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Sol–Gel Abrasive Grains: History, Precursor Properties, and Microstructural Control

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Handbook of Sol-Gel Science and Technology

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Abstract

The sol–gel approach is ideally suited to the synthesis of abrasive grains. Abrasive grains are generally deployed in the size range (up to about 2 mm) that is easily obtainable by colloidal sol–gel processing, and the sol–gel approach allows for unprecedented control of abrasive particle properties. This paper provides a concise historical perspective of sol–gel abrasive materials, an overview of the synthesis and properties of boehmite, the critical alumina precursor material used in the production of commercial abrasive minerals, a discussion of the conversion of boehmite into abrasive grains, and examples of the microstructural control that has been achieved via manipulation of the chemistry of these sol–gel materials.

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References

  • Baker BR, Pearson RM. Water content of pseudoboehmite: a new model for its structure. J Catal. 1974;33:265–78.

    Article  Google Scholar 

  • Beggs RL, Lewis DJ, Madderra GK, Decker Jr LB Process for preparing sub-micron alumina particles. WO 92/19536, assigned to Vista Chemical Company, Austin. 1992.

    Google Scholar 

  • Bloch HS. Production of alumina. US patent 2,758,011, assigned to Universal Oil Products Company, Chicago. 1956.

    Google Scholar 

  • Block J. Dispersible alpha-aluminate monohydrate. GB 2 123 804 A, assigned to W.R. Grace and Co., New York. 1983.

    Google Scholar 

  • Brown RL, Bugosh J. Process for the preparation of water-dispersible fibrous alumina monohydrate. US patent 3,207,578, assigned to E.I. DuPont de Nemours and Company, Wilmington. 1965.

    Google Scholar 

  • Bugosh J. Fibrous alumina monohydrate and its production. US patent 2,915,475, assigned to E.I. DuPont de Nemours and Company, Wilmington. 1959.

    Google Scholar 

  • Bugosh J. Colloidal anisodiametric transition aluminas and process for making them. US patent 3,108,888, assigned to E.I. DuPont de Nemours and Company, Wilmington. 1963.

    Google Scholar 

  • Christoph GG, Cobato CE, Hofmann DA, Tettenhorst RT. The crystal structure of boehmite. Clay Clay Miner. 1979;27(2):81–6.

    Article  Google Scholar 

  • Coes Jr L. US patent 3,909,991. Filed 1970.

    Google Scholar 

  • Coes Jr L. Abrasives. New York: Springer; 1971.

    Google Scholar 

  • Cottringer TE, van de Merwe RH, Bauer R. Abrasive material and method for preparing the same. US patent 4,623,364, assigned to Norton Company, Worcester. 1986.

    Google Scholar 

  • Doss CJ, Zallen R. Raman studies of sol–gel alumina: finite-size effects in nanocrystalline AlO(OH). Phys Rev B. 1993;48(21):15626–37.

    Article  Google Scholar 

  • Erickson DD, Wood TE, Wood WP. Historical development of abrasive grain. Ceram Trans. 1998;95:73–83.

    Google Scholar 

  • Ervin Jr G, Osborne EF. J Geol. 1950;59:381.

    Article  Google Scholar 

  • Feng K, Pasek E. Salt of boehmite alumina. International patent publication WO 97/41063. 1997.

    Google Scholar 

  • Gerk AP. Process for improved densification of sol–gel produced alumina ceramics. US patent 4.574,003, assigned to Minnesota Mining and Manufacturing, St. Paul. 1986.

    Google Scholar 

  • Gieselmann MJ, Anderson MA. Effect of ionic strength on boehmite hydrogel formation. J Am Ceram Soc. 1989;72(6):980–5.

    Article  Google Scholar 

  • Gitzen WH. Alumina as a ceramic material. Columbus: The American Ceramic Society; 1970. p. 14.

    Google Scholar 

  • Gunage JC. Canadian patent 743715, assigned to The Carborundum Company. 1966.

    Google Scholar 

  • Hervert GL, Bloch HS. Production of alumina. US patent 2,871,095, assigned to Universal Oil Products Company, Des Plaines. 1959.

    Google Scholar 

  • Hervert GL, Bloch HS. Production of alumina. US patent 2,958,581, assigned to Universal Oil Products Company, Des Plaines. 1960.

    Google Scholar 

  • Julbe A, Guizard C, Larbot A, Cot L, Giroir-Fendler A. The sol–gel approach to prepare candidate microporous inorganic membranes for membrane reactors. J Membr Sci. 1993;77:137–53.

    Article  Google Scholar 

  • Kindl B, Carlsson DJ, Deslandes Y, Hoddenbagh MA. Preparation of alumina ceramics: the use of boehmite sols as dispersing agensts. Ceram Int. 1991;17:347–50.

    Article  Google Scholar 

  • Kumagai M, Messing GL. Enhanced densification of boehmite sol-gels by a-alumina seeding. Comm Am Ceram Soc. 1984;67:C230–1.

    Article  Google Scholar 

  • Kumagai M, Messing GL. Controlled transformation and sintering of a boehmite sol–gel by α-alumina seeding. J Am Ceram Soc. 1985;68(9):500.

    Article  Google Scholar 

  • Leitheiser M, Sowman H. Non-fused aluminum-oxide-based abrasive mineral. US patent 4,314,827, assigned to Minnesota Mining and Manufacturing Company, St. Paul. 1982.

    Google Scholar 

  • Mathers JP, Forester TE, Wood WP. Sol–gel preparation of non-oxide abrasives. Am Ceram Soc Bull. 1989;68(7):1330–6.

    Google Scholar 

  • Miller AW, Atkinson W. Process for the production of alumina. US patent 3,864,461, assigned to Laporte Industries Limited, London. 1975.

    Google Scholar 

  • Misuda K, Hasegawa T. Carrier medium for a coloring matter. US patent 4,879,166, assigned to Ashai Glass Company, Ltd., Tokyo. 1989.

    Google Scholar 

  • Monroe LD, Wood WP. Abrasive grits formed of ceramic containing oxides of aluminum and yttrium, method of making and using the same and products made therewith. US patent 4,770,671, assigned to Minnesota Mining and Manufacturing Company, St. Paul. 1988.

    Google Scholar 

  • Monroe LD, Wood TE. Alpha alumina-based abrasive grain containing silica and iron oxide. US patent 5,611,829, assigned to Minnesota Mining and Manufacturing Company, St. Paul. 1997.

    Google Scholar 

  • Morris ML, Wood TE. Ceramic alumina abrasive grains seeded with iron oxide. US patent 4,964,883, assigned to Minnesota Mining and Manufacturing, St. Paul. 1990.

    Google Scholar 

  • Napier DR. Process for producing colloidal-size particles of alumina monohydrate. US patent 3,357,791, assigned to Continental Oil Company, Ponca City. 1967.

    Google Scholar 

  • Pearson A, Fleming HL, Lacrousse MF. European patent application 0,147,167, assigned to Aluminum Company of America, Pittsburgh. 1985.

    Google Scholar 

  • Pullen JB, Mobley BL. US patent 3,919,403. assigned to W.R. Grace & Company, Ellicott City. 1975.

    Google Scholar 

  • Quinan JR, Patchett JE. Coated abrasive material comprising alumina-zirconia abrasive compositions. US patent 3,893,826, assigned to Norton Company, Worcester. 1975.

    Google Scholar 

  • Rowse RA, Watson GR. Zirconia-alumina abrasive grain and grinding tools. US patent 3,891,408, assigned to Norton Company, Worcester. 1975.

    Google Scholar 

  • Schwabel MG. Process for durable sol–gel produced alumina-based ceramics, abrasive grain and abrasive products. U.S. patent 4,744,802, assigned to Minnesota Mining and Manufacturing, St. Paul. 1988.

    Google Scholar 

  • Schwabel MG, Kendall PE. Alumina abrasive grains produced by sol–gel technology. Ceram Bull. 1991;70:1596–8.

    Google Scholar 

  • Tettenhorst RT, Corbato CE. Comparison of experimental and calculated x-ray powder diffraction data for boehmite. Clay Clay Miner. 1988;36(2):181–3.

    Google Scholar 

  • Tettenhorst RT, Hoffmann DA. Crystal chemistry of boehmite. Clay Clay Miner. 1980;28:373–80.

    Article  Google Scholar 

  • Tosterud M. Aluminum hydrate of low water content and process of producing the same. U.S. patent 1,953,201, assigned to Aluminum Company of America, Pittsburgh. 1934.

    Google Scholar 

  • Wefers K, Bell GM. Oxides and hydroxides of aluminum. Technical Paper No. 19. Aluminum Company of America; 1972.

    Google Scholar 

  • Weingärtner F. Process for manufacturing highly active, dispersed low apparent density aluminum hydrate. US patent 4,637,908, assigned to Swiss Aluminum Company, Chippia. 1987.

    Google Scholar 

  • Wilson SJ. The development of porous microstructures during the dehydration of boehmite. Mineralogical Magazine 1979;43:301–306.

    Google Scholar 

  • Wood WP. Abrasive grits formed of ceramic impregnation, method of making the same and products made therewith. US patents 5,164,348 and 5,312,789, assigned to Minnesota Mining and Manufacturing, St. Paul. 1994.

    Google Scholar 

  • Wood TE, Dislich H. An abbreviated history of sol–gel technology. In: Pope EJA, Sakka S, Klein LC, editors. Sol–gel science and technology. Westerville: The American Ceramic Society; 1995.

    Google Scholar 

  • Wood WP, Monroe LD, Conwell SL. Abrasive grits formed of ceramic containing oxides of aluminum and rare earth metal, method of making and products made therewith. US patent 4,881,951, assigned to Minnesota Mining and Manufacturing, St. PaulMN. 1989.

    Google Scholar 

  • Wood R, Fornasiero D, Ralston J. Electrochemistry of the boehmite-water interface. Colloids Surf. 1990;51:389.

    Article  Google Scholar 

  • Yoldas BE. Method of forming transmissive porous metal oxide optical layer of a vitreous substrate. US patent 4,271,210, assigned to Westinghouse Electric Corporation, Pittsburg. 1981.

    Google Scholar 

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Authors and Affiliations

  1. Minnesota Mining and Manufacturing Company, 11019 Ironwood Ave N, Stillwater, MN, 55082-9431, USA

    Thomas E. Wood, Dwight D. Erickson, Mark G. Schwabel & Chris J. Goodbrake

Authors
  1. Thomas E. Wood
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  2. Dwight D. Erickson
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  3. Mark G. Schwabel
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  4. Chris J. Goodbrake
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Corresponding author

Correspondence to Thomas E. Wood .

Editor information

Editors and Affiliations

  1. Rutgers University, Piscataway, New Jersey, USA

    Lisa Klein

  2. Madrid, Spain

    Mario Aparicio

  3. City University of New York, New York, USA

    Andrei Jitianu

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Wood, T.E., Erickson, D.D., Schwabel, M.G., Goodbrake, C.J. (2016). Sol–Gel Abrasive Grains: History, Precursor Properties, and Microstructural Control. In: Klein, L., Aparicio, M., Jitianu, A. (eds) Handbook of Sol-Gel Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-19454-7_60-1

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  • DOI: https://doi.org/10.1007/978-3-319-19454-7_60-1

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  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-319-19454-7

  • Online ISBN: 978-3-319-19454-7

  • eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics

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