Abstract
In this chapter, an overview of the commercially important polymer blends is presented with a particular emphasis on the rationale for their commercial development, the compatibilization principles, their key mechanical properties, and their current applications and markets. To facilitate the discussion, the commercial polymer blends have been classified as follows into 13 major groups depending on the type of the resin family they are based on.
-
(i)
Polyolefin blends
-
(ii)
Styrenic blends
-
(iii)
Vinyl resin blends
-
(iv)
Acrylic blends
-
(v)
Elastomeric blends
-
(vi)
Polyamide blends
-
(vii)
Polycarbonate blends
-
(viii)
Poly(oxymethylene) blends
-
(ix)
Polyphenyleneether blends
-
(x)
Thermoplastic polyester blends
-
(xi)
Specialty polymer blends
-
(xii)
Thermoset blend systems
-
(xiii)
Biodegradable polymer blends
Within each major category, the individual polymer blends of industrial significance have been described with relevant data. Since the discussion is limited only to those blends that are actually produced and used on a commercial scale, the relevant cost and performance factors that contribute to the commercial viability and success of various types of blends have been outlined.
In comparing the different blends, the specific advantages of each type, as well as any potential overlap in performance with other types of blends have also been discussed. The fundamental advantage of polymer blends, viz., their ability to combine cost-effectively the unique features individual resins, is particularly illustrated in the discussion of crystalline/amorphous polymer blends such as the polyamide and the polyester blends. Key to the success of many commercial blends, however, is the selection of intrinsically complementing systems or the development of effective compatibilization methods. The use of reactive compatibilization techniques in commercial polymer blends has also been illustrated under the appropriate sections such as the polyamide blends.
In many commercial blends, rubber toughening plays an important and integral part of the blend design. Combining high impact strength with other useful properties such as heat and solvent resistance can significantly enhance the commercial value of a blend. Hence, the nature of the impact modifiers used and the role of morphology on properties have been discussed under the appropriate cases of commercial blends. The chapter concludes with an outline of the potential trends in the commercial polymer development.
M.K. Akkapeddi: retired
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References
R.K. Adams, G.K. Hoeschele, in Thermoplastic Elastomers, ed. by N.R. Legge, G. Holden, H.E. Schroeder (Hanser, Münich, 1987)
M.K. Akkapeddi, B. VanBuskirk, A.C. Brown, PCT Int. Appl., W088/08433, 3 Nov 1988, Appl. 24 Aug 1987; U.S. Patent 5,162,440, 10 Nov 1992, Appl. 24 Apr 1987, to AlliedSignal Inc.
M.K. Akkapeddi, J.A. Gervasi, U.S. Patent 4,826,955, 2 May 1989, Appl. 21 Jan 1988 to AlliedSignal Inc.
M.K, Akkapeddi, J.C. Haylock, J.A. Gervasi, U.S. Patent 4,847,322, 11 July 1989, Appl. 22 Oct 1987 to AlliedSignal Inc.
M.K. Akkapeddi, C.D. Mason, PCT Int. Appl., WO91/15545, 17 Oct 1991, Appl. 26 Feb 1991 to AlliedSignal Inc.
M.K. Akkapeddi, T.J. Kraft, B. VanBuskirk, U.S. Patent 5,115,018, 19 May 1992 to AlliedSignal Inc.
M.K. Akkapeddi, B. VanBuskirk, Adv. Polym. Technol. 11(4), 263 (1992); Polym. Prepr. 33(2), 602 (1992); Proceedings of the Polymer Processing Society, 9th Annual Meeting, Manchester, 1993
M.K. Akkapeddi, B. VanBuskirk, Polym. Mater. Sci. Eng. 67, 317 (1992)
M.K. Akkapeddi, C.D. Mason, B. VanBuskirk, Polym. Prepr. 34(2), 848 (1993a)
M.K. Akkapeddi, B. VanBuskirk, J.H. Glans, in Advances in Polymer Blends and Alloys Technology, ed. by K. Finlayson, vol. 4 (Technomic Publishing, Lancaster, 1993b)
M.K. Akkapeddi, B. VanBuskirk, T. Kraft, U.S. Patent 4,902,749, 20 Feb 1990, Appl. 24 Aug 1987; U.S. Patent 5,1115,018, 9 May 1992, Appl. 24 Aug 1987; U.S. Patent 5,210,134, 11 May 1993, Appl. 24 Aug 1987, to AlliedSignal Inc.
K. Akkapeddi, Rubber toughening of polyamides by reactive blending, Chap. 8, in Reactive Polymer Blending, ed. by W. Baker, C. Scott, G.H. Hu (Hanser, Munich, 2001), pp. 207–253
M.K. Akkapeddi, B. VanBuskirk, P. Gallantly, Unpublished results
M.K. Akkapeddi et al., U.S. Pat. 6,410,156; U.S. Pat. 6,423,776 (2002)
M.K. Akkapeddi et al., ANTEC’03 SPE Conference Tech. Papers 61, 3845 (2003)
M.K. Akkapeddi et al., E.P. Socci, T.J. Kraft, U.S. Pat. 6,756,444 (2004)
Anonymous, Product Literature on Vistanex® Polyisobutylene, Exxon Chem. Co. (1974)
Anonymous, Mod. Plast. 60(2), 12 (1983)
Anonymous, Product Literature on Trefsin® Thermoplastic Elastomer, Exxon Chem., Co. (1988)
Anonymous, Selar® PA 3426 Product Literature, DuPont Co. (1989)
Anonymous, Preliminary Product Literature on Blendex® HPP PPO® Modifier resins, General Electric Co. (1991)
Anonymous, Preliminary Literature on Capron® AB, AlliedSignal (1992)
Anonymous, Mod. Plast. 70(1), 83 (1993)
Anonymous, Technical information-Plastics modification, Engage® Polyolefin elastomers, Dow Chem. Co. (2006a)
Anonymous, Styrolux® Styrene-butadiene copolymer (SBC)- mechanical and optical properties, BASF chem. brochure (2006b)
Anonymous, Plast. Technol., April 2012, p.13
M. Aonuma, T. Suzuki, I. Isomura, K. Nishimura, U.S. Patent 4,996,264, issued 26 Feb 1991 to Nippon Zeon
B.C. Arkles, U.S. Patent 4,500,688, 19 Feb 1985, Appl. 20 Apr 1982, to Petrarch Systems
K.E. Atkins, in Polymer Blends, ed. by D.R. Paul, S. Newman, vol. 2 (Academic, New York, 1978)
K.E. Atkins, in Sheet Molding Compounds: Science and Technology, ed. by H.G. Kia (Hanser, NewYork, 1993), Chap. 4
K.E. Atkins, in Plastic Additives, an A-Z Reference, ed. by G. Pritchard (Chapman Hall, NewYork, 1998), p. 442
D.F. Aycock, S.P. Ting, U.S. Patent 4,600,741, 15 July 1986, Appl. 27 Sept 1984, to General Electric Co.
M. Baer, U.S. Patent 4,707,513, 17 Nov 1987, Appl. 11 Mar 1986, to Monsanto Co.
C. Bastioli, Polym. Degrad. Stab. 59, 263 (1998)
R.E. Bernstein, C.A. Crua, D.R. Paul, J.W. Barlow, Macromolecules 10, 681–686 (1977)
R.E. Bernstein, C.A. Cruz, D.R. Paul, J.W. Barlow, Macromolecules 10, 681 (1997)
H. Bertillson, B. Franzen, J. Kubat, Plast. Rubber Process. Appl. 10, 137 (1988)
M.D. Bertolucci, D.E. Delaney, SPE Tech. Pap 29, 23 (1983)
R. Binsack, T. Goldman, Ger. Patent 3,336,499, 25 Apr 1985, App. 7 Oct 1983, to Bayer A. G.
M. Biron, O. Marichal, Thermoplastics and Thermoplastic Composites, 2nd edn. (Elsevier, Oxford, U.K.) p. 31 (2013)
E.M. Boldebuck, U.S. Patent 3,063,872, 13 Nov 1962; App. 15 Feb 1960, to General Electric Co.
R.J.M. Borggreve, R.J. Gaymans, A.R. Luther, Makromol. Chem. Macromol. Symp. 16, 195 (1988)
R.J.M. Borggreve, R.J. Gaymans, Polym. Commun. 30, 71 (1989)
R.S. Brookman, Overview of blends and alloys for flexible PVc, in PVC Blends, Alloys and Graft Polymers Conference Proceedings (Atlanta, GA, 10th–12th Oct. 1898), p. 7–18
A.L. Brody, E.R. Strupinsky, L.R. Kline, Oxygen scavenger systems, in Active Packaging for Food Applications (Technomic Publishing, Pennsylvania, 2001)
S.B. Brown, D. McFay, J.B. Yates, G.F. Lee, U.S. Patent 4,978,715, 18 Dec 1990, Appl. 15 Aug 1988, to General Electric Co.
S.B. Brown, J.R. Campbell, T.J. Shea, U.S. Patent 5,039,742, 13 Aug 1991, Appl. 30 Oct 1989, to General Electric Co.
C.B. Bucknall, Toughened Plastics (Applied Science Publishers, London, 1977)
C.B. Bucknall, D. Clayton, W.E. Keast, J. Mater. Sci. 7, 1443 (1973)
C.B. Bucknall, I.K. Partridge, M.V. Ward, J. Mater. Sci. 19, 2064 (1984)
K. Burg, H. Chedron, F. Kloos, H. Schlaf, Eur. Patent App. 156,285, 2 Oct 1985, Appl. 19 March 1985; U.S. Patent 5,047,470, 10 Sept 1991, Appl. 20 May 1988
L.R. Burke, J.M. Newcombe, Plast. Eng., April 1982, p. 35
J. Bussink, J. DeMunck, C. Van Abeleen, U.S. Patent 4,122,131, 24 Oct 1978; App. 11 Sept 1977, to General Electric Co.
P.J. Cahill, S.Y. Chen, U.S. Patent 6,083,585, 4 July 2000 to B. P. Amoco Corp.
J.R. Campbell, S.Y. Hobbs, T.J. Shea, V.H. Watkins, Polym. Eng. Sci. 30, 1056 (1990)
R. Carew, R. Deisler, in Proceedings of the Compalloy ‘89 (Schotland Business Research, Princeton, 1989)
R.O. Carhart, in Engineering Thermoplastics, ed. by J.M. Margolis (Marcel Dekker, New York, 1985)
Ceresana Brochure, Market Study: Polypropylene, 2nd edn (2012), http://www.ceresana.com/en/market-studies/plastics/polypropylene
H.S. Chao, R.E. Colborn, J.R. Presley, J.M. Whalen, M.J. Davis, J.E. Tracy, E.F. Chu, U.S. Patent 5,213,886, 25 May 1993, Appl. 17 Feb 1989, to General Electric Co.
H. Chen, R. Porter, Polym. Eng. Sci. 32, 1870 (1992)
Y. Chen, Q. Sun, J. Drbohlav, Int. Patent. Appl. Pub. WO 2009/032560, 12 March 2009, to Invista Technologies.
C.I. Chung, Extrusion of Polymers: Theory and Practice (Hanser, 2000)
J.C. Chung, M.K. Akkapeddi, Polym. Prepr. 34(1), 614 (1993)
J.Y. Chung, D. Neuray, M. Witman, U.S. Patent 4,554,314, 19 Nov 1985, Appl. 14 Nov 1984, to Mobay Co.
E.P. Cizek, U.S. Patent 3,383,435, 14 May 1968, Appl. 6 Jan 1965, to General Electric Co.
A.Y. Coran, in Thermoplastic Elastomers, ed. by N.R. Legge, G. Holden, H.E. Schroeder (Hanser, Münich, 1987)
A.Y. Coran, R. Patel, Rubber Chem. Technol. 53, 781 (1980)
A.Y. Coran, R. Patel, U.S. Patent 4,355,139, 29 Oct 1982, Appl. 22 June 1981, to Monsanto Co.
A.Y. Coran, R. Patel, Rubber Chem. Technol. 56, 1045 (1983)
A.Y. Coran, B. Das, R. Patel, U.S. Patent 4,130,535, 19 Dec 1978, Appl. 30 Apr 1978 to Monsanto Co.
M.J. Cyr, H. Clauberg, M.E. Stewart, S.N. Falling, M.E. Rogers, U.S. Patent 6,455,620 24 Sept 2002 to Eastman Chemical Co.
S. Dagli, K. Kamdar, Polym. Eng. Sci. 34, 709 (1994)
L. D’orazio, R. Greco, C. Mancarella, E. Martucelli, G. Ragosta, C. Silvester, Polym. Eng. Sci. 22, 536 (1982)
K.C. Dao, J. Appl. Polym. Sci. 27, 4799 (1982)
K.C. Dao, Polymer 25, 1527 (1984)
M.E.J. Dekkers, S.Y. Hobbs, I. Bruker, V.H. Watkins, Polym. Eng. Sci. 30, 1628 (1990)
A. DeNicola, K. Okamoto, M. Van Cleuvenbergen, Proceed. Compalloy Europe, 95 (1992)
A. DeNicola, Hivalloy Resin technology: reactor produced polyolefin alloys, in 2nd Annual North America Symposium on “Recent Advances in Polymer Blends Alloys, Hilton Head, 1994
J. Deveaux, P. Goddard, J.P. Mercier, J. Polym. Sci. Poly. Phys. Ed. 20, 1881 (1982)
E.J. Deyrup, U.S. Patent 4,352,904, 5 Oct 1982, Appl. 5 Jan 1979 to DuPont Co.
E.J. Deyrup, U.S. Patent 4,753,980, 28 June 1988, Appl. 14 Nov 1986, to DuPont Co.
F. Dobkowski, Polymer 25, 110 (1988)
V. Dobrescu, V. Cobzaru, J. Polym. Sci. Polym. Symp. 64, 27 (1978)
M. Doescher, H. Jadamus, U.S. Patent 4,760,115, 26 July 1988, Appl. 30 March 1987, to Hüls A. G.
C.P. Donbe, D.J. Walsh, Polymer 20, 1115 (1979)
S. Dotson, G. Niznik, Modern Plastics Encyclopedia (McGraw Hill, New York, 1991), p. 175
R.S. Drake, A.R. Siebert, SAMPE Q 6, p. 1 (1975)
R.S. Drake, D.R. Egan, W.T. Murphy, ACS Symp. Ser. 221, 1 (1983)
E.A. Eastman, M.D. Dadmun, Polymer 43, 6707–6717 (2002)
A. Echte, Rubber Toughened Plastics (ACS Monograph, Washington, DC, 1989)
J.L. Eguiburu, J.J. Iruin, M.J. Fernandez-Berridi, J. Roman, Polymer 39, 6891 (1998)
T.S. Ellis, Polym. Eng. Sci. 30, 998 (1990)
B.N. Epstein, U.S. Patent 4,174,358, 13 Nov 1979, App. 11 Apr 1977, to DuPont Co.
J. Equiazabal, M. Cortazar, J. Irwin, J. Appl. Polym. Sci. 42, 489 (1991)
A. Escala, R.S. Stein, Adv. Chem. Ser. 176, 455 (1979)
T.R. Evans, D.D. Mosier, Plast. Eng. 17 (1991)
S.B. Farnham, T. Goldman, U.S. Patent 4,096,202, 20 June 1978, Appl. 9 June 1976, to Rohm and Haas Co.
Y. Feng, A. Schmidt, R.A. Weiss, Macromolecules 29, 3909 (1996)
E.A. Flexman, D.D. Huang, H.L. Snyder, Polym. Prepr. 31(2), 189 (1990)
E.A. Flexman, U.S. Patent 4,804,716, 24 Feb 1989; App. 21 July 1987, to DuPont Co.
G.R. Forger, Mater. Eng. 85, 44 (1977)
G.R. Forger, Plast. World 40, 28 (1982)
D. Freitag, V. Grigo, P.R. Muller, W. Nouvertne, in Encyclopedia of Polymer Science and Technology, ed. by H.F. Mark, N. Bikales, C.G. Overberger, G. Menges, vol. 11 (Wiley, New York, 1985), p. 706
D. Freitag, G. Fengler, L. Morbitzer, Angew. Chem. Int. Ed. 30, 1598 (1991)
J.R. Fried, F.E. Karasz, W.J. McKnight, Macromolecules 11, 150 (1978)
K. Friedrich, Crazing in polymers, in Advances in Polymer Science, ed. by H.H. Kausch, vol. 52/53 (Springer, Berlin, 1983)
J.S. Fry, C.N. Merriam, W.H. Boyd, in Applied Polymer Science, ed. by R.W. Tess, G.W. Poehlain, ACS Symp. Ser. 285, 1141 (1985)
M. Gabrielle, Plast. Technol., 59 (1992)
P. Galli, J.C. Haylock, E. Albizzati, A.J. DeNicola, High Performance Polyolefins (IUPAC, Akron, 1994)
P. Galli, J.C. Haylock, Prog. Polym. Sci. 16, 443 (1991)
R.R. Gallucci, M.A. Sanner, P. Sybert, SPE-ANTEC Tech. Conf., 2508 (2005)
R.R. Gallucci, A. Sanner, A. May, SPE ANTEC Tech. Conf., 1278 (2008)
R.R. Gallucci, M.A. Sanner, SPE ANTEC Tech. Conf., 2741 (2011)
Z.G. Gardlund, in Polymer Blends and Composites in Multiphase Systems, ed. by C.D. Han, Adv. Chem. Ser., 206 (ACS, Washington, DC, 1984)
B. Gelles, M. Modic, J. Kirkpatrick, SPE Tech. Pap. 34, 513 (1988)
J. Girard, Eng. Plast. 3, 51 (1990)
J.H. Glans, M.K. Akkapeddi, Macromolecules 24, 383 (1991)
P. Goddard, J.M. Dekoninck, V. Pevlesaver, J. Deveaux, J. Polym. Sci. Polym. Chem. 24, 3315 (1986)
T.S. Grabowski, U.S. Patent 3,130,177, 21 Apr 1964 to Borg-Warner Co.
T.S. Grant, C.L. Meyers, U.S. Patent 4,496,690, 29 Jan 1985, Appl. 3 June 1983, to Borg-Warner Co.
T.S. Grant, R.L. Jalbert, D. Whalen, U.S. Patent 4,732,935, 22 March 1988; App. 6 Dec 1985, to Borg-Warner
B. F. Greek, C & EN, June 10, 39 (1991)
P.F. Haartman, C.L. Eddy, G.P. Koo, SPE. J. 26(5), 62 (1970a)
P.F. Haartman, C.L. Eddy, G.P. Koo, Rubber World 163, 59 (1970b)
W.A. Haile, M.E. Tincher, F.W. Williams, Tappi INJ Summer 2002
W.J. Hall, A.C.S. Div. Org. Coat. Plast. Prepr., 47, 298 (1982)
C.F. Hammer, Macromolecules 4, 69 (1971)
B.D. Hanrahan, S.R. Angeli, J. Runt, Polym. Bull. 14, 399 (1985)
A. Hassan, B. Haworth, J. Mater. Process. Technol. 172, 341 (2006)
A.S. Hay, Polym. Eng. Sci. 16, 1 (1976)
A.S. Hay, U.S. Patent 3,306,874, 18 Feb 1967, Appl. 24 July 1962, to General Electric Co.
A.S. Hay, J. Am. Chem. Soc. 81, 6335 (1959)
D.R. Hazelton, R.C. Puydak, U.S. Patent 4,639,487, 27 Jan 1987, Appl. 11 July 1984, to Exxon Co.
P.L. Heater, G.A. Elliott, U.S. Patent App.Pub. US2007/0082157, 12 Apr 2007 to M&G U.S.A.
J.L. Hecht, T.M. Ford, SPE Tech. Pap. 31, 777 (1985)
J.J. Hemphill et al., Expanding the product portfolio of ethylene elastomers – ENGAGE™ polyolefin elastomers for large volume TPO applications, in Proceedings of the SPE-Automotive TPO Global Conference, October 10–12, 2005, Sterling Heights, MI, USA
S. Hirakawa, M. Haraguchi, M. Yasinawa, Rep. Progr. Polym. Phys. Jpn. 28, 171 (1985)
S.Y. Hobbs, R.C. Bopp, V.H. Watkins, Polym. Eng. Sci. 23, 380 (1983)
S.Y. Hobbs, M.E.J. Dekkers, V.H. Watkins, Polym. Bull. 17, 341 (1987)
S.Y. Hobbs, T. Stanley, O. Phansteil, Polym. Prepr. 33(2), 614 (1992)
C.J. Hooley, D.R. Moore, M. Whale, Plast. Rubber Process Appl. 345, 1 (1981)
D.J. Hourston, S. Lane, H.S. Zhang, Polymer 32, 2215 (1991)
D.V. Howe, M.D.J. Wolkowicz, Polym. Eng. Sci. 27, 1582 (1987)
Z. Huang, L. Wang, Makromol. Rapid Commun. 7, 255 (1986)
K.S. Hyun, C.G. Gogos, M.H. Kim, Extrusion technology for manufacturing polymer blends, in Encyclopedia of Polymer Blends, vol. 2 (Wiley-VCH, Weinheim, 2011)
F. Ide, A. Hasegawa, J. Appl. Polym. Sci. 18, 963 (1974)
Encyclopedia of Polymer Blends, vol. 2, Chap. 5, ed. by A.I. Isayev (Wiley-VCH, Weinheim, 2011), pp. 207–259
B. Imre, B. Pukanskzy, Eur. Polym. J. (2013; Article in press @ http://dx.doi.org/10.1016/j.eurpolymj.2013.01.019)
S.H. Jafaria, P. Potschkea, M. Stephana, H. Warth, H. Alberts, Polymer 43, 6985 (2002)
H. Iida, K. Kometani, M. Yanagi, U.S. Patent 4,284,540, 18 Aug 1981; App. 16 Apr 1980, to Toray Co.
H. Jager, E.J. Vorenkamp, G. Challa, Polym. Commun. 24, 290 (1983)
R.L. Jalbert, T.S. Grant, U.S. Patent 4,654,405, 31 March 1987; App. 5 Dec 1985, to Borg-Warner Co.
B.Z. Jang, D.R. Uhlman, J. VanderSande, Polym. Eng. Sci. 25, 643 (1985)
A.A. Jones, Macromolecules 18, 902 (1985)
G. Kailasam, R. Gallucci, M.A. Sanner, U.S. Patent App., 2009/0018242, 15 Jan 2009 to G.E.
N.K. Kalfouglou, Angew. Makromol. Chem. 118, 19 (1983)
R.P. Kambour, R.C. Bopp, A. Maconnachie, W.J. McKnight, Polymer 21, 133 (1980)
P.J. Kay, T. Ouhadi, J. Elastom. Plast. 23, 282 (1991)
J.D. Keitz, J.W. Barlow, D.R. Paul, J. App. Polym. Sci. 29, 3131 (1984)
W.N. Kim, C.M. Burns, Polym. Eng. Sci. 28, 1115 (1988)
W.N. Kim, C.M. Burns, J. Polym. Sci. Polym. Phys. 28, 1409 (1990)
A.J. Kinloch, R.J. Young, Fracture Behavior of Polymers (Applied Science Publishers, New York, 1983)
K. Kircher, Kunststoffe 80, 1113 (1990)
J. Kirkpatrick, M. Modic, D. Gilmore, in Proceedings of the Compalloy ‘89 (Schotland Business Research, Princeton, 1989)
K. Knoll, N. Niesner, Macromol. Symp. 132, 231 (1998)
R.M. Kossoff, “Future of Plastics Alloys” – III, international strategic plastics reports (R. M. Kossoff Associates, New York, 1987)
G.P. Kozielski, Plast. Technol., 73 (1988)
S.M. Krause, Compatible polymers, Chap. VI, in Polymer Handbook, ed. by J. Brandrup, E.H. Immergut (Wiley, New York, 1989), p. 347
S. Krause, Macromol. J. Sci. Rev. Macromol. Chem. C-7, 251 (1972)
R.J. Kray, R.J. Bellet, U.S. Patent 3,388,186, 11 June 1968, Appl. 2 March 1965, to Allied Chemical Co.
E.N. Kresge, in Polymer Blends, ed. by D.R. Paul, S. Newman, vol. 2 (Academic, New York, 1978)
T.D. Krizan, J.C. Coburn, P.S. Blatz, Polym. Prepr. 30, 9 (1989)
P.L. Ku, Adv. Polym. Technol. 8(3), 201 (1985)
R. Kusumgar, U.S. Patent 4,713,414, 15 Dec 1987, Appl. 16 July 1986, to Celanese Co.
L. Landers, J. Schmitt, J. Terenzi, U.S. Patent 3,354,238, 21 Nov 1967, Appl. 20 Dec 1966, to American Cyanamid Corp.
R.E. Lavengood, F.M. Silver, SPE RETEC ‘87, 266 (1987a)
R.E. Lavengood, F.M. Silver, SPE Tech. Pap. 33, 1369 (1987b)
R.E. Lavengood, A.F. Harris, A.R. Padwa, Europ. Patent Appl. 202,214, 20 Nov 1986, Appl. 9 May 1986, to Monsanto Co.
R.E. Lavengood, R. Patel, A.R. Padwa, U.S. Patent 4,777,211, 11 Oct 1988; App. 9 July 1986, to Monsanto Co.
G.F. Lee Jr., U.S. Patent 4,972,021, 20 Nov 1990, Appl. 14 Sept 1988, to General Electric Co.
Y.C. Lee, Q. Trementozzi, U.S. Patent 4,305,869, 15 Dec 1981; App. 17 Dec 1979, to Monsanto Co.
R. Legras, C. Bailley, M. Daumerie, J. Dekoninck, J. Mercier, V. Zichy, E. Nield, Polymer 25, 835 (1984)
H.M. Li, A.H. Wong, MMI Press Symposium Series, vol. 2 (Harwood Academic, New York, 1982)
P. Liu, D. Overton, U.S. Patent 4,532,282, July 1985, Appl. 16 March 1983, to General Electric Co.
W.L. Liu, Ger. Patent 3,728,685, 10 March 1988, Appl. 27 Aug 1987, to Rohm and Haas Co.
Z. Liu, S. Mehta, X. Huang, D.A. Schiraldi, U.S. Patent 7,919,159, 5 Apr 2011 to Invista.
G.L. Loomis, R.J. Statz, U.S. Patent 4,613,533, Sept 1986, App. July 1982, to DuPont Co.
W.A. Mack, Mod. Plast. 48(8), 62 (1971)
I. Manas-Zloczower (ed.), Mixing and Compounding of Polymers (Hanser, Munich, 2009)
C.D. Mason, H.W. Tuller, U.S. Patent 4,404,325, 13 Sept 1983, Appl. 11 May 1981 to AlliedSignal Inc.
M. Matsuo, Jpn. Plast. 2, 6 (1968)
M. Matsuo, C. Nozaki, Y. Jyo, Polym. Eng. Sci. 9, 197 (1969)
L.V. McAdams, J. Gamon, in Encyclopedia of Polymer Science and Technology, ed. by H.F. Mark, N. Bikales, C.G. Overberger, G. Menges, vol. 6 (Wiley, New York, 1985), p. 363
D.C. McConnell, G.M. McNally, W.R. Murphy, Dev. Chem. Eng. Miner. Process. 12, 37 (2004)
S.M. McDougle, SPE Tech. Pap. 13, 596 (1967)
F.J. McGarry, A.M. Willner, Research Report RJ-68-8 (School of Eng., M.I.T., Cambridge, MA, 1968)
G.A. Mellinger, H.F. Giles Jr., F. Holub, W.R. Schlich, U.S. Patent 4,548,997, 22 Oct 1985, App. 22 May 1984, to General Electric Co.
J. Mijovic, H.L. Luo, C.D. Han, Polym. Eng. Sci. 22, 234 (1982)
R.N. Mohn, D.R. Paul, J.W. Barlow, C.A. Cruz, J. Appl. Polym. Sci. 23, 575 (1979)
I. Mondragon, M. Gartelumindi, J. Nazabal, Polym. Eng. Sci. 28, 1126 (1989)
B.W. Moody, SPE Tech. Pap. 50, 1416 (1992)
L. Morbitzer, H.J. Kress, C. Lindner, K.H. Ott, Angew. Makromol. Chem. 132 (1983)
L.E. Murch, U.S. Patent 3,845,163, 29 Oct 1974; App. 24 Jan 1966, to DuPont Co.
S.R. Murff, J.W. Barlow, D.R. Paul, J. Appl. Polym. Sci. 29, 3231 (1984)
C.V. Murphy, SPE Tech. Pap. 31, 73 (1986)
M. Naitove, Conference report: bioplastics are breaking out of their green niche, Plastics Technology, Apr 2012
Y. Nakamura, R. Hasegawa, H. Kubota, U.S. Patent 3,864,428, 4 Feb 1975, App. 27 Aug 1973, to Teijin Ltd.
T.R. Nassar, D.R. Paul, J.W. Barlow, J. Appl. Polym. Sci. 23, 85 (1979)
D. Neuray, K.H. Ott, Angew. Makromol. Chem. 98, 123 (1981)
Nexant/Chemsystems online news article “PET suffering from over supply” (2007), www.chemsystems.com
Nexant/Chemsystems, “Nylon 6 and Nylon 66” PERP07/08S6 Report Abstract (2009)
Nexant/Chemsystems Online news article on ‘Polyolefins (2012)’, www.chemsystems.com
Y. Ohtsuka, EP 0658603 A2, 21 June 1995 to Daicel Chemical Industries
T. Okamoto, K. Yasue, T. Marutani, Y. Fukushima, U.S. Patent 4804707, 14 Feb 1989 to Unitika Ltd.
A.O. Ogah, J.L. Afikuwa, Int. J. Eng. Manag. Sci. 3(2), 85 (2012)
I. Ozen, G. Bozoklu, C. Dalgicdir, Y. Orcun, E. Unsal, M. Cakmak, Y. Menceloglu, Eur. Polym. J. 46, 226 (2010)
P.J. Perron, Adv. Polym. Technol. 6, 79 (1984)
P.J. Perron, U.S. Patent 4,782,114, 1 Nov 1988, Appl. 3 Oct 1986, to Dexter Corp.
E. Pittenger, G. Cohan, Mod. Plast. 25(1), 81 (1947a)
E. Pittenger, G. Cohan, Rubber Age 61, 563 (1947b)
A.P. Plochocki, Polyolefin blends, Chap. 21, in Polymer Blends, ed. by D.R. Paul, S. Newman, vol. 2 (Academic Press, New York, 1978), p. 223
R.S. Porter, L.H. Wang, Polymer 33, 2019 (1992)
V. Prattipati, Y. Hu, S. Bandi, S. Mehta, D.A. Schiraldi, A. Hiltner, E. Baer, J. Appl. Polym. Sci. 99, 225 (2006)
C.F. Pratt, S.Y. Hobbs, Polymer 17, 12 (1976)
W.M. Priest, R.S. Porter, J. Polym. Sci. Polym. Chem. 10, 1639 (1972)
F. Ramsteiner, W. Heckmann, Polym. Commun. 26, 199 (1985)
G.G. Ranby, J. Polym. Sci. Polym. Symp. 51, 89 (1975)
G.S. Rellick, J. Runt, Proc. ACS PSME 52, 331 (1985)
Reseau-plasturgie netzworke kunsoffetechnologie Conference- Bayer presentation on “Plastics industry and its role on our society”, Fribourg, Apr 2012
C.K. Riew, E.H. Rowe, A.R. Siefert, ACS Adv. Chem. Ser. 154, 326 (1976)
M.R. Rifi, H.K. Fieker, D.A. Walker, Mod Plast. 62(2), 62 (1987)
L.M. Robeson, J. Appl. Polym. Sci. 30, 4081 (1985)
L.M. Robeson, U.S. Patent 4,532,288, 30 July 1985; App. 29 Jan 1982, to Union Carbide Co.
L.M. Robeson, Miscible polymer blends containing poly (vinyl chloride), In PVC Blends, Alloys and Graft Polymers Conference Proceedings (Atlanta, GA; October 10–12, 1989), p. 134
M. Roodvoets, F. Embs, U.S. Patent App.Pub. US2012/02114935, 23 Aug 2012, to Invista, N. A.
J. Runt, D. Lei, L.M. Martynowicz, D.M. Brezny, M. Mayo, Macromolecules 22, 3908 (1989)
K. Saito, High Polym. Jpn. 22, 463 (1973)
H. Sakano, M. Kodama, T. Shoji, I. Yoshida, U.S. Patent 4,228,051, 14 Oct 1980, Appl. 31 July 1979 to Sumitomo Chem., Co.
J. Salay, D.J. Dougherty, Modern Plastics Encyclopedia (McGraw Hill, New York, 1992), p. 94
R. Saltman, B. Varnell, SPE Tech. Pap. 34, 1725 (1988)
R. Saltman, U.S. Patent 5,091,478, 25 Feb 1992; App. 21 May 1990, to DuPont Co.
M.A. Sanner, R.R. Gallucci, SPE ANTEC Tech. Conf., 2684 (2011)
L.R. Schmidt, J. Appl. Polym. Sci. 23, 2463 (1979)
W. Schuett, E. McKee, A. Hilt, H. Gorissen, G. Heinz, Ger. Patent 3,441,547, 15 May 1986, App. 14 Nov 1984, to BASF Co.
A.R. Schulz, B.M. Gendron, J. Appl. Polym. Sci. 16, 461 (1972)
H.H. Schut, Plast. Technol. 39(3), 29 (1993)
J.H. Schut, Plast. Technol. 38(7), 31 (1992)
J.H. Schut, Plast. World, 41 (1996)
R. Shanks, I. Kong, Thermoplastic starch, Chap.6, in Thermoplastic Elastomers, ed. by A. El-Sonbati (2012), http://www.intechopen.com/books/thermoplasticelastomers/thermoplastic-starch
M.T. Shaw, Polym. Eng. Sci. 22, 115 (1992)
L. Sherman, Plast. Technol., 17 (1997)
C.K. Shih, in Proceedings of the Compalloy (Schotland Business Research, Princeton, 1990)
Y.J. Shur, B.G. Ranby, J. Appl. Polym. Sci. 20, 3721 (1976)
W.A. Smith, J.W. Barlow, D.R. Paul, J. Appl. Polym. Sci. 26, 4223 (1981)
L.R. Spencer, Modern Plastics Encyclopedia (McGraw Hill, New York, 1991), p. 128
W.M. Speri, G.R. Patrick, Polym. Eng. Sci. 15, 668 (1975)
SRI, Report on Compounding of Engineering Thermoplastics (SRI International, Menlo Park, 1992a)
SRI, Report on World Petrochemicals (SRI International, Menlo Park, 1992b)
S. Srinivasan, Modern Plastics Encyclopedia (McGraw Hill, New York, 1992), p. 103
R.A. Steinkamp, U.S. Patent 3,953,655, 27 Apr 1976; App. 9 Apr 1971, to Exxon Co.
H. Suarez, J.W. Barlow, J. Appl. Polym. Sci. 29, 3253 (1984)
P.M. Subramanian, U.S. Patent 4,444,817, 24 Apr 1984, App. 29 Sept 1982, to DuPont. Co.
P.M. Subramanian, Polym. Eng. Sci. 25, 483 (1985)
M. Takayanagi, T. Ogata, M. Morikawa, T. Kai, J. Macromol. Sci. Phys. B17, 591 (1980)
Y. Takeda, D.R. Paul, Polymer 33, 3899 (1992)
J.M. Tibbitt, P.J. Cahill, G.E. Rotter, D.P. Sinclair, G.T. Brooks, R.T. Behrend, U.S. Patent 7,214,415, 8 May 2007 to B. P. Corporation North America Inc.
T.D. Traugott, in Encyclopedia of Polymer Science and Technology, ed. by H.F. Mark, N. Bikales, C.G. Overberger, G. Menges, vol. 16, 2nd edn. (Wiley, New York, 1985), p. 83
C. Tremblay, R.E. Prud’homme, J. Polym. Sci. Polym. Phys. 22, 1857 (1984)
K. Ueno, T. Maruyama, U.S. Patent 4,315,086, 9 Feb 1982, App. 16 July 1980, to Sumitomo Chemical Co.
L.A. Utracki, Commercial Polymer Blends (Chapman and Hall, London, 1998)
D.W. VanKrevelen, Properties of Polymers, 3rd edn. (Elsevier, Amsterdam, 1990)
I. Vrooman, L. Tighzert, Materials 2, 307 (2009)
D.C. Wahrmund, D.R. Paul, J.W. Barlow, J. Polym. Sci. 22, 2155 (1978)
J.G. Wallace, Modern Plastics Encyclopedia (McGraw Hill, New York, 1992), p. 100
T.T. Wang, T. Nashi, Macromolecules 10, 421–425 (1977)
D.G. Walsh, J.G. McKeown, Polymer, 21, 1220, 1335 (1980)
D.J. Walsh, G.L. Cheng, Polymer 25, 495 (1984)
L.B. Weaver et al., Novel ethylene/alpha-olefin copolymers-polyproylene blends for thermoforming, blow molding and extruded profiles, in Proceedings of SPE Polyolefins 2006, Houston, 2006
A. Wambach, Modern Plastics Encyclopedia (McGraw Hill, New York, 1992), p. 95
G.A. Weber, J. Schoeps, Angew. Makromol. Chem. 136, 45 (1985)
C.A. Weber, W. Paige, U.S. Patent 4,624,986, 25 Nov 1986, Appl. 7 Aug 1984, to Dow Chemical Co.
N.E. Weeks, F.E. Karasz, W.J. McKnight, J. Appl. Phys. 48, 4068 (1977)
W. Wenig, T. Schoeller, Angew. Makromol. Chem. 130, 155 (1985)
D.M. White, J.E. Hallgreen, J. Polym. Sci. Polym. Chem. 21, 2921 (1983)
D. White, R. Matthews, U.S. Patent 4,141,927 (1979) to G.E.
V. Wigotsky, Plast. Eng., 15 (1995)
M.W. Witman, Eur. Patent Appl. (05) 0036127, 23 Sept 1981, Appl. 4 March 1981 to Mobay Chemical Co.
K. Wood, A. Tanaka, M. Zheng, D. Garcia, 70% PVDF coatings for highly weatherable architectural coatings. Atofina Chem. Tech. Paper (2005) www.arkema-inc.com/pdf/techpoly/kurtpaper.pdf
S. Wu, in Polymer Handbook, Chap. VI, 3rd edn, ed. by J. Brandrup, E.H. Immergut (Wiley, New York, 1989)
S. Wu, Polymer 26, 1855 (1985)
S. Wu, J. Appl. Polym. Sci. 35, 549 (1988)
A.F. Yee, Polym. Eng. Sci. 17, 213 (1977)
A.F. Yee, Proceedings of the International Conference on Toughening of Plastics – II, London (1985).
P.-L. Yeh, A.W. Bisley, Plast. Rubber Process. Appl. 5, 249 (1985)
G.A. Zakrzewski, Polymer 14, 347 (1973)
M.P. Zamora, T. Miller, Plast. Eng., 75 (1997)
G. Zhang, J. Zhang, S. Wang, D. Shen, J. Polym. Sci. Polym. Phys. 41, 23 (2002)
J. Zimmerman, E.M. Pearce, I.K. Miller, J.A. Muzzio, I.G. Epstein, E.A. Hosegood, J. Appl. Polym. Sci. 17, 849 (1973)
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Notations and Abbreviations
- ABS
-
Acrylonitrile-co-butadiene-co-styrene polymer
- AES
-
Acrylonitrile-co-ethylene/propylene-co-styrene polymer
- ASA
-
Acrylonitrile-co-styrene-co-acrylate polymer
- BMC
-
Bulk molding compound
- BMI
-
Bismaleimide
- DMA
-
Dynamic mechanical analyzer
- DSC
-
Differential scanning calorimeter
- DTUL
-
Distortion temperature under load
- EPDM
-
Ethylene-co-propylene-co-diene terpolymer rubber
- EPR
-
Ethylene propylene copolymer rubber
- EVA
-
Ethylene-vinylacetate copolymer
- EVOH
-
Ethylene vinyl alcohol copolymer
- HDPE
-
High density polyethylene
- HDT
-
Heat distortion temperature
- HIPS
-
High impact polystyrene
- IPN
-
Interpenetrating network
- LCP
-
Liquid crystal polyester
- LCST
-
Lower critical solution temperature
- LDPE
-
Low density polyethylene
- LLDPE
-
Linear low density polyethylene
- MBS
-
Methyl methacrylate-butadiene-styrene terpolymer rubber
- Mt
-
Million metric tons
- NBR
-
Acrylonitrile-co-butadiene rubber
- PA
-
Polyamide
- PBAT
-
Poly(butylene adipate-co-terephthalate)
- PBD
-
Polybutadiene
- PBS
-
Poly(butylene succinate)
- PBT
-
Poly(butylene terephthalate)
- PC
-
Polycarbonate
- PCL
-
Polycaprolactone
- PCTG
-
Poly (cyclohexane dimethanol-co-ethylene glycol terephthalate)
- PEI
-
Polyetherimide
- PET
-
Poly(ethylene terephthalate)
- PHB
-
Poly(hydroxybutyric acid)
- PLA
-
Poly(lactic acid)
- PMMA
-
Poly(methyl methacrylate)
- POE
-
Polyolefin elastomer
- POM
-
Polyoxymethylene
- PP
-
Polypropylene
- PPA
-
Polyphthalamide
- PPE
-
Poly(phenylene ether)
- PPS
-
Poly(phenylene sulfide)
- PPSU
-
Poly(phenyl sulfone)
- PSU
-
Polysulfone
- PVC
-
Poly(vinyl chloride)
- SAN
-
Styrene-acrylonitrile copolymer
- SBC
-
Styrene-butadiene block copolymer
- SBR
-
Styrene-butadiene rubber
- SEBS
-
Styrene-ethylene/butane-styrene block copolymer
- SMA
-
Styrene-maleic anhydride copolymer
- SMMA
-
Styrene-co-methyl methacrylate polymer
- TPE
-
Thermoplastic elastomer
- TPO
-
Thermoplastic polyolefin
- TPU
-
Thermoplastic polyurethane
- TPV
-
Thermoplastic vulcanizate
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Akkapeddi, M.K. (2014). Commercial Polymer Blends. In: Utracki, L., Wilkie, C. (eds) Polymer Blends Handbook. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6064-6_22
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