Abstract
Cellulose-based superabsorbent hydrogels can absorb and retain huge amounts of water or aqueous solutions. They have a wide range of industrial applications including (a) hygienic and bio-related uses (more specifically in disposable diapers); (b) agricultural uses (such as water reserving in soil, soil conditioning, and controlled release of agrochemicals); (c) pharmaceutical dosage forms; (d) separation technology; (e) textile, leather, and paper industries (such as in wastewater treatment); (f) water-swelling rubbers; (g) soft actuators/valves; (h) electrical applications; (i) construction, packaging, and artificial snow; (j) sludge/coal dewatering; and (k) fire extinguishing gels. Many new advanced technologies are evolving by the day to cope with rigorous industrial-scale applications to ensure improved technical feasibilities. This chapter will briefly cover some of the selected aspects of cellulose-based hydrogels and their industrial applications.
References
Cipriano BH, Banik SJ, Sharma R, Rumore D, Hwang W, Briber RM, Raghavan SR (2014) Superabsorbent hydrogels that are robust and highly stretchable. Macromolecules 47(13):4445–4452
Zhang M, Cheng Z, Zhao T, Liu M, Hu, Li J (2014) Synthesis, characterization, and swelling behaviors of salt-sensitive maize bran–poly (acrylic acid) superabsorbent hydrogel. J Agric Food Chem 62(35):8867–8874
Sun JY, Zhao X, Illeperuma WR, Chaudhuri O, Oh KH, Mooney DJ, Vlassak JJ, Suo Z (2012) Highly stretchable and tough hydrogels. Nature 489(7414):133–136
Zohuriaan-Mehr MJ, Kabiri K (2008) Superabsorbent polymer materials: a review. Iran Polym J 17:451–477
Ohmine I, Tanaka T (1982) Salt effects on the phase transition of ionic gels. J Chem Phys 77(11):5725–5729
Chang C, Zhang L (2011) Cellulose-based hydrogels: present status and application prospects. Carbohydr Polym 84(1):40–53
Duan J, Zhang X, Jiang J, Han C, Yang J, Liu L, Lan H, Huang D (2014) The synthesis of a novel cellulose physical gel. J Nanomater. Article ID 312696, 1–7
Meng H, Zhao Y, Duan J, Wang Z, Chen Y, Zhang L (2014) Fast contact of solid-liquid interface created high strength multi-layered cellulose hydrogels with controllable size. ACS Appl Mater Interfaces 6(3):1872–1878
Lee J, Halake KS (2014) Superporous thermo-responsive hydrogels by combination of cellulose fibers and aligned micropores. Carbohydr Polym 105(5):184–192
Sannino A, Demitri C, Madaghiele M (2009) Biodegradable cellulose-based hydrogels: design and applications. Materials 2:353–373
Richter A, Howitz S, Kuckling D, Arndt KF (2004) Influence of volume phase transition phenomena on the behavior of hydrogel-based valves. Sensors Actuators B 99(2–3):451–458
Mao L, Hu Y, Piao Y, Chen X, Xian W, Piao D (2005) Structure and character of artificial muscle model constructed from fibrous hydrogel. Curr Appl Phys 5(5):426–428
Peppas NA (1997) Hydrogels and drug delivery. Curr Opin Colloid Interface Sci 2(5):531–537
Qiu Y, Park K (2001) Environment-sensitive hydrogels for drug delivery. Adv Drug Deliv Rev 53(3):321–339
Wichterle O, Lim D (1960) Hydrophilic gels for biological use. Nature 185(4706):117–118
Chambers DR, Fowler HH, Fujiura Y, Masuda F (1992) Super-absorbent polymer having improved absorbency properties. US Patent 5145906
(a) Ago M, Okajima K, Jakes JE, Park S, Rojas OJ (2012) Lignin-based electrospun nanofibers reinforced with cellulose nanocrystals. Biomacromol 13(3):918–926; (b) Crawford RL (1981) Lignin biodegradation and transformation. Wiley, New York
(a) Harris D, Bulone V, Ding S-Y, DeBolt S (2010) Tools for cellulose analysis in plant cell walls. Plant Physiol 153:420–426; (b) Payen A (1838) Mémoire sur la composition du tissu propre des plantes et du ligneux. Comptes Rendus 7:1052–1056
(a) Moon RJ, Martini A, Nairn J, Simonsenf J, Youngblood, J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40:3941–3994; (b) Dorée C (1947) The methods of cellulose chemistry. Chapman & Hall, London
(a) Ten E, Vermerris W (2013) Functionalized polymers from lignocellulosic biomass: state of the art. Polymers 5:600–642; (b) The Merck Index (1968) Merck & Co, Rahway, 8th edn
(a) Deng L, Young RJ, Kinloch IA, Abdelkader AM, Holmes SM, Rio DAD H-D, Eichhorn SJ (2013) Supercapacitance from cellulose and carbon nanotube nanocomposite fibers. ACS Appl Mater Interf 5:9983–9990; (b) Singh AV, Rahman A, Kumar NVGS, Aditi AS, Galluzzi M, Bovio SS, Barozzi S, Montani E, Parazzoli D (2012) Bio-inspired approaches to design smart fabrics. Mater Des 36:829–839
Visakh PM, Thomas S (2010) Preparation of bionanomaterials and their polymer nanocomposites from waste and biomass. Waste Biomass Valorization 1(1):121–134
Williams GI, Wool RP (2000) Composites from natural fibers and soy oil resins. Appl Compos Mater 7(5–6):421–432
(a) Torres FG, Diaz RM (2004) Morphological characterisation of natural fibre reinforced thermoplastics (NFRTP) processed by extrusion, compression and rotational moulding. Polym Polym Compos 12(8):705–718; (b) Rong MZ, Zhang MQ, Liu Y, Yang GC, Zeng HM (2001) The effect of fiber treatment on the mechanical properties of unidirectional sisal-reinforced epoxy composites. Compos Sci Tech 61:1437–1447
Eichhorn SJ, Dufresne A, Aranguren M, Marcovich NE, Capadona JR, Rowan SJ, Weder C, Thielemans W, Roman M, Renneckar S, Gindl W, Keckes VJ, Yano H, Abe K, Nogi M, Nakagaito AN, Mangalam A, Simonsen J, Benight AS, Bismarck A, Berglund LA, Peijs T (2010) Review: current international research into cellulose nanofibers and nanocomposites. J Mater Sci 45:1–33
Baley C (2002) Analysis of the flax fibres tensile behaviour and analysis of the tensile stiffness increase. Compos Part A 33(7):939–948
Lamy B, Baley C (2000) Stiffness prediction of flax fibers-epoxy composite materials. J Mater Sci Lett 19(11):979–980
Ono T, Sugimoto T, Shinkai S, Sada K (2007) Lipophilic polyelectrolyte gels as super-absorbent polymers for nonpolar organic solvents. Nat Mater 6(6):429–433
Li X, He JZ, Hughes JM, Liu Y-R, Zheng Y-M (2014) Effects of superabsorbent polymers on a soil–wheat (Triticum aestivum L.) system in the field. Appl Soil Ecol 73(2014):58–63
Demitri C, Scalera F, Madaghiele M, Sannino A, Maffezzoli A (2013) Potential of cellulose-based superabsorbent hydrogels as water reservoir in agriculture. Int J Polym Sci 2013:435073, 6 pages
Li J, Jiang M, Wu H, Li Y (2009) Addition of modified bentonites in polymer gel formulation of 2, 4-D for its controlled release in water and soil. J Agric Food Chem 57(7):2868–2874
Li J, Li Y, Dong H (2008) Controlled release of herbicide acetochlor from clay/carboxymethylcellulose gel formulations. J Agric Food Chem 56(4):1336–1342
Lafah WA, Hashim S (2013) Preparation and possible agricultural applications of polymer hydrogel composite as soil conditioner. Adv Mater Res 626:6–10
Bortolin A, Aouada FA, Mattoso LH, Rebeiro C (2013) Nanocomposite PAAm/methyl cellulose/montmorillonite hydrogel: evidence of synergistic effects for the slow release of fertilizers. J Agric Food Chem 61(31):7431–7439
Liu H, Zhang Y, Yao J (2014) Preparation and properties of an eco-friendly superabsorbent based on flax yarn waste for sanitary napkin applications. Fiber Polym 15(1):145–152
Bissah K, Davies P, Hernandez FJV, Paque FW (2014) Absorbent article including an absorbent core layer having a material free zone and a transfer layer arranged below the absorbent core layer. US Patent 8,764,719, pp 7–1
Lavash BW (2014) Sanitary napkin for dynamic body fit. US Patent 8,808,264, pp 8–19
Warren R, Hammons JL, Blevins JM (2014) Skin care compositions on a thin sanitary napkin. US Patent 8,795,716, pp 8–5
Zhou Y, Fu S, Zhang L, Zhan H, Levit MV (2014) Use of carboxylated cellulose nanofibrils-filled magnetic chitosan hydrogel beads as adsorbents for Pb (II). Carbohydr Polym 101:75–82
Kamel S, Hassan EM, El-Sakhawy M (2006) Preparation and application of acrylonitrile-grafted cyanoethyl cellulose for the removal of copper (II) ions. J Appl Polym Sci 100(1):329–334
Rohrbach K, Li Y, Zhu H, Liu Z, Dai J, Andreasen J, Hu L (2014) A cellulose based hydrophilic, oleophobic hydrated filter for water/oil separation. Chem Commun 50(87):13296–13299
Persin Z, Maver U, Pivec T, Vesel A, Mozetič M, Stana-Kleinschek K (2014) Novel cellulose based materials for safe and efficient wound treatment. Carbohydr Polym 100:55–64
He M, Zhao Y, Duan J, Duan J, Wang Z, Chen Y, Zhang L (2014) Fast contact of solid – liquid interface created high strength multi-layered cellulose hydrogels with controllable size. ACS Appl Mater Interfaces 6(3):1872–1878
Yang X, Bakaic E, Hoare T, Cranston ED (2013) Injectable polysaccharide hydrogels reinforced with cellulose nanocrystals: morphology, rheology, degradation, and cytotoxicity. Biomacromolecules 14(12):4447–4455
Eyholzer C, Borges de Couraca A, Duc F, Bourban PE, Tingaut P, Zimmermann T, Månson JAE, Oksman K (2011) Biocomposite hydrogels with carboxymethylated, nanofibrillated cellulose powder for replacement of the nucleus pulposus. Biomacromolecules 12(5):1419–1427
Lin N, Dufresne A (2013) Supramolecular hydrogels from in situ host–guest inclusion between chemically modified cellulose nanocrystals and cyclodextrin. Biomacromolecules 14(3):871–880
Oliveira VA, Veloso TC, Leao VA, dos Santos CG, Botaro VR (2013) Hydrogels of cellulose acetate crosslinked with pyromellitic dianhydride: part I: synthesis and swelling kinetics. Quim Nova 36(1):102–106
Haque A, Morris ER (1993) Thermogelation of methylcellulose. Part I: molecular structures and processes. Carbohydr Polym 22(3):161–173
Joshi SC (2011) Sol-gel behavior of hydroxypropyl methylcellulose (HPMC) in ionic media including drug release. Materials 4(10):1861–1905
Jackson JK, Letchford K, Wasserman BZ, Ye L, Hamad WY, Burt HM (2011) The use of nanocrystalline cellulose for the binding and controlled release of drugs. Int J Nanomedicine 6:321–330
Zohuriaan-Mehr MJ, Omidian H, Doroudiani S, Kabiri K (2010) Advances in non-hygienic applications of superabsorbent hydrogel materials. J Mater Sci 45(21):5711–5735
Ngwuluka NC, Choonara YE, Kumar P, Modi G, du Toit LC, Pillay V (2013) A hybrid methacrylate-sodium carboxymethylcellulose interpolyelectrolyte complex: rheometry and in silico disposition for controlled drug release. Materials 6(10):4284–4308
Sklenář Z, Vitková Z, Herdová P, Horáčková K, Šimunková V (2013) Formulation and release of alaptide from cellulose-based hydrogels. Acta Vet Brno 81(3):301–306
Appel EA, Forster RA, Rowland MJ, Scherman OA (2014) The control of cargo release from physically crosslinked hydrogels by crosslink dynamics. Biomaterials 35(37):9897–9903
Patenaude M, Hoare T (2012) Injectable, mixed natural synthetic polymer hydrogels with modular properties. Biomacromolecules 13(2):369–378
Spagnol C, Rodrigues FHA, Neto AGV (2012) Nanocomposites based on poly (acrylamide-co-acrylate) and cellulose nanowhiskers. Eur Polym J 48(3):454–463
Spagnol C, Rodrigues FHA, Pereira AGB, Fajardo A, Rubira A, Muniz E (2012) Superabsorbent hydrogel composite made of cellulose nanofibrils and chitosan-graft-poly (acrylic acid). Carbohydr Polym 87(3):2038–2045
Wang Y, Shi X, Wang W, Wang A (2013) Synthesis, characterization, and swelling behaviors of a pH responsive CMC-g-poly (AA-co-AMPS) superabsorbent hydrogel. Turk J Chem 37(1):149–159
Hebeish A, Farag S, Sharaf S, Shaheen THI (2014) Thermal responsive hydrogels based on semi interpenetrating network of poly (NIPAm) and cellulose nanowhiskers. Carbohydr Polym 102:159–166
Tang H, Chen H, Duan B, Zhang L (2014) Swelling behaviors of superabsorbent chitin/carboxymethyl cellulose hydrogels. J Mater Sci 49(5):2235–2242
De France KJ, Hoare T, Cranston ED (2017) Review of hydrogels and aerogels containing nanocellulose. Chem Mater 29(11):4609–4631
Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40(7):3941–3994
Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50(24):5438–5466
(a) Plackett DV, Letchford K, Jackson JK, Burt HMA (2014) Review of nanocellulose as a novel vehicle for drug delivery. Nord Pulp Pap Res J 29(1):105–118; (b) Jorfi M, Foster EJ (2015) Recent advances in nanocellulose for biomedical applications. J Appl Polym Sci 132:41719–41737
Bissah K, Davies P, Hernandez FJV, Paques FW (2014) Absorbent article including an absorbent core layer having a material free zone and a transfer layer arranged below the absorbent core layer. US Patent 8,764,719, pp 7–1
Eichhorn SJ, Dufresne A, Aranguren M, Marcovich NE, Capadona JR, Rowan SJ, Weder C, Thielemans W, Roman M, Renneckar S, Gindl W, Veigel S, Keckes J, Yano H, Abe K, Nogi M, Nakagaito AN, Mangalam A, Simonsen J, Benight AS, Bismarck A, Berglund LA, Peijs T (2010) Review: current international research into cellulose nanofibres and nanocomposites. J Mater Sci 45(1):1–33
Koski A, Yim K, Shivkumar S (2004) Effect of molecular weight on fibrous PVA produced by electrospinning. Mater Lett 58:493–497
Mbhele ZH, Salemane MG, van Sittert CGCE, Nedeljkovi JM, Djokovi V, Luyt AS (2003) Fabrication and characterization of silver-polyvinyl alcohol nanocomposites. Chem Mater 15:5019–5024
Li D, Xia Y (2004) Electrospinning of nanofibers: reinventing the wheel? Adv Mater 16:1151–1170
Agarwal S, Wendorff JH, Greiner A (2008) Use of electrospinning technique for biomedical applications. Polymer 49:5603–5621
Li D, Wang Y, Xia Y (2003) Electrospinning of polymeric and ceramic nanofibers as uniaxially aligned arrays. Nano Lett 3(8):1167–1171
Pinto NJ, Johnson JAT, McDiarmid AG, Mueller CH, Theofylaktos N, Robinson DC, Miranda FA (2003) Electrospun polyaniline/polyethylene oxide nanofiber field-effect transistor. Appl Phys Lett 83:4244–4246
Guo Z, Zhang D, Wei S, Wang Z, Karki AB, Li Y, Bernazzani P, Young DP, Gomes J, Cocke D, Ho TC (2010) Effects of iron oxide nanoparticles on polyvinyl alcohol: interfacial layer and bulk nanocomposites thin film. J Nanopart Res 12:2415–2426
Teo WE, Ramakrishna SA (2006) Review on electrospinning design and nanofibre assemblies. Nanotechnology 17:89–106
Doshi J, Reneker DH (1995) Electrospinning process and applications of electrospun fibers. J Electrost 35:151–160
Ramakrishna S, Fujihara K, Teo WE, Yong T, Ma Z, Ramaseshan R (2006) Electrospun nanofibers: solving global issues. Mater Today 9:40–50
Greiner A, Wendorff JH (2007) Electrospinning: a fascinating method for the preparation of ultrathin fibers. Angew Chem Int Ed 46:5670–5703
Zuo W, Zhu M, Yang W, Yu H, Chen Y, Zhang Y (2005) Experimental study on relationship between jet instability and formation of beaded fibers during electrospinning. Polym Eng Sci 45:704–709
(a) Deitzel JM, Kleinmeyer J, Harris D, Beck TNC (2001) The effect of processing variables on the morphology of electrospun nanofibers and textiles. Polymer 42:261–272; (b) Lin T, Wang H, Wang H, Wang X, Brenner MP (2004) The charge effect of cationic surfactants on the elimination of fibre beads in the electrospinning of polystyrene. Nanotechnology 15:1375–1381
Yang Z, Chen S, Hu W, Yin N, Zhang W, Xiang C, Wang H (2012) Flexible luminescent CdSe/bacterial cellulose nanocomposite membranes. Carbohydr Polym 88(1):173–178
Hohman MM, Shin M, Rutledge G, Brenner MP (2001) Electrospinning and electrically forced jets. I. Stability theory. Phys Fluids 13:2201–2220
Hohman MM, Shin M, Rutledge G (2001) Electrospinning and electrically forced jets. II. Appl Phys Fluid 13:2221–2236
Reneker DH, Yarin AL, Fong H, Koombhongse S (2000) Bending instability of electrically charged liquid jets of polymer solutions in electrospinning. J Appl Phys 87:4531–4547
Yarin AL, Koombhongse S, Reneker DH (2001) Bending instability in electrospinning of nanofibers. J Appl Phys 89:3018–3026
Kim GM, Lach R, Michler GH, Poetschke P, Albrecht K (2006) Relationships between phase morphology and deformation mechanisms in polymer nanocomposite nanofibres prepared by an electrospinning process. Nanotechnology 17:963–972
Appell D (2002) Wired for success. Nature 419:553–555
Law M, Sirbuly DJ, Johnson JC, Goldberger J, Saykally RJ, Yang P (2004) Nanoribbon waveguides for subwavelength photonics integration. Science 305:1269–1273
Xia Y, Yang P, Sun Y, Wu Y, Mayers B, Gates B, Yin Y, Kim F, Yan Y (2003) One dimensional nanostructures: synthesis, characterization, and applications. Adv Mater 15:353–389
Huang Y, Duan X, Cui Y, Lauhon L, Kim KH, Lieber C (2001) Logic gates and computation from assembled nanowire building blocks. Science 294:1313–1317
Wang J, Gudiksen M, Duan X, Cui Y, Lieber C (2001) Highly polarized photoluminescence and photodetection from single indium phosphide nanowires. Science 293:1455–1457
Kind H, Yan H, Messer B, Law M, Yang P (2002) Nanowire ultraviolet photodetectors and optical switches. Adv Mater 14:158–160
Law M, Kind H, Messer B, Kim H, Yang P (2002) Photochemical sensing of NO2 with SnO2 nanoribbon nanosensors at room temperature. Angew Chem Int Ed 41:2405–2408
Zhang JP, Chu DY, Wu SL, Ho ST, Bi WG, Tu CW, Tiberio RC (1995) Photonic wire laser. Phys Rev Lett 75:2678–2681
Duan X, Huang Y, Agarwal R, Lieber CM (2003) Single-nanowire electrically driven lasers. Nature 421:241–245
Tong L, Gattass RR, Ashcom JB, He S, Lou J, Shen M, Maxwell I, Mazur E (2003) Subwavelength-diameter silica wires for low-loss optical wave guiding. Nature 426:816–819
Pyayt B, Wiley Y, Xia A, Chen T, Dalton L (2008) Integration of photonic and silver nanowire plasmonic waveguides. Nat Nanotechnol 3:660–665
Brambilla G, Xu F, Feng X (2006) Fabrication of optical fiber nanowires and their optical and mechanical characterization. Electron Lett 42:517–518
Tong L, Lou J, Gattass RR, He S, Chen X, Liu L, Mazur E (2005) Assembly of silica nanowires on silica aerogels for microphotonic devices. Nano Lett 5:259–262
Li Y, Tong L (2008) Mach-Zehnder interferometers assembled with optical microfibers or nanofibers. Opt Lett 33:303–305
Harfenist SA, Cambron SD, Nelson EW, Berry SM, Isham AW, Crain MM, Walsh KM, Keynton RS, Cohn RW (2004) Direct drawing of R. W. suspended filamentary micro- and nanostructures from liquid polymers. Nano Lett 4:1931–1937
Liu H, Edel JB, Bellan LM, Craighead HG (2006) Electrospun polymer nanofibers as subwavelength optical waveguides incorporating quantum dots. Small 2:495–499
Xing XB, Wang YQ, Zhu H, Li BJ (2008) Nanofiber drawing and nanodevice assembly in poly(trimethylene terephthalate). Opt Express 16:10815–10822
Xing XB, Zhu H, Wang YQ, Li BJ (2008) Ultra compact photonic coupling splitters twisted by PTT nanowires. Nano Lett 8:2839–2843
Wang H, Shao Z, Bacher M, Liebner F, Rosenau T (2013) Fluorescent cellulose aerogels containing covalently immobilized (ZnS)x(CuInS2)1-x/ZnS (core/shell) quantum dots. Cellulose 20:3007–3024
Billah SMR, Thompson RL, Kimani SM, Hutchings LH, Wu J (2013) Influences of polyethylene functionalisation on silica nanocomposites. In: IUPAC 10th international conference on advanced polymers via macromolecular engineering, Durham, 18–22 Aug 2013
Hassan ML, Ward AA, Eid MA (2010) Mechanical, optical, and electrical properties of cellulosic semiconductor nanocomposites. J Appl Polym Sci 115:2847–2854
Ruan D, Huang Q, Zhang L (2005) Structure and properties of CdS/regenerated cellulose nanocomposites. Macromol Mater Eng 290(10):1017–1024
Small AC, Johnston JH (2008) Novel hybrid materials of cellulose fibres and doped ZnS nanocrystals. Curr Appl Phys 8(3–4):512–515
Hassan ML, Ali AF (2008) Synthesis of nanostructured cadmium and zinc sulfides in aqueous solutions of hyperbranched polyethyleneimine. J Cryst Growth 310:5252–5258
Wang W, Wang A (2010) Nanocomposite of carboxymethyl cellulose and attapulgite as a novel pH-sensitive superabsorbent: synthesis, characterization and properties. Carbohydr Polym 82:83–91
Nadagouda MN, Varma RS (2007) Synthesis of thermally stable carboxymethyl cellulose/metal biodegradable nanocomposites for potential biological applications. Biomacromolecules 8(9):2762–2767
Chang C, Han K, Zhang L (2011) Structure and properties of cellulose/poly(N- isopropylacrylamide) hydrogels prepared by IPN strategy. Polym Adv Technol 22(9):1329–1334
Dong H, Strawheckera KE, Snydera JF, Orlicki JA, Reiner RS, Rudie AW (2012) Cellulose nanocrystals as a reinforcing material for electrospun poly(methyl methacrylate) fibers: formation, properties and nanomechanical characterization. Carbohydr Polym 87:2488–2495
Domingues RMA, Gomes ME, Reis RL (2014) The potential of cellulose nanocrystals in tissue engineering strategies. Biomacromolecules 15(7):2327–2346
Salas C, Nypelö T, Rodriguez-Abreu C, Carrillo C, Rojas OJ (2014) Nanocellulose properties and applications in colloids and interfaces. Curr Opin Colloid Interface Sci 19(5):383–396
Peresin MS, Vesterinen A-H, Habibi Y, Johansson L-S, Pawlak JJ, Nevzorov AA, Rojas OJ (2014) Crosslinked PVA nanofibers reinforced with cellulose nanocrystals: water interactions and thermomechanical properties. J Appl Polym Sci 131(11):1–12
Abitbol T, Wilson JT, Gray DG (2011) Electrospinning of fluorescent fibers from CdSe/ZnS quantum dots in cellulose triacetate. J Appl Polym Sci 119(2):803–810
Smart CL, Zellner CNC (1971) Cellulose triacetate fibers. In: Bikales NM, Segal L (eds) Cellulose and cellulose derivatives, vol 5. Wiley-Interscience, New York, pp 1151–1167
Iwamoto S, Lee S-H, Endo T (2014) Relationship between aspect ratio and suspension viscosity of wood cellulose nanofibers. Polym J 46:73–76
Steinmeier H (2004) 3. Acetate manufacturing, process and technology, 3.1 chemistry of cellulose acetylation. In: Rustemeyer P (ed) Cellulose acetates: properties and applications. Wiley-VCH, Heidelberg, pp 39–60
Zugenmaier P (2004) Characteristics of cellulose acetates. In: Rustemeyer P (ed) Cellulose acetates: properties and applications. Wiley-VCH, Heidelberg, pp 81–166
Hiatt GD, Rebel WJB (1971) Esters. In: Bikales NM, Segal L (eds) Cellulose and cellulose derivatives, vol V. Wiley Interscience, New York, pp 741–784
Abitbol T, Gray DG (2007) CdSe/ZnS quantum dots embedded in cellulose triacetate films with hydrophilic surfaces. Chem Mater 19(17):4270–4276
Abitbol T, Gray DG (2009) Incorporation into paper of cellulose triacetate films containing semiconductor nanoparticles. Cellulose 16(2):319–326
Taajamaa L, Kontturi E, Lainea J, Rojas OJ (2012) Bicomponent fibre mats with adhesive ultra-hydrophobicity tailored with cellulose derivatives. J Mater Chem 22:12072–12082
Han SO, Son WK, Youk JH, Lee TS, Park WH (2005) Ultrafine porous fibers electrospun from cellulose triacetate. Mater Lett 59(24–25):2998–3001
Chu YC, Wang CC, Chen CY (2005) Synthesis of luminescent and rodlike CdS nanocrystals dispersed in polymer templates. Nanotechnology 16:58
Zhao X, Ding X, Deng Z, Zheng Z, Peng Y, Tian C, Long X (2006) A kind of smart gold nanoparticle–hydrogel composite with tunable thermo-switchable electrical properties. New J Chem 30:915–920
Shimmin RG, Vajtai R, Siegel RW, Braun PV (2007) Room-temperature assembly of germanium photonic crystals through colloidal crystal templating. Chem Mater 19:2102–2107
Park JJ, Prabhakaran P, Jang KK, Lee YG, Lee J, Lee KH, Hur J, Kim JM, Cho N, Son Y, Yang DY, Lee KS (2010) Photopatternable quantum dots forming quasi-ordered arrays. Nano Lett 10(7):2310–2317
Kabiri K, Omidian H, Zohuriaan-Mehr MJ, Doroudiani S (2011) Superabsorbent hydrogel composites and nanocomposites: a review. Polym Compos 32(2):277–289
Billah SMR, Cameron NR, Przyborski SA, Humphrey EH, Tams DH (2013) Photochromic dye-doped electrospun nanofibre-based scaffolds for cell culture, security and optical data storage applications. In: IUPAC 10th international conference on advanced polymers via macromolecular engineering, Durham, 18–22 Aug 2013
Cha R, He Z, Ni Y (2012) Preparation and characterization of thermal/pH-sensitive hydrogel from carboxylated nanocrystalline cellulose. Carbohydr Polym 88:713–718
Gorgieva S, Kokol V (2011) Synthesis and application of new temperature-responsive hydrogels based on carboxymethyl and hydroxyethyl cellulose derivatives for the functional finishing of cotton knitwear. Carbohydr Polym 85:664–673
Sannino A, Pappadà S, Giotta L, Valli L, Maffezzoli A (2007) Spin coating cellulose derivatives on quartz crystal microbalance plates to obtain hydrogel-based fast sensors and actuators. J Appl Polym Sci 106:3040–3050
Chang C, He M, Zhou J, Zhang L (2011) Swelling behaviors of pH- and salt- responsive cellulose-based hydrogels. Macromolecules 44:1642–1648
Chang C, Duan B, Cai J, Zhang L (2010) Superabsorbent hydrogels based on cellulose for smart swelling and controllable delivery. Eur Polym J 46:92–100
Pourjavadi A, Barzegar S, Mahdavinia GR (2006) MBA-crosslinked Na-Alg/CMC as a smart full-polysaccharide superabsorbent hydrogels. Carbohydr Polym 66:386–395
Fang A, Cathala B (2011) Smart swelling biopolymer microparticles by a microfluidic approach, synthesis, in situ encapsulation and controlled release. Colloids Surf B: Biointerfaces 82:81–86
Salmawi KME, Ibrahim SM (2011) Characterization of superabsorbent carboxymethyl cellulose/clay hydrogel prepared by electron beam irradiation. Macromol Res 19:1029–1034
Liao Q, Shao Q, Qiu G, Lu X (2012) Methacrylic acid-triggered phase transition behavior of thermosensitive hydroxypropylcellulose. Carbohydr Polym 89:1301–1304
Chen Y, Ding D, Mao Z, He Y, Hu Y, Wu W, Jiang X (2008) Synthesis of hydroxypropylcellulose-poly(acrylic acid) particles with semi-interpenetrating polymer network structure. Biomacromolecules 9:2609–2614
Demirel GB, Caykara T, Demiray M, Guru M (2009) Effect of pore-forming agent type on swelling properties of macroporous poly(N-[3-(dimethylaminopropyl)]- methacrylamide-co-acrylamide) hydrogels. J Macromol Sci A Pure Appl Chem 46:58–64
Chauhan GS, Mahajan S (2002) Structural aspects and nature of swelling medium as equilibrium swelling determinants of acrylamide and cellulosic based smart hydrogels. J Appl Polym Sci 85:1161–1169
Ma L, Liu R, Tan J, Wang D, Jin X, Kang H, Wu M, Huang Y (2010) Self- assembly and dual-stimuli sensitivities of hydroxypropylcellulose-graft-poly(N,N-dimethyl amino ethyl methacrylate) copolymers in aqueous solution. Langmuir 26:8697–8703
Ma L, Kang H, Liu R, Huang Y (2010) Smart assembly behaviours of hydroxypropylcellulose-graftpoly(4-vinyl pyridine) copolymers in aqueous solution by thermo and pH stimuli. Langmuir 26:18519–18525
Xu FJ, Zhu Y, Liu FS, Nie J, Ma J, Yang WT (2010) Comb-shaped conjugates comprising hydroxypropyl cellulose backbones and low-molecular-weight poly(N- isopropylacrylamide) side chains for smart hydrogels, synthesis, characterization, and biomedical applications. Bioconjug Chem 21:456–464
Marsano E, Bianchi E, Viscardi A (2004) Stimuli responsive gels based on interpenetrating network of hydroxypropylcellulose and poly(N-isopropylacrylamide). Polymer 45:157–163
Çaykara T, Şengül G, Birlik G (2006) Preparation and swelling properties of temperature-sensitive semi-interpenetrating polymer networks composed of poly[(N-tert-butylacrylamide)-co-acrylamide] and hydroxypropyl cellulose. Macromol Mater Eng 291:1044–1051
Tan J, Kang H, Liu R, Wang D, Jin X, Li Q, Huang Y (2011) Dual-stimuli sensitive nanogels fabricated by self-association of thiolated hydroxypropyl cellulose. Polym Chem 2:672–678
Wan S, Jiang M, Zhang G (2007) Dual temperature- and pH-dependent self-assembly of cellulose-based copolymer with a pair of complementary grafts. Macromolecules 40:5552–5558
Peng Z, Chen F (2010) Synthesis and properties of temperature-sensitive hydrogel based on hydroxyethyl cellulose. Int J Polym Mater 59:450–461
Kim B, Kang H, Kim J (2002) Thermo-sensitive microparticles of PNIPAM-grafted ethylcellulose by spray-drying method. J Microencapsul 19:661–669
Yuan W, Zhang J, Zou H, Shen T, Ren J (2012) Amphiphilic ethyl cellulose brush polymers with mono and dual side chains, facile synthesis, self-assembly, and tunable temperature-pH responsivities. Polymer 53:956–966
Estrada R, Rodríguez R, Castaño VM (2010) Smart polymeric membranes, pH- induced non-linear changes in pore size. Appl Phys A Mater Sci Process 99:723–728
Cao S, Hu B, Liu H (2009) Synthesis of pH-responsive crosslinked poly[styrene-co- (maleic sodium anhydride)] and cellulose composite hydrogel nanofibers by electrospinning. Polym Int 58:545–551
Liebert T (2010) Cellulose solvents – remarkable history, bright future. In: Liebert TF, Heinze TJ, Edgar KJ (eds) Cellulose solvents, for analysis, shaping and chemical modification. American Chemical Society, Washington, DC, pp 3–54
Sui X, Yuan J, Zhou M, Zhang J, Yang H, Yuan W, Wei Y, Pan C (2008) Synthesis of cellulose-graft-poly(N,N-dimethylamino-2-ethyl methacrylate) copolymers via homogeneous ATRP and their aggregates in aqueous media. Biomacromolecules 9:2615–2620
Wondraczek H, Pfeifer A, Heinze T (2012) Water soluble photoactive cellulose derivatives, synthesis and characterization of mixed 2-[(4-methyl-2-oxo-2H-chromen-7-yl) oxy] acetic acid-(3-carboxypropyl) trimethylammonium chloride esters of cellulose. Cellulose 19:1327–1335
Cai Z, Kim J (2008) Characteristics and performance of electroactive paper actuator made with cellulose/polyurethane semi-interpenetrating polymer networks. J Appl Polym Sci 109:3689–3695
Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals, chemistry, self- assembly, and applications. Chem Rev 110(6):3479–3500
Zoppe JO, Habibi Y, Rojas OJ, Venditti RA, Johansson L-S, Efimenko K, Österberg M, Laine J (2010) Poly(N-isopropylacrylamide) brushes grafted from cellulose nanocrystals via surface-initiated single-electron transfer living radical polymerization. Biomacromolecules 11:2683–2691
Azzam F, Heux L, Putaux J-L, Jean B (2010) Preparation by grafting onto, characterization, and properties of thermally responsive polymer-decorated cellulose nanocrystals. Biomacromolecules 11:3652–3659
Way AE, Hsu L, Shanmuganathan K, Weder C, Rowan SJ (2012) pH- responsive cellulose nanocrystal gels and nanocomposites. ACS Macro Lett 1:1001–1006
Morandi G, Thielemans W (2012) Synthesis of cellulose nanocrystals bearing photocleavable grafts by ATRP. Polym Chem 3:1402–1407
Pan K, Zhang X, Ren R, Cao B (2010) Double stimuli-responsive membranes grafted with block copolymer by ATRP method. J Membr Sci 356:133–137
Qiu X, Ren X, Hu S (2012) Fabrication of dual-responsive cellulose-based membrane via simplified surface-initiated ATRP. Carbohydr Polym 92:1887–1895
Gorey C, Escobar IC (2011) N-isopropylacrylamide (NIPAAM) modified cellulose acetate ultrafiltration membranes. J Membr Sci 383:272–279
Kubota H, Suka IG, Kuroda S-I, Kondo T (2001) Introduction of stimuli- responsive polymers into regenerated cellulose film by means of photo-grafting. Eur Polym J 37:1367–1372
Gorey C, Escobar IC, Gruden C, Coleman M, Mileyeva-Biebesheimer O (2008) Development of smart membrane filters for microbial sensing. Sep Sci Technol 43:4056–4074
Isaad J, Achari AE (2011) Colorimetric sensing of cyanide anions in aqueous media based on functional surface modification of natural cellulose materials. Tetrahedron 67:4939–4947
Karlsson JO, Andersson M, Berntsson P, Chihani T, Gatenholm P (1998) Swelling behavior of stimuli-responsive cellulose fibers. Polymer 39:3589–3596
Peng J, Liu Q, Xu Z, Masliyah J (2012) Synthesis of interfacially active and magnetically responsive nanoparticles for multiphase separation applications. Adv Funct Mater 22:1732–1740
Gaharwar AK, Wong JE, Müller-Schulte D, Bahadur D, Richtering W (2009) Magnetic nanoparticles encapsulated within a thermoresponsive polymer. J Nanosci Nanotechnol 9:5355–5361
Siqueira G, Bras J, Dufresne A (2010) Cellulosic bionanocomposites: a review of preparation, properties and applications properties and applications. Polymers 2:728–765
Hubbe MA, Rojas OJ, Lucia LA, Sain M (2008) Cellulosic nanocomposites: a review. Bioresources 3:929–980
Khalil HPSA, Bhat AH, Yusra AFI (2012) Green composites from sustainable cellulose nanofibrils: a review. Carbohydr Polym 87:963–979
Yu L, Dean K, Li L (2006) Polymer blends and composites from renewable resources. Prog Polym Sci 31:576–602
Zhang K, Wu XY (2004) Temperature and pH-responsive polymeric composite membranes for controlled delivery of proteins and peptides. Biomaterials 25:5281–5291
Zhang K, Wu XY (2002) Modulated insulin permeation across a glucose-sensitive polymeric composite membrane. J Control Release 80:169–178
Regmi BP, Monk J, El-Zahab B, Das S, Hung FR, Hayes DJ, Warner IM (2012) A novel composite film for detection and molecular weight determination of organic vapors. J Mater Chem 22:13732–13741
Lin Y-Y, Chen K-S, Lin S-Y (1996) Development and investigation of a thermo- responsive cholesteryl oleyl carbonate-embedded membrane. J Control Release 41:163–170
Lin S-Y, Lin H-L, Li M-J (2003) Reproducibility of temperature response and long-term stability of thermo-responsive membrane prepared by adsorption of binary liquid crystals. J Membr Sci 225:135–143
Atyabi F, Khodaverdi E, Dinarvand R (2007) Temperature modulated drug permeation through liquid crystal embedded cellulose membranes. Int J Pharm 339:213–221
Suedee R, Jantarat C, Lindner W, Viernstein H, Songkro S, Srichana T (2010) Development of a pH-responsive drug delivery system for enantioselective-controlled delivery of racemic drugs. J Control Release 142:122–131
Waich K, Mayr T, Klimant I (2008) Fluorescence sensors for trace monitoring of dissolved ammonia. Talanta 77:66–72
Mahadeva SK, Yun S, Kim J (2011) Flexible humidity and temperature sensor based on cellulose-polypyrrole nanocomposite. Sens Actuators A Phys 166:194–199
Ichinose I, Kunitake T (1999) Polymerization-induced adsorption: a preparative method of ultrathin polymer films. Adv Mater 11:413–415
Csoka L, Hoeger IC, Rojas OJ, Peszlen I, Pawlak JJ, Peralta PN (2012) Piezoelectric effect of cellulose nanocrystals thin films. ACS Macro Lett 1:867–870
Kim J, Yun S, Mahadeva SK, Yun K, Yang SY, Maniruzzaman M (2010) Paper actuators made with cellulose and hybrid materials. Sensors 10:1473–1485
Pandey JK, Takagi H, Nakagaito AN, Saini DR, Ahn S-H (2012) An overview on the cellulose based conducting composites. Compos Part B Eng 43:2822–2826
Kim J, Wang N, Chen Y, Lee S-K, Yun G-Y (2007) Electroactive-paper actuator made with cellulose/NaOH/urea and sodium alginate. Cellulose 14:217–223
Kim J, Yun S, Ounaies Z (2006) Discovery of cellulose as a smart material. Macromolecules 39:4202–4206
Li J, Vadahanambi S, Kee C-D, Oh I-K (2011) Electrospun fullerenol-cellulose biocompatible actuators. Biomacromolecules 12:2048–2054
Kunchornsup W, Sirivat A (2012) Physically cross-linked cellulosic gel via 1-butyl-3-methylimidazolium chloride ionic liquid and its electromechanical responses. Sens Actuators A Phys 175:155–164
Kacmaz S, Ertekin K, Suslu A, Ergun Y, Celik E, Cocen U (2012) Sub- nanomolar sensing of ionic mercury with polymeric electrospun nanofibers. Mater Chem Phys 133:547–552
Ongun MZ, Ertekin K, Gocmenturk M, Ergun Y, Suslu A (2012) Copper ion sensing with fluorescent electrospun nanofibers. Spectrochim Acta A Mol Biomol Spectrosc 90:177–185
Schueren LVD, Clerck KD, Brancatelli G, Rosace G, Damme EV, Vos WD (2012) Novel cellulose and polyamide halochromic textile sensors based on the encapsulation of methyl red into a sol-gel matrix. Sensors Actuators B Chem 162:27–34
Posey-Dowty JD, Watterson TL, Wilson AK, Edgar KJ, Shelton MC, Lingerfelt LR Jr (2007) Zero-order release formulations using a novel cellulose ester. Cellulose 14:73–83
Karewicz A, Zasada K, Szczubiałka K, Zapotoczny S, Lach R, Nowakowska M (2010) Smart alginate–hydroxypropylcellulose microbeads for controlled release of heparin. Int J Pharm 385:163–169
Tripathi GK, Singh S (2012) Formulation and in vitro evaluation of pH trigger polymeric blended buoyant beads of clarithromycin. Int J Pharm Tech Res 4:5–14
Tripathi G, Singh S (2010) Formulation and in vitro evaluation of pH sensitive oil entrapped polymeric blended gellan gum buoyant beads of clarithromycin. DARU J Pharm Sci 18:247–253
Ichikawa H, Fukumori Y (2000) A novel positively thermosensitive controlled- release microcapsule with membrane of nano-sized poly(nisopropylacrylamide) gel dispersed in ethylcellulose matrix. J Control Release 63:107–119
Kettunen M, Silvennoinen RJ, Houbenov N, Nykänen A, Ruokolainen J, Sainio J, Pore V, Kemell M, Ankerfors M, Lindström T, Ritala M, Ras RHA, Ikkala O (2011) Photoswitchable superabsorbency based on nanocellulose aerogels. Adv Funct Mater 21:510–517
Pääkk M, Ankerfors M, Kosonen H, Nykänen A, Ahola S, Österberg M, Ruokolainen J, Laine J, Larsson PT, Ikkala O, Linstrom T (2007) Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. Biomacromolecules 8:1934–1941
Pääkkö M, Vapaavuori J, Silvennoinen R, Kosonen H, Ankerfors M, Lindström T, Berglund LA, Ikkala O (2008) Long and entangled native cellulose I nanofibers allow flexible aerogels and hierarchically porous templates for functionalities. Soft Matter 4:2492–2499
Katepetch C, Rujiravanit R (2011) Synthesis of magnetic nanoparticle into bacterial cellulose matrix by ammonia gas-enhancing in situ co-precipitation method. Carbohydr Polym 86:162–170
Klemm D, Heublein B, Fink H-P, Bohn A (2005) Cellulose, fascinating biopolymer and sustainable raw material. Angew Chem Int Ed 44:3358–3393
Shanmuganathan K, Capadona JR, Rowan SJ, Weder C (2010) Biomimetic mechanically adaptive nanocomposites. Prog Polym Sci 35:212–222
Lendlein A, Kelch S (2002) Shape-memory polymers. Angew Chem Int Ed 41:2034–2057
Behl M, Razzaq MY, Lendlein A (2010) Multifunctional shape-memory polymers. Adv Mater 22:3388–3410
Huang WM, Yang B, Zhao Y, Ding Z (2010) Thermo-moisture responsive polyurethane shape-memory polymer and composites: a review. J Mater Chem 20:3367–3381
Zhu Y, Hu J, Luo H, Young RJ, Deng L, Zhang S, Fan Y, Ye G (2012) Rapidly switchable water-sensitive shape-memory cellulose/elastomer nano-composites. Soft Matter 8:2509–2517
Han J, Zhu Y, Hu J, Luo H, Yeung L-Y, Li W, Meng Q, Ye G, Zhang S, Fan Y (2012) Morphology, reversible phase crystallization, and thermal sensitive shape memory effect of cellulose whisker/SMPU nanocomposites. J Appl Polym Sci 123:749–762
Luo H, Hu J, Zhu Y (2011) Polymeric shape memory nanocomposites with heterogeneous twin switches. Macromol Chem Phys 212:1981–1986
Luo H, Hu J, Zhu Y (2011) Tunable shape recovery of polymeric nano-composites. Mater Lett 65:3583–3585
Auad ML, Contos VS, Nutt S, Aranguren MI, Marcovich NE (2008) Characterization of nanocellulose-reinforced shape memory polyurethanes. Polym Int 57:651–659
Auad ML, Richardson T, Orts WJ, Medeiros E, Mattoso LHC, Mosiewicki MA, Marcovich NE, Aranguren MI (2011) Polyaniline-modified cellulose nanofibrils as reinforcement of a smart polyurethane. Polym Int 60:743–750
Mendez J, Annamalai PK, Eichhorn SJ, Rusli R, Rowan SJ, Foster EJ, Weder C (2011) Bioinspired mechanically adaptive polymer nanocomposites with water- activated shape-memory effect. Macromolecules 44:6827–6835
Capadona JR, Shanmuganathan K, Tyler DJ, Rowan SJ, Weder C (2008) Stimuli-responsive polymer nanocomposites inspired by the sea cucumber dermis. Science 319:1370–1374
Shanmuganathan K, Capadona JR, Rowan SJ, Weder C (2010) Bio-inspired mechanically-adaptive nanocomposites derived from cotton cellulose whiskers. J Mater Chem 20:180–186
Shanmuganathan K, Capadona JR, Rowan SJ, Weder C (2010) Stimuli- responsive mechanically adaptive polymer nanocomposites. ACS Appl Mater Interfaces 2:165–174
Dagnon KL, Shanmuganathan K, Weder C, Rowan SJ (2012) Water-triggered modulus changes of cellulose nanofiber nanocomposites with hydrophobic polymer matrices. Macromolecules 45:4707–4715
Spagnol C, Rodrigues FHA, Pereira AGB, Fajardo AR, Rubira AF, Muniz EC (2012) Superabsorbent hydrogel composite made of cellulose nanofibrils and chitosan- graft-poly(acrylic acid). Carbohydr Polym 87:2038–2045
Edgar KJ, Buchanan CM, Debenham JS, Rundquist PA, Seiler BD, Shelton MC, Tindall D (2001) Advances in cellulose ester performance and application. Prog Polym Sci 26:1605–1688
Kamel S, Ali N, Jahangir K, Shah SM, El-Gendy AA (2008) Pharmaceutical significance of cellulose: a review. Express Polym Lett 2:758–778
Edgar KJ (2007) Cellulose esters in drug delivery. Cellulose 14:49–64
Murtaza G (2012) Ethylcellulose microparticles: a review. Acta Pol Pharm 69:11–22
Rogers TL, Wallick D (2012) Reviewing the use of ethylcellulose, methylcellulose and hypromellose in microencapsulation. Part 1, materials used to formulate microcapsules. Drug Dev Ind Pharm 38:129–157
Rogers TL, Wallick D (2011) Reviewing the use of ethylcellulose, methylcellulose and hypromellose in microencapsulation. Part 2, techniques used to make microcapsules. Drug Dev Ind Pharm 37:1259–1271
Rogers TL, Wallick D (2012) Reviewing the use of ethylcellulose, methylcellulose and hypromellose in microencapsulation. Part 3: applications for microcapsules. Drug Dev Ind Pharm 38:521–539
Lecomte F, Siepmann J, Walther M, MacRae RJ, Bodmeier R (2005) pH- sensitive polymer blends used as coating materials to control drug release from spherical beads, importance of the type of core. Biomacromolecules 6:2074–2083
Josephine LJJ, Yathish M, Wilson B, Premakumari KB (2012) Formulation and evaluation of microparticles containing curcumin for colorectal cancer. J Drug Deliv Ther 2:125–128
Wang J, Wu F-Q, Shi K-H, Wang X-H, Sun P-P (2004) Humidity sensitivity of composite material of lanthanum ferrite/polymer quaternary acrylic resin. Sensors Actuators B Chem 99:586–591
Wang X, Guo Y, Li D, Chen H, Sun R-C (2012) Fluorescent amphiphilic cellulose nanoaggregates for sensing trace explosives in aqueous solution. Chem Commun 48:5569–5571
Arias JL, López-Viota M, Delgado ÁV, Ruiz MA (2010) Iron/ethylcellulose (core/shell) nanoplatform loaded with 5-fluorouracil for cancer targeting. Colloids Surf B: Biointerfaces 77:111–116
Cheng R, Feng F, Meng F, Deng C, Feijen J, Zhong Z (2011) Glutathione- responsive nano-vehicles as a promising platform for targeted intracellular drug and gene delivery. J Control Release 152:2–12
Delcea M, Moehwald H, Skirtach AG (2011) Stimuli-responsive LbL capsules and nanoshells for drug delivery. Adv Drug Deliv Rev 63:730–747
Wohl BM, Engbersen JFJ (2012) Responsive layer-by-layer materials for drug delivery. J Control Release 158:2–14
Manchun S, Dass CR, Sriamornsak P (2012) Targeted therapy for cancer using pH-responsive nanocarrier systems. Life Sci 90:381–387
Fleige E, Quadir MA, Haag R (2012) Stimuli-responsive polymeric nanocarriers for the controlled transport of active compounds. Concepts and applications. Adv Drug Deliv Rev 64:866–884
Sanna R, Sanna D, Alzari V, Nuvoli D, Scognamillo S, Piccinini M, Lazzari M, Gioffredi E, Malucelli G, Mariani A (2012) Synthesis and characterization of graphene-containing thermoresponsive nanocomposite hydrogels of poly (N vinlcaprolactam) prepared by frontal polymerization. J Polym Sci A Polym Chem 50:4110–4118
Zhang J, Li X, Li X (2012) Stimuli-triggered structural engineering of synthetic and biological polymeric assemblies. Prog Polym Sci 37:1130–1176
Felber AE, Dufresne M-H, Leroux J-C (2012) pH-sensitive vesicles, polymeric micelles, and nanospheres prepared with polycarboxylates. Adv Drug Deliv Rev 64:979–992
Zhang Q, Ko NR, Oh JK (2012) Recent advances in stimuli-responsive degradable block copolymer micelles, synthesis and controlled drug delivery applications. Chem Commun 48:7542–7552
Prabaharan M, Mano JF (2006) Stimuli-responsive hydrogels based on polysaccharides incorporated with thermo-responsive polymers as novel biomaterials. Macromol Biosci 6:991–1008
Estrada RF, Rodríguez R, Castaño VM (2003) Smart polymeric membranes with adjustable pore size. Int J Polym Mater 52:833–843
Cabrera RQ, Meersman F, McMillan PF, Dmitriev V (2011) Nanomechanical and structural properties of native cellulose under compressive stress. Biomacromolecules 12:2178–2183
Lima MMDS, Borsali R (2004) Rodlike cellulose microcrystals, structure, properties, and applications. Macromol Rapid Commun 25:771–787
Kim J, Seo YB (2002) Electro-active paper actuators. Smart Mater Struct 11:355–360
Mahadeva SK, Yun K, Kim J, Kim J-H (2011) Highly durable, biomimetic electro-active paper actuator based on cellulose polypyrrole-ionic liquid (CPIL) nanocomposite. J Nanosci Nanotechnol 11:270–274
Yun G-Y, Kim J, Kim J-H, Kim S-Y (2010) Fabrication and testing of cellulose EAPap actuators for haptic application. Sens Actuators A Phys A164:68–73
Gao Y, Kuang Y, Guo Z-F, Guo Z, Krauss IJ, Xu B (2009) Enzyme-instructed molecular self-assembly confers nanofibers and a supramolecular hydrogel of taxol derivative. J Am Chem Soc 131:13576–13577
Imran AB, Seki T, Takeoka Y (2010) Recent advances in hydrogels in terms of fast stimuli responsiveness and superior mechanical performance. Polym J 42:839–851
Yetisen AK, Butt H, Volpatti LR, Pavlichenko I, Humar M, Kwok SSK, Koo K, Kim KS, Naydenova I, Khademhosseini A, Hahn SK, Yun SH (2016) Photonic hydrogel sensors. Biotechnol Adv 34(3):250–271
Stuart MAC, Huck WT, Genzer J, Müller M, Ober C, Stamm M, Sukhorukow GB, Szleifer I, Tsukruk VV, Urban M, Winnik F, Zauscher S, Luzinov I, Minko S (2010) Emerging applications of stimuli-responsive polymer materials. Nat Mater 9:101–113
Buenger D, Topuz F, Groll J (2012) Hydrogels in sensing applications. Prog Polym Sci 37:1678–1719
Zhao Y, Wostyn K, de Schaetzen G, Schoonheydt RA (2003) The fabrication of photonic band gap materials with a two-dimensional defect. Appl Phys Lett 82:3764–3766
Zhao Y, Zhao X, Gu Z (2010) Photonic crystals in bioassays. Adv Funct Mater 20:2970–2988
Zhao Y, Zhao X, Tang B, Xu W, Gu Z (2010) Rapid and sensitive biomolecular screening with encoded macroporous hydrogel photonic beads. Langmuir 26:6111–6114
Zhao Y, Zhao X, Tang B, Xu W, Li J, Hu J, Gu Z (2010) Quantum-dot-tagged bioresponsive hydrogel suspension array for multiplex label-free DNA detection. Adv Funct Mater 20:976–982
Zhao Y, Xie Z, Gu H, Zhu C, Gu Z (2012) Bio-inspired variable structural color materials. Chem Soc Rev 41:3297–3317
Zhao Y, Shang L, Cheng Y, Gu Z (2014) Spherical colloidal photonic crystals. Acc Chem Res 47:3632–3642
Zhao Q, Yetisen AK, Anthony CJ, Fowler WR, Yun SH, Butt H (2015) Printable ink holograms. Appl Phys Lett 107:041115
Zhao Q, Yetisen AK, Sabouri A, Yun SH, Butt H (2015) Printable nanophotonic devices via holographic laser ablation. ACS Nano 9:9062–9069
Gerlach G, Arndt K-F (2009) Hydrogel sensors and actuators: engineering and technology. Springer Science & Business Media, Heidelberg
Naydenova I, Jallapuram R, Toal V, Martin S (2008) A visual indication of environmental humidity using a color changing hologram recorded in a self-developing photopolymer. Appl Phys Lett 92:031109
Naydenova I, Jallapuram R, Toal V, Martin S (2009) Characterisation of the humidity and temperature responses of a reflection hologram recorded in acrylamide-based photopolymer. Sensors Actuators B139:35–38
Naydenova I, Jallapuram R, Martin S, Toal V (2011) Holographic humidity sensors. In: Okada CT (ed) Humidity sensors: types, nanomaterials and environmental monitoring. Nova Science Publishers, Hauppauge, pp 117–142
Yetisen AK (2015) Fundamentals of holographic sensing. Springer International Publishing, Cham, pp 27–51
Yetisen AK (2015) Holographic glucose sensors. Holographic sensors. Springer International Publishing, Cham, pp 101–134
Yetisen AK (2015) Holographic metal ion sensors. Holographic sensors. Springer International Publishing, Cham, pp 85–99
Yetisen AK (2015) Holographic pH sensors. Holographic sensors. Springer International Publishing, Cham, pp 53–83
Yetisen AK (2015) Mobile medical applications. Holographic sensors. Springer International Publishing, Cham, pp 135–148
Yetisen AK (2015) Point-of-care diagnostics. Holographic sensors. Springer International Publishing, Cham, pp 1–25
Yetisen AK (2015) The prospects for holographic sensors. Holographic sensors. Springer International Publishing, Cham, pp 149–162
Yetisen AK, Volpatti LR (2014) Patent protection and licensing in microfluidics. Lab Chip 14:2217–2225
Yetisen AK, Akram MS, Lowe CR (2013) Paper-based microfluidic point-of-care diagnostic devices. Lab Chip 13:2210–2251
Tian T, Li X, Cui J, Li J, Lan Y, Wang C, Zhang M, Wang H, Li G (2014) Highly sensitive assay for acetylcholinesterase activity and inhibition based on a specifically reactive photonic nanostructure. ACS Appl Mater Interfaces 6:15456–15465
Cai Z, Liu YJ, Lu X, Teng J (2013) In situ “doping” inverse silica opals with size controllable gold nanoparticles for refractive index sensing. J Phys Chem C 117:9440–9445
Cai Z, Zhang J-T, Xue F, Hong Z, Punihaole D, Asher SA (2014) 2D photonic crystal protein hydrogel coulometer for sensing serum albumin ligand binding. Anal Chem 86:4840–4847
Cai Z, Smith NL, Zhang J-T, Asher SA (2015) Two-dimensional photonic crystal chemical and biomolecular sensors. Anal Chem 87:5013–5025
Baruah U, Chowdhury D (2016) Functionalized graphene oxide quantum dot–PVA hydrogel: a colorimetric sensor for Fe2+, Co2+ and Cu2+ ions. Nanotechnology 27(14):145501
El-Salmawi KM (2007) Application of polyvinyl alcohol (PVA)/carboxymethyl cellulose (CMC) hydrogel produced by conventional crosslinking or by freezing and thawing. J Macromol Sci Part A Pure Appl Chem 44(6):619–624
George J, Sabapathi SN (2015) Cellulose nanocrystals: synthesis, functional properties, and applications. Nanotechnol Sci Appl 8:45–54
Xie X, Ma D, Zhang L-M (2015) Fabrication and properties of a supramolecular hybrid hydrogel doped with CdTe quantum dots. RSC Adv 5:58746–58754
Chang C, Peng J, Zhang L, Pang DW (2009) Strongly fluorescent hydrogels with quantum dots embedded in cellulose matrices. J Mater Chem 9:7771–7776
Palomero CR, Martínez SB, Soriano ML, Valcárcel M (2017) Fluorescent nanocellulosic hydrogels based on graphene quantum dots for sensing laccase. Anal Chim Acta 974(29):93–99
Palomero CR, Soriano ML, Martínez SB, Valcárcel M (2017) Photoluminescent sensing hydrogel platform based on the combination of nanocellulose and S,N-codoped graphene quantum dots. Sensors Actuators B Chem 245:946–953
Thoniyot P, Tan MJ, Karim AA, Young D J, Loh X J (2015) Nanoparticle–Hydrogel Composites: Concept, Design, and Applications of These Promising, Multi-Functional Materials, Adv. Sci. 2(1400010):1–13
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Billah, S.M.R., Mondal, M.I.H., Somoal, S.H., Pervez, M.N. (2018). Cellulose-Based Hydrogel for Industrial Applications. In: Mondal, M. (eds) Cellulose-Based Superabsorbent Hydrogels. Polymers and Polymeric Composites: A Reference Series. Springer, Cham. https://doi.org/10.1007/978-3-319-76573-0_63-1
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