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Development and Application of In Situ High-Temperature, High-Pressure Magic Angle Spinning NMR

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Book cover Modern Magnetic Resonance

Abstract

Solid-state NMR has served as an important tool for investigating chemical systems, not only to better understand the structure of materials, but also to probe the interactions that occur between two or more constituents. Disparities between realistic chemical environments and those experienced during spectroscopic measurements have challenged a firm understanding of these systems. To address this concern, novel methods of conducting NMR spectroscopy under conditions of high pressure and high temperature have been developed to simulate these harsh conditions. Herein, the advancement of this technology is described by detailing the design iterations as the methods have matured to their present state. Several applications from the fields of geochemistry, catalysis, and materials science are recounted that demonstrate the capabilities and usefulness of high-temperature, high-pressure MAS NMR across diverse facets of scientific study.

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Authors and Affiliations

  1. Pacific Northwest National Laboratory, Institute for Integrated Catalysis and Earth and Biological Science Directorate, Richland, WA, 99354, USA

    Nicholas R. Jaegers, Mary Y. Hu, David W. Hoyt, Yong Wang & Jian Zhi Hu

  2. Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA, 99163, USA

    Nicholas R. Jaegers & Yong Wang

Authors
  1. Nicholas R. Jaegers
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  2. Mary Y. Hu
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  3. David W. Hoyt
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  4. Yong Wang
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  5. Jian Zhi Hu
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Corresponding author

Correspondence to Jian Zhi Hu .

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Editors and Affiliations

  1. Royal Society of Chemistry, London, United Kingdom

    Graham A. Webb

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© 2018 This is a U.S. Government work and not under copyright protection in the US; foreign copyright protection may apply

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Jaegers, N.R., Hu, M.Y., Hoyt, D.W., Wang, Y., Hu, J.Z. (2018). Development and Application of In Situ High-Temperature, High-Pressure Magic Angle Spinning NMR. In: Webb, G. (eds) Modern Magnetic Resonance. Springer, Cham. https://doi.org/10.1007/978-3-319-28388-3_93

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