Asao N et al (2011) Formation and properties of Au-based nanograined metallic glasses. Acta Mater 59:6433–6440
Chen N, Shi XT, Witte R et al (2013) A novel Ti-based nanoglass composite with submicron-nanometer-sized hierarchical structures to modulate osteoblast behaviors. J Mater Chem B 1:2568–2574
Feit MD, Rubenchik AM (2003) Influence of subsurface cracks on laser induced surface damage. In: SPIE boulder damage symposium XXXV annual symposium on optical materials for high power lasers, Boulder, Colorado, 22–24 Sept 2003
Fujita K, Morishita Y, Nishiyama N et al (2005) Cutting characteristics of bulk metallic glass. Mater Trans 46:2856–2863
Gilbert CJ, Ritchie RO, Johnson WL (1997) Fracture toughness and fatigue-crack propagation in a Zr-Ti-Ni-Cu-Be bulk metallic glass. Appl Phys Lett 71:476–478
Guo P, Lu Y, Ehmann KF et al (2014a) Generation of hierarchical micro-structures for anisotropic wetting by elliptical vibration cutting. CIRP Ann Manuf Technol 63:553–556
Guo SF, Qiu JL, Yu P et al (2014b) Fe-based bulk metallic glasses: Brittle or ductile? Appl Phys Lett 105:161901
Hasan M, Kumar G (2016) High strain rate thermoplastic demolding of metallic glasses. Scr Mater 123:140–143
Hasan M, Schroers J, Kumar G (2015) Functionalization of metallic glasses through hierarchical patterning. Nano Lett 15:963–968
He P, Li LK, Wang F et al (2016a) Bulk metallic glass mold for high volume fabrication of micro optics. Microsyst Technol 22:617–623
He YX, Peng Y, Li Z et al (2016b) Bio-inspired multifunctional metallic glass. Sci China Chem 59:271–276
Hu Z, Gorumlu S, Aksak B et al (2015) Patterning of metallic glasses using polymer templates. Scr Mater 108:15–18
Huang H, Yan JW (2017) Surface patterning of Zr-based metallic glass by laser irradiation induced selective thermoplastic extrusion in nitrogen gas. J Micromech Microeng 27:075007
Huang H, Zhao HW, Shi CL et al (2012) Effect of residual chips on the material removal process of the bulk metallic glass studied by in situ scratch testing inside the scanning electron microscope. AIP Adv 2:042193
Huang H, Jun N, Jiang MQ et al (2016a) Nanosecond pulsed laser irradiation induced hierarchical micro/nanostructures on Zr-based metallic glass substrate. Mater Des 109:153–161
Huang H, Noguchi J, Yan JW (2016b) Shield gas induced cracks during nanosecond-pulsed laser irradiation of Zr-based metallic glass. Appl Phys A Mater Sci Process 122:881
Inoue A, Takeuchi A (2010) Recent development and applications of bulk glassy alloys. Int J Appl Glas Sci 1:273–295
Jagdheesh R (2014) Fabrication of a superhydrophobic Al2O3 surface using picosecond laser pulses. Langmuir 30:12067–12073
Jiang MQ, Wei YP, Wilde G et al (2015) Explosive boiling of a metallic glass superheated by nanosecond pulse laser ablation. Appl Phys Lett 106:021904
Kaltenboeck G, Harris T, Sun K et al (2014) Accessing thermoplastic processing windows in metallic glasses using rapid capacitive discharge. Sci Rep 4:6441
Ketov SV, Shi XT, Xie GQ et al (2015) Nanostructured Zr-Pd metallic glass thin film for biochemical applications. Sci Rep 5:7799
Khun NW, Yu H, Chong ZZ et al (2016) Mechanical and tribological properties of Zr-based bulk metallic glass for sports applications. Mater Des 92:667–673
Kumar G, Tang HX, Schroers J (2009) Nanomoulding with amorphous metals. Nature 457:868–872
Lewandowski JJ, Wang WH, Greer AL (2005) Intrinsic plasticity or brittleness of metallic glasses. Philos Mag Lett 85:77–87
Li T, Almond DP, Rees DAS (2011) Crack imaging by scanning pulsed laser spot thermography. NDT&E Int 44:216–225
Li N, Xia T, Heng LP et al (2013) Superhydrophobic Zr-based metallic glass surface with high adhesive force. Appl Phys Lett 102:251603
Li N, Chen W, Liu L (2016) Thermoplastic micro-forming of bulk metallic glasses: a review. JOM J Miner Met Mater Soc 68:1246–1261
Liu Z, Schroers J (2015) General nanomoulding with bulk metallic glasses. Nanotechnology 26:145301
Liu Y, Jiang MQ, Yang GW et al (2011) Surface rippling on bulk metallic glass under nanosecond pulse laser ablation. Appl Phys Lett 99:191902
Liu Y, Jiang MQ, Yang GW et al (2012) Saffman-Taylor fingering in nanosecond pulse laser ablating bulk metallic glass in water. Intermetallics 31:325–329
Ma J, Zhang XY, Wang DP et al (2014) Superhydrophobic metallic glass surface with superior mechanical stability and corrosion resistance. Appl Phys Lett 104:173701
Marti K (2007) Sampling the sun. Science 318:401–402
Martinez-Calderon M, Manso-Silvan M, Rodriguez A et al (2016) Surface micro- and nano-texturing of stainless steel by femtosecond laser for the control of cell migration. Sci Rep 6:36296
Miotello A, Kelly R (1995) Critical-assessment of thermal models for laser sputtering at high fluences. Appl Phys Lett 67:3535–3537
Myrach P, Polomski B, Le Claire E et al (2016) Thermographic crack detection in hot steel surfaces. In: 19th world conference on non-destructive testing, Munich, Germany, 13–17 June 2016
Nagendra N, Ramamurty U, Goh TT et al (2000) Effect of crystallinity on the impact toughness of a La-based bulk metallic glass. Acta Mater 48:2603–2615
Pauly S, Lober L, Petters R et al (2013) Processing metallic glasses by selective laser melting. Mater Today 16:37–41
Plummer J, Johnson WL (2015) Is metallic glass poised to come of age? Nat Mater 14:553–555
Sarac B, Ketkaew J, Popnoe DO et al (2012) Honeycomb structures of bulk metallic glasses. Adv Funct Mater 22:3161–3169
Sarac B, Bera S, Balakin S et al (2017) Hierarchical surface patterning of Ni- and Be-free Ti- and Zr-based bulk metallic glasses by thermoplastic net-shaping. Mater Sci Eng C Mater Biol Appl 73:398–405
Schlichting J, Ziegler M, Maierhofer C et al (2012) Flying laser spot thermography for the fast detection of surface breaking cracks. In: 18th world conference on nondestructive testing, Durban, South Africa, 16–20 Apr 2012
Schroers J (2010) Processing of bulk metallic glass. Adv Mater 22:1566–1597
Schroers J (2013) Bulk metallic glasses. Phys Today 66:32–37
Ta DV, Dunn A, Wasley TJ et al (2015) Nanosecond laser textured superhydrophobic metallic surfaces and their chemical sensing applications. Appl Surf Sci 357:248–254
Telford M (2004) The case for bulk metallic glass. Mater Today 7:36–43
Trexler MM, Thadhani NN (2010) Mechanical properties of bulk metallic glasses. Prog Mater Sci 55:759–839
Vorobyev AY, Guo CL (2015) Multifunctional surfaces produced by femtosecond laser pulses. J Appl Phys 117:033103
Wang WH (2012) The elastic properties, elastic models and elastic perspectives of metallic glasses. Prog Mater Sci 57:487–656
Williams E, Brousseau EB (2016) Nanosecond laser processing of Zr41.2Ti13.8Cu12.5Ni10Be22.5 with single pulses. J Mater Process Technol 232:34–42
Xia T, Li N, Wu Y et al (2012) Patterned superhydrophobic surface based on Pd-based metallic glass. Appl Phys Lett 101:081601
Xu SL, Shimada K, Mizutani M et al (2014) Fabrication of hybrid micro/nano-textured surfaces using rotary ultrasonic machining with one-point diamond tool. Int J Mach Tools Manuf 86:12–17
Yang J, Luo FF, Kao TS et al (2014) Design and fabrication of broadband ultralow reflectivity black Si surfaces by laser micro/nanoprocessing. Light Sci Appl 3:e185
Yoo JH, Jeong SH, Mao XL et al (2000) Evidence for phase-explosion and generation of large particles during high power nanosecond laser ablation of silicon. Appl Phys Lett 76:783–785
Zhao K, Liu KS, Li JF et al (2009) Superamphiphobic CaLi-based bulk metallic glasses. Scr Mater 60:225–227
Zhao M, Abe K, Yamaura S et al (2014) Fabrication of Pd-Ni-P metallic glass nanoparticles and their application as highly durable catalysts in methanol electro-oxidation. Chem Mater 26:1056–1061
Zhu ZW, To S, Zhang SJ (2015) Theoretical and experimental investigation on the novel end-fly-cutting-servo diamond machining of hierarchical micro-nanostructures. Int J Mach Tools Manuf 94:15–25
Acknowledgments
This work was supported by the National Natural Science Foundation of China (Grant No. 51705197), Grant-in-Aid for JSPS Fellows (Grant No. 26-04048), and Young Talent Lift Project of China Association for Science and Technology (CAST) and Chinese Mechanical Engineering Society (CMES).
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Huang, H., Yan, J. (2018). Laser Patterning of Metallic Glass. In: Yan, J. (eds) Micro and Nano Fabrication Technology. Micro/Nano Technologies. Springer, Singapore. https://doi.org/10.1007/978-981-13-0098-1_15
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DOI: https://doi.org/10.1007/978-981-13-0098-1_15
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