Abstract
This chapter reviews the fundamentals of ionic polymer–metal composites (IPMCs), which are used for sensors and actuators. First, the basic structure of IPMCs is described, and a brief review of their development is provided. Then, the configurations of various devices based on them, including those of the electrode materials and ionic polymers, are described. Then, the basic techniques used to characterize IPMCs are described. In the next section, electromechanical models and, in particular, a physics-based model of an IPMC actuator are discussed. Finally, electrochemical models, including an Alternating Current impedance equivalent circuit model and an electrode reaction model, and a mechanical model are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Akle BJ, Bennett MD, Leo DJ (2006) High-strain ionomeric-ionic liquid electroactive actuators. Sens Actuators A 126:173–181
Aoyagi W, Omiya M (2013) Mechanical and electrochemical properties of an IPMC actuator with palladium electrodes in acid and alkaline solutions. Smart Mater Struct 22:055028 (10 pp)
Asaka K, Oguro K (2000) Bending of Polyelectrolyte Membrane-platinum composites by electric stimuli. Part II. Response kinetics. J Electroanal Chem 480:186–198
Asaka K, Oguro K (2009a) IPMC actuators: fundamentals. In: Carpi F, Smela E (eds) Biomedical applications of electroactive polymer actuators. Wiley, Chichester, pp 103–119
Asaka K, Oguro K (2009b) Active microcatheter and biomedical soft devices based on IPMC actuators. In: Carpi F, Smela E (eds) Biomedical applications of electroactive polymer actuators. Wiley, Chichester, pp 103–119
Asaka K, Okuzaki H (eds) (2014) Soft actuators – material, modeling, applications and future perspectives. Springer, Tokyo
Aureli M, Porfiri M (2012) Effect of electrode surface roughness on the electrical impedance of ionic polymer–metal composites. Smart Mater Struct 21:105030
Aureli M, Lin W, Porfiri M (2009) On the capacitance-boost of ionic polymer metal composites due to electroless plating: theory and experiments. J Appl Phys 105:104911
Bard AJ, Falkner LF (2001) Electrochemical methods: fundamentals and applications, 2nd edn. Wiley, New York
Bennett MD, Leo DJ (2004) Ionic liquids as stable solvents for ionic polymer transducers. Sens Actuators A-Phys 115:79–90
Bisquert J (2000) Influence of the boundaries in the impedance of porous film electrodes. Phys Chem Chem Phys 2:4185–4192
Carpi F, Smela E (eds) (2009) Biomedical applications of electroactive polymer actuators. Wiley, Chichester
Cha Y, Porfiri M (2013) Bias-dependent model of the electrical impedance of ionic polymer-metal composites. Phys Rev E 87:022403
Chen Z, Tan X (2008) A control-oriented and physics-based model for ionic polymer-metal composite actuators. IEEE/ASME Trans Mechatron 13(5):519–529
Chung CK, Fung PK, Hong YZ et al (2006) A novel fabrication of ionic polymer-metal composites (IPMC) actuator with silver nano-powders. Sens Actuators B 117:367–375
de Gennes PG, Okumura K, Shahinpoor M, Kim KJ (2000) Mechanoelectric effects in ionic gels. Europhys Lett 50:513–518
de Levie R (1963) On porous electrodes in electrolyte solutions: I. Capacitance effects. Electrochim Acta 8:751–780
de Levie R (1964) On porous electrodes in electrolyte solutions—IV. Electrochim Acta 9:1231–1245
DeRossi D, Kajiwara K, Osada Y, Yamauchi A (eds) (1991) Polymer gels – fundamentals and biomedical applications. Plenum Press, New York
Doi M (2009) Gel dynamics. J Phys Soc Jpn 78(5): 052001
Fujiwara N, Asaka K, Nishimura Y et al (1999) Preparation of gold-solid electrolyte composites as electric stimuli responsive materials. Chem Mater 12:1750–1754
Hamlen RP, Kent CE, Shafer SN (1965) Electrolytically activated contractile polymer. Nature 206:1149–1150
He Q, Yu M, Song L et al (2011) Experimental study and model analysis of the performance of IPMC membranes with various thickness. J Bionic Eng 8:77–85
Jo CH, Pugal D, Oh IK et al (2013) Recent advances in ionic polymer-metal composite actuators and their modeling and applications. Prog Polym Sci 38(7):1037–1066
Johanson U, Maeorg U, Sammelselg V et al (2008) Electrode reactions in Cu-Pt coated ionic polymer actuators. Sens Actuators B 31:340–346
Kikuchi K, Tsuchitani S (2009) Nafion based polymer actuators with ionic liquids as solvent incorporated at room temperature. J Appl Phys 106:053519
Kikuchi K, Sakamoto T, Tsuchitani S et al (2011) Comparative study of bending characteristics of ionic polymer actuators containing ionic liquids for modeling actuation. J Appl Phys 109:073505
Kim SM, Kim KJ (2008) Palladium buffer-layered high performance ionic polymer-metal composites. Smart Mater Struct 17:035011
Kim KJ, Shahinpoor M (2003) Ionic polymer-metal composites – II. Manufacturing techniques. Smart Mater Struct 12:65–79
Kim KJ, Tadokoro S (eds) (2007) Electroactive polymers for robotics applications. Springer, London
Kim SM, Tiwari R, Kim KJ (2009) A novel ionic polymer-metal composites incorporating ZnO thin film. Smart Mater Struct Electroactive Polym Actuators Devices 7287:72870W-1-7
Kim D, Kim KJ, Nam JD et al (2011) Electro-chemical operation of ionic polymer–metal composites. Sens Actuators B 155(2011):106–113
Lee JW, Yoo YT (2009) Anion effects in imidazolium ionic liquids on the performance of IPMCs. Sens Actuators B 137:539–546
Levitsky IA, Kanelos P, Euler WB (2004) Electromechanical actuation of composite material from carbon nanotubes and ionomeric polymer. J Chem Phys 121:1058–1165
Lin J, Liu Y, Zhang QM (2011) Charge dynamics and bending actuation in Aquivion membrane swelled with ionic liquids. Polymer 52:540–546
Liu Y, Zhao R, Ghaffari M et al (2012) Equivalent circuit modeling of ionomer and ionic polymer conductive network composite actuators containing ionic liquids. Sens Actuators A 181:70–76
Lu L, Liu J, Zhang Y et al (2013) Graphene-stabilized silver nanoparticle electrochemical electrode for actuator design. Adv Mater 25:1270–1274
Nemat-Nasser S (2002) Micromechanics of actuation of ionic polymer-metal composites. J Appl Phys 92:2899–2915
Nemat-Nasser S, Wu Y (2003) Comparative experimental study of ionic polymer-metal composites with different backbone ionomers and in various cation forms. J Appl Phys 93:5255–5267
Nemat-Nasser S, Zamani S (2006) Modeling of electrochemomechanical response of ionic polymer-metal composites with various solvents. J Appl Phys 100:064310
Oguro K, Kawami Y, Takenaka H (1992) Bending of an ion-conducting polymer film-electrode composite by an electric stimulus at low voltage. J Micromach Soc 5:27–30
Palmre V, Lust E, Janes A et al (2011) Electroactive polymer actuators with carbon aerogel electrodes. J Mater Chem 21:2577–2583
Panwar V, Lee C, Ko SY et al (2012) Dynamic mechanical, electrical, and actuation properties of ionic polymer metal composites using PVDF/PVP/PSSA blend membranes. Mater Chem Phys 135:928–937
Paquette JW, Kim KJ, Nam JD et al (2003) An equivalent circuit model for ionic polymer-metal composites and their performance improvement by a clay-based polymer nano-composite technique. J Intell Mater Syst Struct 14:633–642
Pasquale GD, Graziani S, Messina FG et al (2014) An investigation of the structure–property relationships in ionic polymer polymer composites (IP2Cs) manufactured by polymerization in situ of PEDOT/PSS on Nafion R 117. Smart Mater Struct 23:035018 (12pp)
Porfiri M (2008) Charge dynamics in ionic polymer metal composites. J Appl Phys 104:104915
Pugal D, Kim KJ, Aabloo A (2011) An explicit physics-based model of ionic polymer-metal composite actuators. J Appl Phys 110(8):084904
Pugal D, Solin P, Aabloo A, Kim KJ (2013) IPMC mechanoelectric transduction: its scalability and optimization. Smart Mater Struct 22(12):125029
Punning A, Kruusmaa M, Aabloo A (2007) Surface resistance experiments with IPMC sensors and actuators. Sens Actuators A 133:200–209
Rajagopalan M, Jeon JH, Oh IK (2010) Electric-stimuli-responsive bending actuator based on sulfonated polyetherimide. Sens Actuators B 151:198–204
Shahinpoor M (1992) Conceptual design, kinematics and dynamics of swimming robotic structures using ionic polymeric gel muscles. Smart Mater Struct 1:91–94
Shahinpoor M, Kim KJ (2000) The effect of surface-electrode resistance on the performance of ionic polymer-metal composite (IPMC) artificial muscles. Smart Mater Struct 9:543–551
Shahinpoor M, Kim KJ (2001) Ionic polymer-metal composites – I. Fundamentals. Smart Mater Struct 10:819–833
Shahinpoor M, Kim KJ (2004) Ionic polymer-metal composites – III. Modeling and simulation as biomimetic sensors, actuators, transducers and artificial muscles. Smart Mater Struct 13:1362–1388
Shahinpoor M, Kim KJ (2005) Ionic polymer-metal composites – IV. Industrial and mechanical applications. Smart Mater Struct 14:197–214
Shahinpoor M, Bar-Cohen Y, Simpson JO, Smith J (1998) Ionic polymer-metal composites (IPMCs) as biomimetic sensors, actuators and artificial muscles-a review. Smart Mater Struct 7:R15–R30
Shahinpoor M, Kim KJ, Mojarrad M (2007) Artificial muscles – applications of advanced polymeric nanocomposites. CRC Press, New York/London
Tadokoro S, Yamagami S, Takamori T et al (2000) Modeling of nafion-Pt composite actuators (ICPF) by ionic motion. Smart Mater Struct Electroactive Polym Actuators Devices 3987:92–102
Vunder V, Itik M, Poldsalu I et al (2014) Inversion based control of ionic polymer–metal composite actuators with nanoporous carbon based electrodes. Smart Mater Struct 23:025010
Wallmersperger T, Leo DJ, Kothera CS (2007) Transport modeling in ionomeric polymer transducers and its relationship to electromechanical coupling. J Appl Phys 101:024912
Wang XL, Oh IK, Lee S (2010) Electroactive artificial muscle based on crosslinked PVA/SPTES. Sens Actuators B 150:57–64
Wang Y, Zhu Z, Chen H et al (2014) Effects of preparation steps on the physical parameters and electromechanical properties of IPMC actuators. Smart Mater Struct 23:125015
Yamaue T, Mukai H, Asaka K, Doi M (2005) Electrostress diffusion coupling model for polyelectrolyte gels. Macromolecules 38:1349–1356
Zhang L, Yang Y (2007) Modeling of an ionic polymer–metal composite beam on human tissue. Smart Mater Struct 16:S197–S206
Zhu Z, Asaka K, Chang L et al (2013a) Multiphysics of ionic polymer-metal composite actuator. J Appl Phys 114:084902
Zhu Z, Asaka K, Chang L et al (2013b) Physical interpretation of deformation evolvement with water content of ionic polymer-metal composite actuator. J Appl Phys 114:184902
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this entry
Cite this entry
Asaka, K., Kim, K., Oguro, K., Shahinpoor, M. (2016). IPMCs as EAPs: Fundamentals. In: Carpi, F. (eds) Electromechanically Active Polymers. Polymers and Polymeric Composites: A Reference Series. Springer, Cham. https://doi.org/10.1007/978-3-319-31530-0_6
Download citation
DOI: https://doi.org/10.1007/978-3-319-31530-0_6
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-31528-7
Online ISBN: 978-3-319-31530-0
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics