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Commercial Polymer Blends

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Polymer Blends Handbook

Abstract

In this chapter, an overview of the commercially important polymer blends is presented with a particular emphasis on the rationale for their commercial development, the compatibilization principles, their key mechanical properties, and their current applications and markets. To facilitate the discussion, the commercial polymer blends have been classified as follows into 13 major groups depending on the type of the resin family they are based on.

  1. (i)

    Polyolefin blends

  2. (ii)

    Styrenic blends

  3. (iii)

    Vinyl resin blends

  4. (iv)

    Acrylic blends

  5. (v)

    Elastomeric blends

  6. (vi)

    Polyamide blends

  7. (vii)

    Polycarbonate blends

  8. (viii)

    Poly(oxymethylene) blends

  9. (ix)

    Polyphenyleneether blends

  10. (x)

    Thermoplastic polyester blends

  11. (xi)

    Specialty polymer blends

  12. (xii)

    Thermoset blend systems

  13. (xiii)

    Biodegradable polymer blends

Within each major category, the individual polymer blends of industrial significance have been described with relevant data. Since the discussion is limited only to those blends that are actually produced and used on a commercial scale, the relevant cost and performance factors that contribute to the commercial viability and success of various types of blends have been outlined.

In comparing the different blends, the specific advantages of each type, as well as any potential overlap in performance with other types of blends have also been discussed. The fundamental advantage of polymer blends, viz., their ability to combine cost-effectively the unique features individual resins, is particularly illustrated in the discussion of crystalline/amorphous polymer blends such as the polyamide and the polyester blends. Key to the success of many commercial blends, however, is the selection of intrinsically complementing systems or the development of effective compatibilization methods. The use of reactive compatibilization techniques in commercial polymer blends has also been illustrated under the appropriate sections such as the polyamide blends.

In many commercial blends, rubber toughening plays an important and integral part of the blend design. Combining high impact strength with other useful properties such as heat and solvent resistance can significantly enhance the commercial value of a blend. Hence, the nature of the impact modifiers used and the role of morphology on properties have been discussed under the appropriate cases of commercial blends. The chapter concludes with an outline of the potential trends in the commercial polymer development.

M.K. Akkapeddi: retired

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Notations and Abbreviations

ABS

Acrylonitrile-co-butadiene-co-styrene polymer

AES

Acrylonitrile-co-ethylene/propylene-co-styrene polymer

ASA

Acrylonitrile-co-styrene-co-acrylate polymer

BMC

Bulk molding compound

BMI

Bismaleimide

DMA

Dynamic mechanical analyzer

DSC

Differential scanning calorimeter

DTUL

Distortion temperature under load

EPDM

Ethylene-co-propylene-co-diene terpolymer rubber

EPR

Ethylene propylene copolymer rubber

EVA

Ethylene-vinylacetate copolymer

EVOH

Ethylene vinyl alcohol copolymer

HDPE

High density polyethylene

HDT

Heat distortion temperature

HIPS

High impact polystyrene

IPN

Interpenetrating network

LCP

Liquid crystal polyester

LCST

Lower critical solution temperature

LDPE

Low density polyethylene

LLDPE

Linear low density polyethylene

MBS

Methyl methacrylate-butadiene-styrene terpolymer rubber

Mt

Million metric tons

NBR

Acrylonitrile-co-butadiene rubber

PA

Polyamide

PBAT

Poly(butylene adipate-co-terephthalate)

PBD

Polybutadiene

PBS

Poly(butylene succinate)

PBT

Poly(butylene terephthalate)

PC

Polycarbonate

PCL

Polycaprolactone

PCTG

Poly (cyclohexane dimethanol-co-ethylene glycol terephthalate)

PEI

Polyetherimide

PET

Poly(ethylene terephthalate)

PHB

Poly(hydroxybutyric acid)

PLA

Poly(lactic acid)

PMMA

Poly(methyl methacrylate)

POE

Polyolefin elastomer

POM

Polyoxymethylene

PP

Polypropylene

PPA

Polyphthalamide

PPE

Poly(phenylene ether)

PPS

Poly(phenylene sulfide)

PPSU

Poly(phenyl sulfone)

PSU

Polysulfone

PVC

Poly(vinyl chloride)

SAN

Styrene-acrylonitrile copolymer

SBC

Styrene-butadiene block copolymer

SBR

Styrene-butadiene rubber

SEBS

Styrene-ethylene/butane-styrene block copolymer

SMA

Styrene-maleic anhydride copolymer

SMMA

Styrene-co-methyl methacrylate polymer

TPE

Thermoplastic elastomer

TPO

Thermoplastic polyolefin

TPU

Thermoplastic polyurethane

TPV

Thermoplastic vulcanizate

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Akkapeddi, M.K. (2014). Commercial Polymer Blends. In: Utracki, L., Wilkie, C. (eds) Polymer Blends Handbook. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6064-6_22

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