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Handbook of Porous Silicon pp 463–472Cite as

Chemiluminescence of Porous Silicon

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Abstract

Visible chemiluminescence (CL) arising from the oxidation of porous silicon is reviewed from the perspectives of its discovery, excitation and detection, potential mechanisms, and future applications. CL can be more sensitive to surface states than PL, and efficiencies are generally much higher for one-electron oxidizing agents like the permanganate ion than two-electron oxidizers like the persulfate ion. Applications in biosensing and forensics are highlighted.

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References

  • Brandt MS, Fuchs HD, Stutzmann M, Weber J, Cardona M (1992) The origin of visible luminescence from “porous silicon”: a new interpretation. Solid State Commun 81:302

    Article  Google Scholar 

  • Bressers PMMC, Knapen JWJ, Meulenkamp EA, Kelly JJ (1992) Visible light emission from a porous silicon/solution diode. Appl Phys Lett 61:108

    Article  CAS  Google Scholar 

  • Campbell AK (1988) Chemiluminescence: principles & Applications in Biology & Medicine. VCH, Weinheim, 608pp

    Google Scholar 

  • Canham LT (1990) Silicon quantum wire array fabrication by electrochemical and chemical dissolution of wafers. Appl Phys Lett 57:1046

    Article  CAS  Google Scholar 

  • Canham LT, Leong WY, Beale MIJ, Cox TI, Taylor L (1992) Efficient visible electroluminescence from highly porous silicon under cathodic bias. Appl Phys Lett 61:2563

    Article  CAS  Google Scholar 

  • Deak P, Rosenbauer M, Stutzmann M, Weber J, Brandt MS (1992) Siloxene: chemical quantum confinement due to oxygen in a silicon matrix. Phys Rev Lett 69:2531

    Article  CAS  Google Scholar 

  • Ding Z, Quinn BM, Haram SK, Pell LE, Korgel BA, Bard AJ (2002) Electrochemistry and electrogenerated chemiluminescence from silicon nanocrystal quantum dots. Science 296:1293

    Article  CAS  Google Scholar 

  • Gee A (1960) Electrochemiluminescence at a silicon anode in contact with an electrolyte. J Electrochem Soc 107:787

    Article  CAS  Google Scholar 

  • Gerischer H, Lubke M (1988) On the etching of silicon by oxidants in ammonium fluoride solutions: a mechanistic study. J Electrochem Soc 135:2782

    Article  CAS  Google Scholar 

  • Hory MA, Hérino R, Ligeon M, Muller F, Gaspard F, Mihalcescu I, Vial JC (1995) Fourier transform IR monitoring of porous silicon passivation during post-treatments such as anodic oxidation and contact with organic solvents. Thin Solid Films 255:200

    Article  CAS  Google Scholar 

  • Koch EC, Clement D (2007) Special materials in pyrotechnics: VI Silicon – an old fuel with new perspectives. Prop Explos Pyrotech 32:205

    Article  CAS  Google Scholar 

  • Kooij ES, Noordhoek SM, Kelly JJ (1996) Reduction of peroxodisulfate at porous and crystalline silicon electrodes: an anomaly. J Phys Chem 100:10754

    Article  CAS  Google Scholar 

  • Kooij ES, Rama AR, Kelly JJ (1997) Infrared induced visible emission from porous silicon: the mechanism of anodic oxidation. Surf Sci 370:125

    Article  CAS  Google Scholar 

  • Kooij ES, Butter K, Kelly JJ (1998) Hole injection at the silicon/aqueous electrolyte interface: a possible mechanism for chemiluminescence from porous silicon. J Electrochem Soc 145:1232

    Article  CAS  Google Scholar 

  • Koshida N, Koyama H (1992) Visible electroluminescence from porous silicon. Appl Phys Lett 60:347

    Article  CAS  Google Scholar 

  • McCord P, Yau SL, Bard AJ (1992) Chemiluminescence of anodized and etched silicon: evidence for a luminescent siloxene-like layer on porous Silicon. Science 257:68

    Article  CAS  Google Scholar 

  • Meulenkamp EA, Bressers PMMC, Kelly JJ (1993) Visible chemiluminescence and electroluminescence of porous silicon. Appl Surf Sci 64:283

    Article  CAS  Google Scholar 

  • Meulenkamp EA, Cleij TJ, Kelly JJ (1994) Electroluminescence and chemiluminescence of porous silicon in nonaqueous solution. Electrchem Soc 141:1157

    Article  CAS  Google Scholar 

  • Pickering C, Beale MIJ, Robbins DJ, Pearson PJ, Greef R (1984) Optical studies of the structure of porous silicon films formed in p-type degenerate and non-degenerate silicon. J Phys C 17:6535

    Article  CAS  Google Scholar 

  • Poznyak SK, Talapin DV, Shevchenko EV, Weller H (2004) Quantum dot chemiluminescence. Nano Lett 4:693

    Article  CAS  Google Scholar 

  • Tan J, Xu L, Li T, Su B, Wu J (2014) Image-contrast technology based on the electrochemiluminescence of porous silicon and its application in fingerprint visualization. Angew Chem Int Ed 53:9822

    Article  CAS  Google Scholar 

  • Turner DR (1958) Electropolishing silicon in hydrofluoric acid solutions. J Electrochem Soc 105:402

    Article  CAS  Google Scholar 

  • Uhlir A (1956) Electrolytic shaping of germanium and silicon. Bell Syst Tech J 35:333

    Article  CAS  Google Scholar 

  • Van de Walle CG, Northrup JE (1993) First-principles investigation of visible light emission from silicon-based materials. Phys Rev Lett 70:1116

    Article  Google Scholar 

  • Wang Z, Li J, Liu B, Hu J, Yao X, Li J (2005) Chemiluminescence of CdTe nanocrystals induced by direct chemical oxidation and its size-dependent and surfactant-sensitized effect. J Phys Chem B 109:23304

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang, China

    Jianmin Wu

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  1. Jianmin Wu
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Correspondence to Jianmin Wu .

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Editors and Affiliations

  1. School of Physics and Astronomy, University of Birmingham, Birmingham, Worcestershire, United Kingdom

    Leigh Canham

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Wu, J. (2018). Chemiluminescence of Porous Silicon. In: Canham, L. (eds) Handbook of Porous Silicon. Springer, Cham. https://doi.org/10.1007/978-3-319-71381-6_130

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