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Ethanol–Water Mixtures: Separation by Pervaporation

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Encyclopedia of Membranes
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Pervaporation is an important membrane process in chemical industries in which valuables are isolated from the liquid mixture. Liquid and vapor separation by thermal processes has always been highly energy intensive, and new separation processes taking advantage of mass transfer through dense membranes have already shown they enable very significant energy savings as compared to more classic technologies (Anne et al. 2002). Membranes can be used for the selective removal of water from aqueous organic mixtures. Pervaporation (PV) is a separation process that involves separation of liquid mixtures, in contact with a membrane. With feed solution on one side, permeate is removed as a vapor from the other side (Brian et al. 2011); pervaporation (PV) is a very well-known membrane process for the separation of liquid and vapor mixtures due to its energetic aspects (EP 909209A1 1999; EP 944575A1 1999; EP 880400A1 1998). Pervaporation mostly allows a variety of possible application areas:...

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References

  • Anne J, Robert C, Pierre LND, Bruno C (2002) Industrial state-of-the-art of pervaporation and vapour permeation in the western countries. J Membr Sci 206:87–117

    Article  Google Scholar 

  • Binning RC, Lee RJ, Jennings JF, Martin EC (1961) Separation of liquid mixtures by permeation. Ind Eng Chem 53:45

    Article  Google Scholar 

  • Brian B, Manh H, Zongli X (2011) A review of membrane selection for the dehydration of aqueous ethanol by pervaporation. Chem Eng Process 50:227–235

    Article  CAS  Google Scholar 

  • EP 749351A1 (1996) Device for separating mixtures or for purifying substances by pervaporation

    Google Scholar 

  • EP 765682A1 (1997) Apparatus for separating liquid media with two membranes having their primary sides connected by an intermediate space

    Google Scholar 

  • EP 811420A1 (1997) Composite membrane for selective separating organic substances by pervaporation

    Google Scholar 

  • EP 880400A1 (1998) Composite membrane with a support membrane made in particular of a microporous material

    Google Scholar 

  • EP 909209A1 (1999) Pervaporisation and module for carrying out said process

    Google Scholar 

  • EP 944575A1 (1999) Esterification of fermentation-derived acids via pervaporation

    Google Scholar 

  • Graham T (1866) On the absorption and dialytic separation of gases by colloid septa. Philos Mag J Sci 32:401–420

    Google Scholar 

  • Kataoka T, Tsuru T, Nakao S, Kimura S (1991a) Permeation equations developed for prediction of membrane performance in pervaporation, vapor permeation and reverse osmosis based on the solution± diffusion model. J Chem Eng Jpn 24:326

    Article  CAS  Google Scholar 

  • Kataoka T, Tsuru T, Nakao S, Kimura S (1991b) Membrane transport properties of pervaporation in ethanol±water system using polyacrylonitrile and cellulose acetate membranes. J Chem Eng Jpn 24:334

    Article  CAS  Google Scholar 

  • Kita H, Horii K, Ohtoshi Y, Tanaka K, Okamoto K (1995) Synthesis of a zeolite NaA membranefor pervaporation of water/organic liquid mixtures. J Mater Sci Lett 14:206

    Article  CAS  Google Scholar 

  • Kujawski W (2000) Application of pervaporation and vapor permeation in environmental protection. Pol J Environ Stud 91:13–26

    Google Scholar 

  • Lee CH (1975) Theory of reverse osmosis and some other membrane permeation operations. J Appl Polym Sci 1983

    Google Scholar 

  • Mikihiro N, Takeo Y, Sin-ichi N (1998) Ethanol/water transport through silicalite membranes. J Membr Sci 144:161–171

    Article  Google Scholar 

  • Mulder MHV, Smolders CA (1984) On the mechanism of separation of ethanol/water mixtures by pervaporation I. Calculations of concentration profiles. J Membr Sci 17:289

    Article  CAS  Google Scholar 

  • Paul DR, Paciotti JD (1975) Driving force for hydraulic and pervaporative transport in homogeneous membranes. J Polym Sci 13:1201

    CAS  Google Scholar 

  • Sano T, Yanagishita H, Kiyozumi Y, Mizukami F, Haraya K (1994) Separation of ethanol/water mixture by silicalite membrane on pervaporation. J Membr Sci 95:221

    Article  CAS  Google Scholar 

  • Semenova SI, Ohya H, Soontarapa K (1997) Hydrophilic membranes for pervaporation: an analytical review. Desalination 110:251–286

    Article  CAS  Google Scholar 

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Correspondence to Kew-Ho Lee .

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Lee, KH. (2016). Ethanol–Water Mixtures: Separation by Pervaporation. In: Drioli, E., Giorno, L. (eds) Encyclopedia of Membranes. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-44324-8_1063

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