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Supported Ionic Liquids

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Encyclopedia of Ionic Liquids
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Introduction

Supported ionic liquids (SILs) consist of two components: the support material and the ionic liquid (IL), and there are various types of each. SIL preparation can be divided into two strategies according to the interactions between the IL and support. The first method is a noncovalent preparation strategy, where ILs adsorb onto either the surface or pores of a support with a high specific surface area. In this case, there are only weak interactions, such as van der Waals forces, hydrogen bonding, and π-π interactions, between the support and the IL. Such materials are greatly affected by the surrounding environment, and their reusability is not ideal. The second method is referred to as a covalent preparation strategy, where the support and IL are connected by covalent bonds. The SILs prepared by this strategy have higher stability and better reusability than those prepared by the first method, but this second preparation process is more complicated. SIL preparation...

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References

  1. Werner S, Szesni N, Kaiser M, Haumann M, Wasserscheid P (2012) A scalable preparation method for SILP and SCILL ionic liquid thin-film materials. Chem Eng Technol 35(11):1962–1967

    Article  CAS  Google Scholar 

  2. Bi W, Zhou J, Row KH (2010) Separation of xylose and glucose on different silica-confined ionic liquid stationary phases. Anal Chim Acta 677(2):162–168

    Article  CAS  Google Scholar 

  3. Liu H, Li Z, Takafuji M, Ihara H, Qiu H (2017) Octadecylimidazolium ionic liquid-modified magnetic materials: preparation, adsorption evaluation and their excellent application for honey and cinnamon. Food Chem 229:208–214

    Article  CAS  Google Scholar 

  4. Zhou H, Chen J, Li H, Quan K, Zhang Y, Qiu H (2020) Imidazolium ionic liquid-enhanced poly(quinine)-modified silica as a new multi-mode chromatographic stationary phase for separation of achiral and chiral compounds. Talanta 211:120743

    Article  CAS  Google Scholar 

  5. Zhou X, Weber J, Yuan J (2019) Poly(ionic liquid)s: platform for CO2 capture and catalysis. Curr Opin Green Sustain Chem 16:39–46

    Article  Google Scholar 

  6. Branco LC, Crespo JG, Afonso CAM (2002) Highly selective transport of organic compounds by using supported liquid membranes based on ionic liquids. Angew Chem Int Ed 41(15):2771–2773

    Article  CAS  Google Scholar 

  7. Mecerreyes D (2011) Polymeric ionic liquids: broadening the properties and applications of polyelectrolytes. Prog Polym Sci 36(12):1629–1648

    Article  CAS  Google Scholar 

  8. Mehnert CP (2005) Supported ionic liquid catalysis. Chem Eur J 11(1):50–56

    Article  Google Scholar 

  9. Zhang Y, Shen Y, Yuan J, Han D, Wang Z, Zhang Q, Niu L (2006) Design and synthesis of multifunctional materials based on an ionic-liquid backbone. Angew Chem Int Ed 45(35):5867–5870

    Article  Google Scholar 

  10. Jon C-S, Meng L-Y, Li D (2019) Recent review on carbon nanomaterials functionalized with ionic liquids in sample pretreatment application. Trends Anal Chem 120:115641

    Article  CAS  Google Scholar 

  11. Fukushima T, Kosaka A, Ishimura Y, Yamamoto T, Takigawa T, Ishii N, Aida T (2003) Molecular ordering of organic molten salts triggered by single-walled carbon nanotubes. Science 300(5628):2072–2074

    Article  CAS  Google Scholar 

  12. Zhang B, Ning W, Zhang J, Qiao X, Zhang J, He J, Liu C-Y (2010) Stable dispersions of reduced graphene oxide in ionic liquids. J Mater Chem 20(26):5401–5403

    Article  CAS  Google Scholar 

  13. Tunckol M, Fantini S, Malbosc F, Durand J, Serp P (2013) Effect of the synthetic strategy on the non-covalent functionalization of multi-walled carbon nanotubes with polymerized ionic liquids. Carbon 57:209–216

    Article  CAS  Google Scholar 

  14. Xin B, Hao J (2014) ChemInform abstract: imidazolium-based ionic liquids grafted on solid surfaces. ChemInform 45(50)

    Google Scholar 

  15. Yang H, Shan C, Li F, Han D, Zhang Q, Niu L (2009) Covalent functionalization of polydisperse chemically-converted graphene sheets with amine-terminated ionic liquid. Chem Commun (26):3880–3882

    Google Scholar 

  16. Safaei M, Foroughi MM, Ebrahimpoor N, Jahani S, Omidi A, Khatami M (2019) A review on metal-organic frameworks: synthesis and applications. Trends Anal Chem 118:401–425

    Article  CAS  Google Scholar 

  17. Fujie K, Kitagawa H (2016) Ionic liquid transported into metal–organic frameworks. Coord Chem Rev 307:382–390

    Article  CAS  Google Scholar 

  18. Kurisingal JF, Rachuri Y, Pillai RS, Gu Y, Choe Y, Park D-W (2019) Ionic-liquid-functionalized UiO-66 framework: an experimental and theoretical study on the Cycloaddition of CO2 and epoxides. ChemSusChem 12(5):1033–1042

    Article  CAS  Google Scholar 

  19. Chong SY, Wang TT, Cheng LC, Lv HY, Ji M (2019) Metal–organic framework MIL-101-NH2-supported acetate-based Butylimidazolium ionic liquid as a highly efficient heterogeneous catalyst for the synthesis of 3-Aryl-2-oxazolidinones. Langmuir 35(2):495–503

    Article  CAS  Google Scholar 

  20. Dedzo GK (2019) Kaolinite clay mineral reactivity improvement through ionic liquid functionalization. Isr J Chem 59(9):778–788

    Article  CAS  Google Scholar 

  21. Letaief S, Detellier C (2005) Reactivity of kaolinite in ionic liquids: preparation and characterization of a 1-ethyl pyridinium chloride–kaolinite intercalate. J Mater Chem 15(44):4734–4740

    Article  CAS  Google Scholar 

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Correspondence to Hongdeng Qiu .

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Bi, W., Qiu, H. (2021). Supported Ionic Liquids. In: Zhang, S. (eds) Encyclopedia of Ionic Liquids. Springer, Singapore. https://doi.org/10.1007/978-981-10-6739-6_129-1

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  • DOI: https://doi.org/10.1007/978-981-10-6739-6_129-1

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  • Print ISBN: 978-981-10-6739-6

  • Online ISBN: 978-981-10-6739-6

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