Definition
A proper thermodynamic theory of mixtures avoids the so-called paradox of diffusion, by which disturbances in concentration propagate at infinite speeds. A theory with equations of balance of momenta for the constituents does that. Constraints on the constitutive functions are implied by the entropy principle which is exploited by use of Lagrange multipliers.
Introduction
The entropy principle provides restrictions on the form of the constitutive functions in thermodynamics. And Lagrange multipliers are a convenient tool for the exploitation of such restrictions. The method is illustrated here for a mixture of inviscid fluids – a paradigmatic case.
The basis for a systematic theory of mixtures was laid down by Truesdell (1957), and Müller has developed its thermodynamics in several papers (Müller, 1968, 1973; Müller and Villaggio, 1976), the latter in collaboration with Villaggio. Those were...
References
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Liu I-S, Müller I (1984) Thermodynamics of mixtures of fluids. In: Truesdell C (ed) Rational thermodynamics, 2nd edn. Appendix 5B. Springer, Heidelberg, p 264
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Müller I (1970) A new systematic approach to non-equilibrium thermodynamics. Pure Appl Chem 22:335
Müller I (1973) A new approach to thermodynamics of simple mixtures. Zeitschrift für Naturforschung 28a:1801
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Truesdell C (1957) Sulle basi della termodinamica. Accademia Nazionale dei Lincei. Rendiconti della Classe di Scienze Fisiche, Matematiche e Naturali 22:33
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Müller, I. (2018). Entropy Principle Exploited by Lagrange Multipliers. In: Altenbach, H., Öchsner, A. (eds) Encyclopedia of Continuum Mechanics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-53605-6_60-1
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DOI: https://doi.org/10.1007/978-3-662-53605-6_60-1
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