Atomic Symbol: Os
Atomic Number: 76
Atomic Weight: 190.2
Isotopes and Abundances:
184: 0.0174 %
186: 1.5935 %
187: 1.5129 %
188: 13.296 %
189: 16.217 %
190: 26.376 %
192: 40.988 %
1 Atm Melting Point: 3030 °C
1 Atm Boiling Point: 5010 °C
Common Valences: 0, +3, +4, +8
Ionic Radii: 53–77 pm
Pauling Electronegativity: 2.2
First Ionization Potential: 8.44 eV
Chondritic (CI) Abundance: 490 ppb
Silicate Earth Abundance: 3.9 ppb
Crustal Abundance: 0.031 ppb (continental), 0.055 (oceanic)
Seawater Abundance: 10 pg/L
Core Abundance: 2800 ppb
Properties
Osmium is a highly refractory, bluish-white metal (hexagonal close packed). It is hard and brittle and has a density of 22,600 kg/m3, the highest of any element. Osmium is not a structural constituent of any mineral, but it alloys with iridium and ruthenium and is also found in high abundance in some sulfide minerals, such as laurite (RuS2). Osmium has oxidation states ranging from 0 to +8, but in nature 0, +3, +4, and...
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References
Anders, E., and Grevesse, N., 1989. Abundances of the elements: meteoritic and solar. Geochimica et Cosmochimica Acta, 53, 197–214.
Chen, C., and Sharma, M., 2009. High precision and high sensitivity measurements of osmium in seawater. Analytical Chemistry, 81, 5400–5406.
Chou, C.-L., 1978. Fractionation of siderophile elements in the earth’s upper mantle. In Proceeding of the Lunar and Planetary Science Conference 9th, pp. 219–230.
Dale, C. W., Burton, K. W., Greenwood, R. C., Gannoun, A., Wade, J., Wood, B. J., and Pearson, D. G., 2012. Late accretion on the earliest planetesimals revealed by the highly siderophile elements. Science, 336, 72–75.
Day, J. M. D., 2013. Hotspot volcanism and highly siderophile elements. Chemical Geology, 341, 50–74.
Fischer-Gӧdde, M., Becker, H., and Wombacher, F., 2011. Rhodium, gold and other highly siderophile element abundances in orogenic peridotites and peridotite xenoliths. Chemical Geology, 280, 365–383.
Goldschmidt, V. M., 1937. The principles of distribution of chemical elements in minerals and rocks. Journal of the Chemical Society, 655–673.
Horan, M. F., Morgan, J. W., Grauch, R. I., Coveney, R. M., Murowchick, J. B., and Hulbert, L. J., 1994. Rhenium and osmium isotopes in black shales and Ni-Mo-PGE-rich sulfide layers, Yukon territory, Canada, and Hunan and Guizhou provinces, China. Geochimica et Cosmochimica Acta, 58, 257–265.
Kendall, B., Creaser, R. A., and Selby, D., 2009. 187Re-187Os geochronology of Precambrian organic-rich sedimentary rocks. Geological Society of London, Special Publication, 326, 85–107.
Koeberl, C., Reimold, W. U., Shirey, S. B., and LeRoux, F. G., 1994. Kalkkop Crater, Cape Province, South Africa: confirmation of impact origin using osmium isotope systematics. Geochimica et Cosmochimica Acta, 58, 1229–1234.
Penniston-Dorland, S. C., Walker, R. J., Pitcher, L., and Sorensen, S. S., 2012. Mantle-crust interactions in a paleosubduction zone: evidence from highly-siderophile element systematics of eclogite and related rocks. Earth and Planetary Science Letters, 319–320, 295–306.
Peucker-Ehrenbrink, B., Hanghøj, K., Atwood, T., and Kelemen, P. B., 2012. Rhenium-osmium isotope systematics and platinum group element concentrations in oceanic crust. Geology, 40, 199–202.
Puchtel, I. S., Walker, R. J., Brandon, A. D., and Nisbet, E. G., 2009. Pt-Re-Os and Sm-Nd isotope and HSE and REE systematics of the 2.7 Ga Belingwe and Abitibi komatiites. Geochimica et Cosmochimica Acta, 73, 6367–6389.
Ravizza, G., Turekian, K. K., and Hay, B. J., 1991. The geochemistry of rhenium and osmium in recent sediment from the Black Sea. Geochimica et Cosmochimica Acta, 55, 3741–3752.
Rudnick, R. L., and Gao, S., 2003. Composition of the continental crust. In Rudnick, R. L. (ed.), Treatise on Geochemistry. Amsterdam: Elsevier B.V. The Crust, Vol. 3, pp. 1–64.
Selby, D., and Creaser, R. A., 2005. Direct radiometric dating of hydrocarbon deposits using rhenium-osmium isotopes. Science, 308, 1293–1295.
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Walker, R.J. (2016). Osmium. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_127-1
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DOI: https://doi.org/10.1007/978-3-319-39193-9_127-1
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