Abstract
Consumption of fossil fuels increases year by year with negative impacts on the environment, particularly due to the emission of carbon dioxide (CO2), a major anthropogenic greenhouse gas. Consequently, important scientific challenges for the upcoming years are the development of cleaner energy sources to satisfy the increasing energy demand, the reduction of the consumption of fossil fuels, and mitigation of the CO2 emissions. Therefore, the production of renewable fuels with high energy content is researched, while efficient CO2 capture is developed to reduce emissions from less-clean energy resources. For the former challenge, the production of hydrogen by heterogeneous photocatalysis is a potential solution. For the second problem, the use of solid sorbents for CO2 capture as CaO and alkaline ceramics are promising proposals.
The development of catalysts and materials for CO2 capture with high efficiency and stability as well as reasonable production costs is a great challenge. In the search for new efficient and inexpensive materials, metallurgical slags are quite attractive due to their physicochemical characteristics, abundance, and low cost. The high iron oxide content (>50% w/w) and the presence of crystalline phases such as fayalite (Fe2SiO4) and magnetite (Fe3O4) in the metallurgical copper slag indicate it may be active photocatalyst. On the other hand, the composition of the iron and steel slags makes these materials an excellent feedstock for the synthesis of CaO-based materials and other derived materials for CO2 capture technologies.
References
Davenport W, King M, Schlesinger M, Biswas AK (2002) Overview. In: Davenport W, King M, Schlesinger M, Biswas AK (eds) Extractive metallurgy of copper, 4th edn. Pergamon Press, Oxford, UK, pp 1–16
U.S. Department of the Interior, U.S. Geological Survey (2016) In: Miner-al commodity summaries 2016. Available via DIALOG. https://minerals.usgs.gov/minerals/pubs/mcs/2016/mcs2016.pdf. Accessed 12 Jun 2017
The University of Arizona (2017) Copper mining and processing: processing of copper ores. Accessed 10 Jun 2017
Burroughs C, Lorig C, Shewmon PG, Charles JA (2017) Extractive metallurgy. In: Metallurgy. Encyclopædia Britannica, Inc. Available via DIALOG. https://www.britannica.com/science/metallurgy/Extractive-metallurgy. Accessed 15 Jun 2017
Berdowski J, van der Most P, Slager JM, Mulder W, Hlawiczka S, Fudala J, Bloos JP, Verhoeve P, Quass U, Pierce M, Pulles T, Appelman W, Rentz O, Karl U, Woodfield M (2016) Metal production. In: EMEP/EEA air pollutant emission inventory guidebook 2016. EEA European Environment Agency, Copenhagen, pp 8–18
Secretaria de Medio Ambiente y Recursos Naturales. Norma Oficial Mexicana NOM-157-SEMARNAT-2009 (2011) Available via DIALOG. http://www.profepa.gob.mx/innovaportal/file/6665/1/nom-157-semarnat-2009.pdf. Accessed 9 Jun 2017
National Slag Association (2013) Common uses from slags. http://www.nationalslag.org/common-uses-slag. Accessed 12 Jun 2017
Nippon Slag Association (2003) Types of iron and steel slags. http://www.slg.jp/e/association/index.html. Accessed 12 Jun 2017
Euroslag (2010) Statistics 2010. In: Statistical data. The European Slag Association – Euroslag. Available via DIALOG. http://www.euroslag.org/researchlibrarydownloads/downloads/. Accessed 15 Jun 2017
Environmental Protection Agency (2016) TENORM: Copper Mining and Production Wastes. In: Radiation protection. Available via DIALOG. https://www.epa.gov/radiation/tenorm-copper-mining-and-production-wastes#tab-2. Accessed 1st Jun 2017
European Commission (2017) Extractive waste. In: Environment. European Commission. Available via DIALOG. http://ec.europa.eu/environment/waste/mining/. Accessed 15 Jun 2017
Commission Decision (EU) No 2014/955/EU of 18 December 2014 amending Decision 2000/532/EC on the list of waste pursuant to Directive 2008/98/EC of the European Parliament and of the Council Text with EEA relevance (OJ L 370, 30.12.2014, p. 44–86). Available via DIALOG. http://ec.europa.eu/environment/waste/legislation/a.htm. Accessed 16 Jun 2017
Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain Directives (Text with EEA relevance). Special edition in Croatian: Chapter 15 Volume 034 P. 99–126. Available via DIALOG. http://data.europa.eu/eli/dir/2008/98/oj. Accessed 16 Jun 2017
Commission Implementing Decision (EU) 2016/1032 of 13 June 2016 establishing best available techniques (BAT) conclusions, under Directive 2010/75/EU of the European Parliament and of the Council, for the non-ferrous metals industries (notified under document C (2016) 3563) (Text with EEA relevance) Available via DIALOG. http://eur-lex.europa.eu/legal-content/EN/TXT/HTML/?uri=CELEX:32016D1032&rid=14. Accessed 16 Jun 2017
Mercado-Borrayo BM, Schouwenaars R, González-Chávez JL, Ramírez-Zamora RM (2013) Multianalytical assessment of iron and steel slag characteristics to estimate the removal of metalloids from contaminated water. J Environ Sci Heal A 48:887–895
Jarošíková A, Ettler V, Mihaljevič M, Kříbek B, Mapani B (2017) The pH-dependent leaching behavior of slags from various stages of a copper smelting process: environmental implications. J Environ Manag 187:178–186
Piatak NM, Parsons MB, Seal RRII (2015) Characteristics and environmental aspects of slag: a review. Appl Geochem 57:236–266
Huang Y, Guoping X, Huigao C, Junshi W, Yinfeng W, Hui C (2012) An overview of utilization of steel slag. Procedia Environ Sci 16:791–801
Huaiwei Z, Xin Z (2011) An overview for the utilization of wastes from stainless steel industries. Resour Conserv Recycl 55:745–754
Kim HS, Kim KS, Jung SS, Hwang JI, Choi JS, Sohn I (2015) Valorization of electric arc furnace primary steelmaking slags for cement applications. Waste Manag 41:85–93
Gorai B, Jana RK, Premchand (2003) Characteristics and utilisation of copper slag-a review. Resour Conserv Recycl 39:299–313
IUPAC (2017) International union of pure and applied chemistry. Photocatalysis. Available via DIALOG http://goldbook.iupac.org/P04580.html. Accessed 7 May 2017
Yang J, Wanget S, Lu Z, Yang J, Lou S (2009) Converter slag–coal cinder columns for the removal of phosphorous and other pollutants. J Hazard Mater 168:331–337
Haibo L, Yinghua L, Zongqiang G, Xiaodong L (2013) Performance study of vertical flow constructed wetlands for phosphorus removal with water quenched slag as a substrate. Ecol Eng 53:39–45
Zukhra C, Mirabbos H, Longli B, Okada K (2015) Simultaneous removal of NH4 +, H2PO4 − and Ni2+ from aqueous solution by thermally activated combinations of steel converter slag and spent alumina catalyst. J Water Process Eng 8:151–159
Jiayuan S, Yasutaka K, Taicheng A, Yamashita H (2017) The fabrication of TiO2 supported on slag-made calcium silicate as low-cost photocatalyst with high adsorption ability for the degradation of dye pollutants in water. Catal Today 281:21–28
Kang L, Zhang Y, Zhang L, Zhang K (2017) Preparation, characterization and photocatalytic activity of novel CeO2 loaded porous alkali-activated steel slag-based binding material. Int J Hydrog Energy 42:17341–17349
Cheng M, Zeng G, Huang D, Lai C, Xu P, Zhang C, Liu Y, Wan J, Gong X, Zhu Y (2016) Degradation of atrazine by a novel Fenton-like process and assessment the influence on the treated soil. J Hazard Mater 312:184–191
Tsai T, Kao C, Wang J (2011) Remediation of TCE-contaminated groundwater using acid/BOF slag enhanced chemical oxidation. Chemosphere 83:687–692
Zheng J, Gao Z, He H, Yang S, Sun C (2016) Efficient degradation of acid orange 7 in aqueous solution by iron ore tailing Fenton-like process. Chemosphere 150:40–48
Mihailova I, Ivanov G, Mehandjiev D (2011) Catalytic activity in oxidation reactions of copper furnace slag and converter slag. J Univ Chem Technol Metallurgy 46(2):143–150
Name T, Sheridan C (2014) Remediation of acid mine drainage using metallurgical slags. Miner Eng 64:15–22
Ziemkiewicz P (1998) Steel slag: applications for AMD control. In: Proceedings of the 1998, conference on Hazardous Waste Research. Snowbird, Utah
Abe R (2010) Recent progress on photocatalytic and photoelectrochemical water splitting under visible light irradiation. J Photochem Photobiol C: Photochem Rev 11:179–209
Patsoura A, Kondarides D, Verykios XE (2007) Photocatalytic degradation of organic pollutants with simultaneous production of hydrogen. Catal Today 124:94–102
Colón G (2016) Towards the hydrogen production by photocatalysis. Appl Catal A 518:48–59
Im Y, Kang S, Kim KM, Ju T, Han GB, Park N-K, Lee TJ, Kang M (2013) Dynamic hydrogen production from methanol/water photo-splitting using Core@Shell-structured CuS@TiO2Catalyst wrapped by high concentrated TiO2 particles. Int J Photogr 2013:10. https://doi.org/10.1155/2013/452542
Chen X, Shen S, Guo L, Mao SS (2010) Semiconductor-based photocatalytic hydrogen generation. Chem Rev 101(11):6503–6570
Kaneco M, Okura I (2002) Photocatalysis: science and technology. Springer, Tokyo
García Pérez R (2015) Valorización de escoria metalúrgica de la industria del cobre como fotocatalizador para el tratamiento de aguas contaminadas con ácido acético con una producción simultánea de hidrógeno. Dissertation, Universidad Nacional Autónoma de México. Available via DIALOG http://132.248.9.195/ptd2015/noviembre/091095431/Index.html. Accessed 6 Jun 2017
Hernández Mazatan MA (2014) Producción de hidrógeno por degradación de compuestos orgánicos en agua mediante el proceso de fotocatálisis heterogénea. Dissertation, Universidad Nacional Autónoma de México. Available via DIALOG http://132.248.9.195/ptd2014/octubre/513005824/Index.html. Accessed 6 Jun 2017
Lü H, Li N, Wu X, Li L, Gao Z (2013) A novel conversion of Ti-bearing blast-furnace slag into water splitting photocatalyst with visible-light-response. Metall Mater Trans B 44B:1317–1320
Zhang YJ, Kang L, Si HX, Zhang JF (2014) A novel alkali-activated magnesium slag-based nanocomposite for photocatalytic production of hydrogen. Integr Ferroelectr 154:120–127
Amorim SM, Domenico MD, Dantas TLP, José HJ, Moreira RFPM (2016) Lithium orthosilicate for CO2 capture with high regeneration capacity: kinetic study and modeling of carbonation and decarbonation reactions. Chem Eng J 283:388–396
Erans M, Manovic V, Anthony EJ (2016) Calcium looping sorbents for CO2 capture. Appl Energy 180:722–742
Pfeiffer H (2010) Advances on alkaline ceramics as possible CO2 captors. Advances in CO2 conversion and utilization. ACS Symp Ser 1056:233–253
Abanades JC (2015) Emerging CO2 capture systems. Int J Greenhouse Gas Control 40:126–166
He S (2017) Investigation of CaO-based sorbents derived from eggshells and red mud for CO2 capture. J Alloys Compd 701:828–833
Luo C, Zheng Y, Xu Y, Ding N, Shen Q, Zheng C (2015) Wet mixing combustion synthesis of CaO-based sorbents for high temperature cyclic CO2 capture. Chem Eng J 267:111–116
Chowdhury MBI, Quddus MR, deLasa HI (2013) CO2 capture with a novel solid fluidizable sorbent: thermodynamics and temperature programmed carbonation–Decarbonation. Chem Eng J 232:139–148
Li Y, Zhao C, Chen H, Liang C, Duan L, Zhou W (2009) Modified CaO-based sorbent looping cycle for CO2 mitigation. Fuel 88:697–704
Huijgen WJJ, Witkamp GJ, Comans RNJ (2005) Mineral CO2 sequestration by steel slag carbonation. Environ Sci Technol 39:9676–9682
Bonenfant D (2009) Molecular analysis of carbon dioxide adsorption processes on steel slag oxides. Int J Greenhouse Gas Control 3:20–28
Yu J, Wang K (2011) Study on characteristics of steel slag for CO2 capture. Energy Fuel 25:5483–5492
Tian S, Jiang J, Chen X, Yan F, Li K (2013) Direct gas-solid carbonation kinetics of steel slag and the contribution to in situ sequestration of flue gas CO2 in steel-making plants. ChemSusChem 6:2348–2355
Bonenfant D, Kharoune L, Hausler R, Niquette P (2008) CO2 sequestration potential of steel slags at ambient pressure and temperature. Ind Eng Chem Res 47:7610–7616
Doucet FJ (2010) Effective CO2-specific sequestration capacity of steel slags and variability in their leaching behaviour in view of industrial mineral carbonation. Miner Eng 23:262–269
Tian S, Jiang J, Li K, Yan F, Chen X (2014) Performance of steel slag in carbonation–calcination looping for CO2 capture from industrial flue gas. RSC Adv 4: 6858–6862
Ortiz C, Valverde JM, Chacartegui R (2016) Energy consumption for CO2 capture by means of the calcium looping process: a comparative analysis using limestone, dolomite, and steel slag. Energ Technol 4:1317–1327
Tian S, Jiang J, Yan F, Li K, Chen X (2015) Synthesis of highly efficient CaO-based, self-stabilizing CO2 sorbents via structure-reforming of steel slag. Environ Sci Technol 49: 7464–7472
Miranda-Pizarro J, Perejón A, Valverde JM, Sánchez-Jiménez PE, Pérez-Maqueda LA (2016) Use of steel slag for CO2 capture under realistic calcium-looping conditions. RSC Adv 6: 37656–37663
Alcántar-Vázquez B, Schouwenaars R, Ramirez-Zamora RM (2017) CO2 capture at high temperature using slag – derived lithium silicates. In: Proceedings 5th international slag valorisation symposium, Leuven. Avalilable via DIALOG http://www.slag-valorisation-symposium.eu/wp-content/uploads/downloads/Session%206/Rosa-Mar%C3%ADa%20Ramirez-Zamora%20-%20Paper%20-%20CO2%20capture%20at%20high%20temperature%20using%20slag%20%E2%80%93%20derived%20lithium%20silicates%20-%20SVS2017.pdf. Accessed 15 Nov 2017
IPCC (2014) Climate change 2014: mitigation of climate change. Available via DIALOG. http://www.ipcc.ch/report/ar5/wg3/. Accessed 16 Nov 2017
Romeo LM, Lara Y, Lisbona P, Martinez A (2009) Economical assessment of competitive enhanced limestones for CO2 capture cycles in power plants. Fuel Process Technol 90:803−811
Anthony EJ (2011) Ca looping technology: current status, developments, and future directions. Greenhouse Gas Sci Technol 1:36–47
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Montoya-Bautista, C.V. et al. (2018). Photocatalytic H2 Production and Carbon Dioxide Capture Using Metallurgical Slag and Slag-Derived Materials . In: Martínez, L., Kharissova, O., Kharisov, B. (eds) Handbook of Ecomaterials. Springer, Cham. https://doi.org/10.1007/978-3-319-48281-1_117-1
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DOI: https://doi.org/10.1007/978-3-319-48281-1_117-1
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