Introduction
Generally, ionic liquids (ILs) are defined as those fused salts with a melting point less than 100 °C, with salts with higher melting points referred to as molten salts [16]. As far as we can ascertain, the first truly room-temperature IL discovered was ethylammonium nitrate ([EtNH3][NO3]) reported in 1914 by Walden [41], with a melting point of 12.5 °C [31]. Typical ILs are composed of a large organic cation and an inorganic polyatomic anion or an organic polyatomic anion, showing the high thermal stability, low vapor pressure, wide liquid temperature range, and adjustable physicochemical characteristics [12, 50]. The physicochemical properties of ILs can be easily tuned by changing the type and structure of anions and cations, and once a potential IL satisfying the property specifications is screened, the chemists are required to synthesize it for a given separation task such as the adsorption of toxic gases. Therefore, ILs can be regarded as “designer solvents” in...
References
Anderson JL, Dixon JK, Maginn EJ (2006) Measurement of SO2 solubility in ionic liquids. J Phys Chem B 110:15059–15062
Anderson JL, Dixon JK, Brennecke JF (2007) Solubility of CO2, CH4, C2H6, C2H4, O2, and N2 in 1-hexyl-3-methylpyridinium bis (trifluoromethylsulfonyl) imide: comparison to other ionic liquids. Acc Chem Res 40:1208–1216
Anthony JL, Maginn EJ, Brennecke JF (2002) Solubilities and thermodynamic properties of gases in the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate. J Phys Chem B 106:7315–7320
Bates ED, Mayton RD, Ntai I et al (2002) CO2 capture by a task-specific ionic liquid. J Am Chem Soc 124:926–927
Blanchard LA, Hancu D, Beckman EJ et al (1999) Green processing using ionic liquids and CO2. Nature 399:28
Brennführer A, Neumann H, Beller M (2009) Palladium-catalyzed carbonylation reactions of aryl halides and related compounds. Angew Chem Int Ed 48:4114–4133
Camper D, Scovazzo P, Koval C et al (2004) Gas solubilities in room-temperature ionic liquids. Ind Eng Chem Res 43:3049–3054
Carlisle TK, Bara JE, Gabriel CJ et al (2008) Interpretation of CO2 solubility and selectivity in nitrile-functionalized room-temperature ionic liquids using a group contribution approach. Ind Eng Chem Res 47:7005–7012
Chen Y, Zhou XQ, Cao Y et al (2013) Quantitative investigation on the physical and chemical interactions between CO2 and amine-functionalized ionic liquid [aEMMIM][BF4] by NMR. Chem Phys Lett 574:124–128
Chen FF, Huang K, Zhou Y et al (2016) Multi-molar absorption of CO2 by the activation of carboxylate groups in amino acid ionic liquids. Angew Chem Int Ed 55:7166–7170
Cui G, Zheng J, Luo X et al (2013) Tuning anion-functionalized ionic liquids for improved SO2 capture. Angew Chem Int Ed 52:10620–10624
Cui G, Wang J, Zhang S (2016) Active chemisorption sites in functionalized ionic liquids for carbon capture. Chem Soc Rev 45:4307–4339
Deng D, Gao B, Zhang C et al (2019) Investigation of protic NH4SCN-based deep eutectic solvents as highly efficient and reversible NH3 absorbents. Chem Eng J 358:936–943
Finotello A, Bara JE, Camper D et al (2008) Room-temperature ionic liquids: temperature dependence of gas solubility selectivity. Ind Eng Chem Res 47:3453–3459
Ghobadi AF, Taghikhani V, Elliott JR (2011) Investigation on the solubility of SO2 and CO2 in imidazolium-based ionic liquids using NPT Monte Carlo simulation. J Phys Chem B 115:13599–13607
Greaves TL, Drummond CJ (2008) Protic ionic liquids: properties and applications. Chem Rev 108:206–237
Greer A, Taylor SFR, Daly H et al (2019) Investigating the effect of NO on the capture of CO2 using superbase ionic liquids for flue gas applications. ACS Sustain Chem Eng. https://doi.org/10.1021/acssuschemeng.8b05870
Haruta M, Kobayashi T, Sano H (1987) Novel gold catalysts for the oxidation of carbon monoxide at a temperature far below 0 °C. Chem Lett 16:405–408
Hert DG, Anderson JL, Aki SN et al (2005) Enhancement of oxygen and methane solubility in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide using carbon dioxide. Chem Commun 20:2603–2605
Hu P, Rismani-Yazdi H, Stephanopoulos G (2013) Anaerobic CO2 fixation by the acetogenic bacterium Moorella thermoacetica. AIChE J 59:3176–3183
Huang Y, Cui G, Wang H et al (2018) Tuning ionic liquids with imide-based anions for highly efficient CO2 capture through enhanced cooperations. J CO2 Util 28:299–305
Kumełan J, Kamps ÁPS, Tuma D et al (2005) Solubility of CO in the ionic liquid [bmim][PF6]. Fluid Phase Equilib 228:207–211
Kumełan J, Kamps ÁPS, Tuma D (2007) Solubility of the single gases H2 and CO in the ionic liquid [bmim][CH 3SO4]. Fluid Phase Equilib 260:3–8
Kumełan J, Kamps ÁPS, Tuma D et al (2007) Solubility of the single gases methane and xenon in the ionic liquid [hmim][Tf2N]. Ind Eng Chem Res 46:8236–8240
Kumełan J, Kamps ÁPS, Tuma D et al (2007) Solubility of the single gases methane and xenon in the ionic liquid [bmim][CH3SO4]. J Chem Eng Data 52:2319–2324
Lei Z, Dai C, Chen B (2013) Gas solubility in ionic liquids. Chem Rev 114:1289–1326
Lei X, Xu Y, Zhu L et al (2014) Highly efficient and reversible CO2 capture through 1, 1, 3, 3-tetramethylguanidinium imidazole ionic liquid. RSC Adv 4:7052–7057
Li X, Zhang L, Li L et al (2018) NO removal from flue gas using conventional imidazolium-based ionic liquids at high pressures. Energy Fuel 32:6039–6048
Ohlin CA, Dyson PJ, Laurenczy G (2004) Carbon monoxide solubility in ionic liquids: determination, prediction and relevance to hydroformylation. Chem Commun 9:1070–1071
Perez-Salado Kamps A, Tuma D, Xia J et al (2003) Solubility of CO2 in the ionic liquid [bmim][PF6]. J Chem Eng Data 48:746–749
Poole CF (2004) Chromatographic and spectroscopic methods for the determination of solvent properties of room temperature ionic liquids. J Chromatogr A 1037:49–82
Qian W, Xu Y, Xie B (2017) Alkanolamine-based dual functional ionic liquids with multidentate cation coordination and pyrazolide anion for highly efficient CO2 capture at relatively high temperature. Int J Greenh Gas Con 56:194–201
Schneider WF, Brennecke JF, Maginn EJ et al (2018) U.S. Patent No. 9,951,008. U.S. Patent and Trademark Office, Washington, DC
Shang Y, Li H, Zhang S et al (2011) Guanidinium-based ionic liquids for sulfur dioxide sorption. Chem Eng J 175:324–329
Shang D, Bai L, Zeng S et al (2018) Enhanced NH3 capture by imidazolium-based protic ionic liquids with different anions and cation substituents. J Chem Technol Biotechnol 93:1228–1236
Sharma A, Julcour C, Kelkar AA et al (2009) Mass transfer and solubility of CO and H2 in ionic liquid. Case of [Bmim][PF6] with gas-inducing stirrer reactor. Ind Eng Chem Res 48:4075–4082
Shi W, Maginn EJ (2009) Molecular simulation of ammonia absorption in the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([emim][Tf2N]). AIChE J 55:2414–2421
Shokouhi M, Adibi M, Jalili AH (2009) Solubility and diffusion of H2S and CO2 in the ionic liquid 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate. J Chem Eng Data 55:1663–1668
Sutton MA, Erisman JW, Dentener F et al (2008) Ammonia in the environment: from ancient times to the present. Environ Pollut 156:583–604
Tao DJ, Chen FF, Tian ZQ et al (2017) Highly efficient carbon monoxide capture by carbanion-functionalized ionic liquids through C-site interactions. Angew Chem Int Ed 129:6947–6951
Walden P (1914) Molecular weights and electrical conductivity of several fused salts. Bull Acad Imper Sci (St. Petersburg) 1800:405
Wang C, Cui G, Luo X et al (2011) Highly efficient and reversible SO2 capture by tunable azole-based ionic liquids through multiple-site chemical absorption. J Am Chem Soc 133:11916–11919
Wang C, Luo X, Luo H et al (2011) Tuning the basicity of ionic liquids for equimolar CO2 capture. Angew Chem Int Ed 123:5020–5024
Wang J, Zeng S, Huo F et al (2019) Metal chloride anion-based ionic liquids for efficient separation of NH3. J Clean Prod 206:661–669
Wu W, Han B, Gao H et al (2004) Desulfurization of flue gas: SO2 absorption by an ionic liquid. Angew Chem Int Ed 116:2469–2471
Xu Y (2017) CO2 absorption behavior of azole-based protic ionic liquids: influence of the alkalinity and physicochemical properties. J CO2 Util 19:1–8
Yang Z, Jiang D, Zhu X et al (2014) Coordination effect-regulated CO2 capture with an alkali metal onium salts/crown ether system. Green Chem 16:253–258
Yokozeki A, Shiflett MB (2007) Ammonia solubilities in room-temperature ionic liquids. Ind Eng Chem Res 46:1605–1610
Yokozeki A, Shiflett MB (2007) Vapor–liquid equilibria of ammonia+ionic liquid mixtures. Appl Energy 84:1258–1273
Zeng S, Zhang X, Bai L et al (2017) Ionic-liquid-based CO2 capture systems: structure, interaction and process. Chem Rev 117:9625–9673
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Xu, Y. (2019). Ionic Liquid Materials for the Adsorption of Toxic Gases. In: Zhang, S. (eds) Encyclopedia of Ionic Liquids. Springer, Singapore. https://doi.org/10.1007/978-981-10-6739-6_90-1
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DOI: https://doi.org/10.1007/978-981-10-6739-6_90-1
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