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X-Ray Diffraction

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Encyclopedia of Geochemistry

Part of the book series: Encyclopedia of Earth Sciences Series ((EESS))

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Definition

X-ray diffraction is the result of coherent scattering of an X-ray beam through a solid-state crystalline phase. Single-crystal X-ray diffraction can provide information about the arrangement of atoms and overall chemical composition of mineral phases by determining the angle and intensity of the diffracted beam. Powder samples can also be analyzed using this method to identify unknown phases or mixtures, provide unit cell parameters, and determine particle sizes.

Introduction to X-rays

X-rays were first discovered by Wilhelm Conrad Roentgen in 1985 during experiments with a cathode ray tube (Bertin 1975; Reventos et al. 2012). This device consists of a specialized vacuum tube in which images can be created when electrons are accelerated or deflected onto a phosphorescent screen. During his experiments, he observed that a fluorescent screen located on a table six feet away from his experiments glowed when he activated the tube. Since these rays were previously undescribed,...

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References

  • Bertin E (1975) Principles and practice of X-ray spectrometric analysis. Plenum Press, New York

    Book  Google Scholar 

  • Bindi L, Yao N, Lin C, Hollister LS, Andronicos CL, Distler VV, Eddy MP, Kostin A, Kryachko V, MacPherson GJ, Steinhardt W, Yudovskaya M, Steinhardt PJ (2015) Decagonite, Al71Ni24Fe5, a quasicrystal with decagonal symmetry from the Khatyrka CV3 carbonaceous chondrite. Am Mineral 100:2340–2343

    Article  Google Scholar 

  • Bish DL, Post JE (1989) Modern powder diffraction. The Mineralogical Society of America, Washington, DC

    Google Scholar 

  • Bristow TF, Bish DL, Vaniman DT, Morris RV, Blake DF, Brotzinger JP, Rampe EB, Crisp JA, Achilles CN, Ming DW, Ehlmann BL, King PL, Bridges JC, Eignebrode JL, Sumner DY, Chipera SJ, Moorokian JM, Treimaan AH, Morrison SM, Downs RT, Farmer JD, Des Marais D, Sarrazin P, Floyd MM, Mischna MA, McAdams AC (2015) The origin and implications of clay minerals from Yellowknife Bay, Gale crater, Mars. Am Mineral 100:824–836

    Article  Google Scholar 

  • Cam N, Georgelin T, Jaber M, Lambe JF, Benzerara K (2015) In vitro synthesis of amorphous Mg-, Ca-, Sr-, and Ba-carbonates: what do we learn about intracellular calcification by cyanobacteria? Geochim Cosmochim Acta 161:36–49

    Article  Google Scholar 

  • Dideriksen K, Frandsen C, Bovet N, Wallace AF, Sel O, Arbour T, Navrotsky A, DeYoreo JJ, Banfield J (2015) Formation and transformation of a short range ordered iron carbonate precursor. Geochim Cosmochim Acta 164:94–109

    Article  Google Scholar 

  • Golubkova A, Merlini M, Schmidt MW (2015) Crystal structure, high-pressure, and high-temperature behavior of carbonates in the K2Mg(CO3)2-Na2Mg(CO3)2 join. Am Mineral 100:2458–2467

    Article  Google Scholar 

  • Hazen RM, Hystad G, Downs RT, Golden J, Pires AJ, Grew ES (2015) Earth’s ‘missing’ minerals. Am Mineral 100:2344–2347

    Article  Google Scholar 

  • King AJ, Schofield PF, Howard KT, Russell SS (2015) Modal mineralogy of Cl and Cl-like chondrites by X-ray diffraction. Geochim Cosmochim Acta 165:148–160

    Article  Google Scholar 

  • Massa W (2004) Crystal structure determination. Spinger, Berlin

    Book  Google Scholar 

  • Merlini M, Hanfland M, Salamat A, Petitgard S, Muller H (2015) The crystal structures of Mg2Fe2C4O13, with tetrahedrally coordinated carbon, and Fe13O19, synthesized at deep mantle conditions. Am Mineral 100:2001–2004

    Article  Google Scholar 

  • Mikutta C, Schroder C, Michel FM (2014) Total X-ray scattering, EXAFS, and Mossbauer spectroscopy analysis of amorphous ferric arsenate and amorphous ferric phosphate. Geochim Cosmochim Acta 140:708–719

    Article  Google Scholar 

  • Pecharsky VK, Zavalij PY (eds) (2005) Fundamentals of powder diffraction and structural characterization of materials. Springer, New York

    Google Scholar 

  • Pokroy B, Quintana JP, Caspi EAN, Berner A, Zolotoyabko E (2004) Anisotropic lattice distorions in biogenic aragonite. Nature 3:900–902

    Article  Google Scholar 

  • Reventos MM, Rius J, Amigo JM (2012) Mineralogy and geology: the role of crystallography since the discovery of X-ray diffraction in 1912. Rev Soc Geol Esp 25:133–143

    Google Scholar 

  • Toulemonde P, Goujon C, Laversenne L, Bordet P, Bruyere R, Legendre M, Leynaud O, Prat A, Mezouar M (2014) High pressure and high temperature in situ X-ray diffraction studies in the Paris Edinburgh cell using a laboratory X-ray source. High Pressure Res 34:1–6

    Article  Google Scholar 

  • Villalobos M, Lanson B, Manceau A, Toner B, Sposito G (2006) Structural model for the biogenic Mn oxide produced by Pseudomonas putida. Am Mineral 91:489–502

    Article  Google Scholar 

  • Wegorzewski AV, Kuhn T, Dohrmann R, Wirth R, Grangeon S (2015) Mineralogical characterization of individual growth structures of the Mn-nodules with different Ni + Cu content from the central Pacific ocean. Am Mineral 100:2497–2508

    Article  Google Scholar 

  • Xie X, Yang H, Gu X, Downs RT (2015) Chemical composition and crystal structure of merrillite from the Suizhou meteorite. Am Mineral 100:2753–2756

    Article  Google Scholar 

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Correspondence to Tori Z. Forbes .

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Forbes, T.Z. (2018). X-Ray Diffraction. In: White, W.M. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39312-4_25

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