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Mesopore Diffusion Within Porous Silicon

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Book cover Handbook of Porous Silicon

Abstract

In applications such as sensing and drug delivery, the performance of mesoporous silicon (PSi) may be controlled by the rate of diffusive propagation of the confined molecules. The pulsed field gradient technique of nuclear magnetic resonance provides the most direct access to molecular diffusion. The different factors determining the diffusivities in PSi are the focus of this updated review. In particular, diffusivities in liquid state are shown to be most strongly affected by mesoscale disorder. Atomistic disorder is shown to control surface diffusion in applications in which PSi is brought into contact with gas phases at low vapor pressures. Correlations between the compositions of phases coexisting within the pore space, namely, liquid and gaseous, and liquid and solid ones, respectively, are briefly discussed.

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Authors and Affiliations

  1. Department of Physics, University of Leipzig, 04103, Leipzig, Germany

    Jörg Kärger

  2. Felix Bloch Institute for Solid State Physics, University of Leipzig, Linnéstr. 5, 04103, Leipzig, Germany

    Rustem Valiullin

Authors
  1. Jörg Kärger
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  2. Rustem Valiullin
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Correspondence to Jörg Kärger .

Editor information

Editors and Affiliations

  1. School of Physics and Astronomy, University of Birmingham, Birmingham, Worcestershire, United Kingdom

    Leigh Canham

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Kärger, J., Valiullin, R. (2018). Mesopore Diffusion Within Porous Silicon. In: Canham, L. (eds) Handbook of Porous Silicon. Springer, Cham. https://doi.org/10.1007/978-3-319-71381-6_22

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