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Processing of High Performance Catalysts

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Abstract

Silica and alumina are used commonly for catalyst supports. They have a role in metal-supported and metal oxide-supported catalyst applications. Because the sol-gel process produces high surface area materials, it is an excellent method for preparing catalyst supports. Surface areas need to be between 150 and 850 m2/g in most cases. The surface has to be thermally stable, as well. The surface has to have the right acid/base chemistry to sustain the catalytic activity. Besides silica and alumina, cerates, titanates, and zirconates by the sol-gel process are important components of catalysts supports.

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References

  • Bandosz TJ, Lin C, Ritter JA. Porosity and surface acidity of SiO2–A12O3 xerogels. J Catal. 1998;198:347–53.

    Google Scholar 

  • Barias OA, Holmen A, Blekkan EA. Propane dehydrogenation over supported Pt and Pt–Sn catalysts: catalysts preparation, characterization and activity measurements. J Catal. 1996;158:1–12.

    Article  Google Scholar 

  • Beck C, Mallat T, Burgi T, Baiker A. Nature of active sites in sol–gel TiO2–SiO2 epoxidation catalysts. J Catal. 2001;204:428–39.

    Article  Google Scholar 

  • Bradley DC, Mehrotra RC, Gauer DP. Metal Alkoxides. New York: Academic Press; 1978.

    Google Scholar 

  • Breitscheidel B, Zieder J, Schubert U. Metal complexes in inorganic matrices: 7 nanometer-sized, uniform metal particles in a SiO2 matrix by sol–gel processing of metal complexes. Chem Mater. 1991;3:559–66.

    Article  Google Scholar 

  • Cho IH, Parks SB, Cho SJ, Ryoo R. Investigation of Pt/γ-Al2O3 catalysts prepared by sol–gel method: XAFS and ethane hydrogenolysis. J Catal. 1998;173:295–303.

    Article  Google Scholar 

  • deMiguel S, Castro A, Scelza O, Fierro GJL, Soria J. FTIR and XPS study of supported PtSn catalysts used for light paraffins dehydrogenation. Catal Lett. 1996;36:201–6.

    Article  Google Scholar 

  • Dislich H. New routes to multicomponent oxide glasses. Angew Chem Int Ed Engl. 1971;10:363–70.

    Article  Google Scholar 

  • Guczi L, Schay Z, Stefler G, Mizukami F. Bimetallic catalysis: CO hydrogenation over palladium–cobalt catalysts prepared by sol/gel method. J Mol Catal A. 1999;141:177–85.

    Article  Google Scholar 

  • Guczi L, Stefler G, Schay Z, Kiricsi I, Mizukami F, Toba M, Niwa S. Structure and catalytic properties of cobalt–rhenium bimetallic catalysts prepared by sol/gel method and by ion exchange in NaY zeolite. Stud Surf Sci Catal. 2000;130B:1097–102.

    Article  Google Scholar 

  • Guczi L, Stefler G, Borko L, Koppany Z, Mizukami F, Toba M, Niwa S. Re–Co bimetallic catalysts prepared by sol–gel technique: characterization and catalytic properties. Appl Catal A Gen. 2003;246:79–86.

    Article  Google Scholar 

  • Haneda M, Mizushima T, Kakuta N, Ueno A, Sato Y, Matsuura S, Kasahara K, Sato M. Structural characterization and catalytic behavior of Al2O3-supported cerium oxide. Bull Chem Soc Jpn. 1993;66:1279–88.

    Article  Google Scholar 

  • Haneda M, Kintaichi Y, Shimada H, Hamada H. Selective reduction of NO with propene over Ga2O3–Al2O3: effect of sol–gel method on the catalytic performance. J Catal. 2000;192:137–48.

    Article  Google Scholar 

  • Harada M, Ono K, Tsuiki H, Ueno A, Mizushima T, Udagawa Y. Preparation of fine Fe–Ni alloy particles dispersed in silica. Chem Lett. 1986;15:1569–72.

    Article  Google Scholar 

  • Heinrichs B, Delhez P, Schoebrechts JP, Pirard JP. Palladium–silver sol–gel catalysts for selective hydrodechlorination of 1,2-dichloroethane into ethylene: 1 synthesis and characterization. J Catal. 1997;172:322–35.

    Article  Google Scholar 

  • Heinrichs B, Noville F, Schoebrechts JP, Pirard JP. Palladium–silver sol–gel catalysts for selective hydrodechlorination of 1,2-dichloroethane into ethylene: 2 surface composition of alloy particles. J Catal. 2000;192:108–18.

    Article  Google Scholar 

  • Heinrichs B, Schoebrechts JP, Pirard JP. Palladium–silver sol–gel catalysts for selective hydrodechlorination of 1,2-dichloroethane into ethylene: 3 kinetics and reaction mechanism. J Catal. 2001;200:309–20.

    Article  Google Scholar 

  • Hirashima H, Nishiwaki K, Miyakoshi A, Tuiki H, Ueno A, Nakabayashi H. Role of Ti–O–Zr in TiO2–ZrO2 catalyst for dehydrogenation of ethylbenzene. Bull Chem Soc Jpn. 1988;61:1945–51.

    Article  Google Scholar 

  • Ishiguro K, Ishikawa T, Kakuta N, Ueno A, Mitarai Y, Kamo T. Characterization of alumina prepared by sol–gel methods and its application to MoO3–CoO–Al2O3 catalyst. J Catal. 1990;123:523–33.

    Article  Google Scholar 

  • Ishikawa T, Ohashi R, Nakabayashi H, Kakuta N, Ueno A, Furuta A. Thermally stabilized transitional alumina prepared by fume pyrolysis of boehmite sols. J Catal. 1992;134:87–97.

    Article  Google Scholar 

  • Kaiser A, Gorsmann C, Schubert U. Influence of the metal complexation on size and composition of Cu/Ni nano-particles prepared by sol–gel processing. J Sol-Gel Sci Technol. 1997;8:795–9.

    Google Scholar 

  • Kaneko EY, Pulcinelli SH, da Silva VT, Santilli CV. Sol–gel synthesis of titania–alumina catalyst supports. Appl Catal A Gen. 2002;235:71–8.

    Article  Google Scholar 

  • Kim DH, Woo SI, Noh J, Yang OB. Synergistic effect of vanadium and zirconium oxides in the Pd-only three-way catalysts synthesized by sol–gel method. Appl Catal A Gen. 2001;207:69–77.

    Article  Google Scholar 

  • Klein S, Thorimbert S, Maier WF. Amorphous microporous titania–silica mixed oxides: preparation, characterization, and catalytic redox properties. J Catal. 1996;163:476–88.

    Article  Google Scholar 

  • Liu Z, Tabora J, Davis RJ. Relationship between microstructure and surface acidity of Ti–Si mixed oxide catalysts. J Catal. 1994;149:117–26.

    Article  Google Scholar 

  • Long RQ, Yang RT. Selective catalytic oxidation of ammonia to nitrogen over Fe2O3–TiO2 prepared with a sol–gel method. J Catal. 2002;207:158–65.

    Article  Google Scholar 

  • Lopez T, Solis RM, Novaro O. Proceedings of congress on catalysis VIII, 1984 July; Segovia, p. 695.

    Google Scholar 

  • Lopez T, Villa M, Gomez R. UV-VIS Diffuse reflectance spectroscopic study of Pt, Pd, and Ru catalysts supported on silica. J Phys Chem. 1991;95:1690–3.

    Google Scholar 

  • Lopez T, Bosch P, Asomoza M, Gomez R. Ru/SiO2-rimpregnated and sol–gel-prepared catalysts: synthesis, characterization, and catalytic properties. J Catal. 1992a;133:247–59.

    Article  Google Scholar 

  • Lopez T, Herrera L, Gomez R, Zou W, Robinson K, Gonzalez RD. Improved mechanical stability of supported Ru catalysts: preparation by sol–gel method. J Catal. 1992b;136:621–5.

    Article  Google Scholar 

  • Lopez T, Asomoza M, Bosch P, Figueroa EG, Gomez R. Spectroscopic characterization and catalytic properties of sol–gel Pd/SiO2 catalysts. J Catal. 1992c;138:463–73.

    Article  Google Scholar 

  • Lopez T, Gomez R, Novaro O, Solis AR, Mora ES, Castillo S, Poulain E, Magadan JMM. Sol–gel Ru/SiO2 Catalysts: Theretical and experimental determination of the Ru-in-silica structures. J Catal. 1993;141:114–23.

    Article  Google Scholar 

  • Lopez T, Bosch P, Tzompantzi F, Gomez R, Navarrete J. Effect of sulfation methods on TiO2–SiO2 sol–gel catalyst acidity. Appl Catal A Gen. 2000;197:107–17.

    Article  Google Scholar 

  • Machida M, Arai H. Design of high-temperature combustion catalysts using metal alkoxides In: Ueno A, Mizukami F, Sodesawa T, editors. Catalyst preparation from metal alkoxides. IPC Publisher; 1993. p. 216 (in Japanese).

    Google Scholar 

  • Machida M, Eguchi K, Arai H. Effect of additives on the surface area of oxide supports for catalytic combustion. J Catal. 1987a;103:385–93.

    Article  Google Scholar 

  • Machida M, Eguchi K, Arai H. Preparation and characterization of large surface area BaO·6Al2O3. Bull Chern Soc Jpn. 1987b;61:3659–65.

    Article  Google Scholar 

  • Machida M, Eguchi K, Arai H. Analytical electron microscope analysis of the formation of BaO·6Al2O3. J Am Ceram Soc. 1988;71:1142–7.

    Article  Google Scholar 

  • Machida M, Eguchi K, Arai H. Catalyitic properties of BaMAl11 O19–α. J Catal. 1989;120:377–86.

    Article  Google Scholar 

  • Machida M, Eguchi K, Arai H. Effect of structural modification on the catalytic property of Mn-substituted hexaaliminate. J Catal. 1990;123:477–85.

    Article  Google Scholar 

  • Machida M, Shiomitsu T, Eguchi K, Haneda A, Arai H. secondary-ion mass spectrometric analysis of anisotoropic oxygen self-diffusion in barium hexaaluminate single crystals. J Mater Chem. 1992;2:455–8.

    Article  Google Scholar 

  • Martino A, Sault AG, Kawola JS, Boespflug E, Phillips MLFA. sintering study of novel sol–gel-based nanocluster catalysts. J Catal. 1999;187:30–8.

    Article  Google Scholar 

  • Matsumoto Y, Mita K, Hashimoto K, Tokoroyama T. Preparation of silica–alumina catalysts by the sol–gel method and its activity for the Diels–Alder reaction of isoprene and acrylaldehyde. Appl Catal A Gen. 1995;131:L1–6.

    Article  Google Scholar 

  • Mazdiyasni KS, Dolloff RT, Smith JS. Preparation of high-purity submicron barium titanate powders. J Am Ceram Soc. 1969;52:523–33.

    Article  Google Scholar 

  • Misono M, Hirao Y, Yokokawa C. Reduction of nitrogen oxides with hydrocarbons catalyzed by bifunctional catalysts. Catal Today. 1997;38:157–62.

    Article  Google Scholar 

  • Mizushima T. Silica-supported Fe–Ni alloy catalysts from metal alkoxides. In: Ueno A, Mizukami F, Sodesawa T, editors. Catalyst preparation from metal alkoxides. IPC Publisher; 1993. p. 92 (in Japanese).

    Google Scholar 

  • Mizushima Y, Hori M. Alumina aerogel for support of a methane combustion catalyst. Appl Catal A Gen. 1992;88:137–48.

    Article  Google Scholar 

  • Mizushima T, Tohji K, Udagawa Y, Harada M, Ishikawa M, Ueno A. Characterization of silica-supported bimetallic iron–nickel catalysts by EXAFS. J Catal. 1988;112:282–9.

    Article  Google Scholar 

  • Morke W, Lamber R, Schubert U, Breitscheidel B. Metal complexes in inorganic materials 11: composition of highly dispersed bimetallic Ni Pd alloy particles prepared by sol–gel processing; electron microscopy and ferromagnetic resonance study. Chem Mater. 1994;6:1659–66.

    Article  Google Scholar 

  • Nakabayashi H. Properties of acid sites on TiO2–SiO2 and TiO2–Al2O3 mixed oxides measured by infrared spectroscopy. Bull Chem Soc Jpn. 1992;65:914–6.

    Article  Google Scholar 

  • Nakabayashi H Mixed metal oxides containing TiO2–finely divided particles. In: Ueno A, Mizukami F, Sodesawa T, editors. Catalyst preparation from metal alkoxides. IPC Publisher; 1993. p. 292 (in Japanese)

    Google Scholar 

  • Nakabayashi H, Kakuta N, Ueno A. Strong acid sites generated on small-sized anatase. Bull Chem Soc Jpn. 1991;64:2428–32.

    Article  Google Scholar 

  • Nakanishi K, Soga N. Phase separation in gelling silica–organic polymer solution: systems containing poly(sodium styrenesulfonate). J Am Ceram Soc. 1991;74:2518–30.

    Article  Google Scholar 

  • Nakanishi K, Komura H, Takahashi R, Soga N. Phase separation in silica sol–gel system containing poly(ethylene oxide): 1 phase relation and gel morphology. Bull Chem Soc Jpn. 1994;67:1327–35.

    Article  Google Scholar 

  • Nanba T, Uemura A, Ueno A, Haneda M, Hamada H, Kakuta N, Miura H, Ofune H, Udagawa Y. Studies on active species for selective catalytic reduction of NO on alumina-supported cobalt oxide catalysts. Bull Chem Soc Jpn. 1998;71:2331–7.

    Article  Google Scholar 

  • Nishiwaki K, Kakuta N, Ueno A, Nakabayashi H. Generation of acid sites on finly divided TiO2. J Catal. 1989;118:498–501.

    Article  Google Scholar 

  • Niwa S, Mizukami F, Isoya S, Tsuchiya T, Shimizu K, Imai S, Imamura J. Partial hydrogenation of benzene with ruthenium catalysts prepared by a chemical mixing procedure – preparation and properties of the catalysts. J Chem Technol Biotechnol. 1986a;36:236–46.

    Article  Google Scholar 

  • Niwa S, Mizukami F, Kuno M, Takeshita K, Nakamura K, Tsuchiya T, Shimizu K, Imamura J. Selective hydrogenation of benzene to cyclohexene with new ruthenium catalysts prepared by a chemical mixing procedure. J Mol Catal. 1986b;34:247–9.

    Article  Google Scholar 

  • Noh J, Yang OB, Kim DH, Woo SI. Characteristics of the Pd-only three-way catalysts prepared by sol–gel method. Catal Today. 1999;53:575–82.

    Article  Google Scholar 

  • Noto SY, Sachtler WMH. Infrared spectra of carbon monoxide adsorbed on supported palladium and palladium–silver alloys. J Catal. 1974;32:315–24.

    Article  Google Scholar 

  • Ochoa R, van Woet H, Lee WH, Subramanian R, Kugler E, Eklund PC. Catalytic degradation of medium density polyethylene over silica-alumina supports. Appl Catal A Gen. 1996;49:119–36.

    Google Scholar 

  • Palazzi C, Oliva L, Signoretto M, Strukul G, Catal J. Microporous zirconia–silica mixed oxides made by sol–gel as catalysts for the liquid-phase oxidation of olefins with hydrogen peroxide. J Catal. 2000;194:286–93.

    Article  Google Scholar 

  • Pecchi G, Reyes P, Concha I, Fierro JLG. Methane combustion on Pd/SiO2 sol–gel catalysts. J Catal. 1998;179:309–14.

    Article  Google Scholar 

  • Sachtler WMH. Chemisorption complexes on alloy surfaces. Catal Rev Sci Eng. 1976;14:193–210.

    Article  Google Scholar 

  • Sakka S. In: Tomozawa M, Doremus R, editors. Treatise on Materials Science and Technology, Glass III22 New York: Academic; 1982. p. 129–67.

    Google Scholar 

  • Sakka S. Science of Sol–gel Technology. Agune-Syoufu publishing Co; 1988. (in Japanese).

    Google Scholar 

  • Sarbu C, Delman B. Nanoscale composition inhomogeneity in silica–aluminas prepared by various methods. Appl Catal A Gen. 1999;185:85–97.

    Article  Google Scholar 

  • Sault AG, Martino A, Kawola JS, Boespflug E. Novel sol–gel-based Pt nanocluster catalysts for propane dehydrogenation. J Catal. 2000;191:474–9.

    Article  Google Scholar 

  • Schubert U, Amberg-Schwab S, Breitscheidel B. Metal complexes in inorganic matrixes: 4 Small metal particles in palladium–silica composites by sol–gel processing of metal complexes. Chem Mater. 1989a;1:576–8.

    Article  Google Scholar 

  • Schubert U, Egger C, Rose K, Alt C. Metal-complexes in inorganic matrices. 3. catalytic activity of Rh(CO)Cl(Pr3)2 heterogenised by the sol–gel method. J Mol Catal. 1989b;55:330–9.

    Article  Google Scholar 

  • Seker E, Gulari E. Improved N2 selectivity for platinum on alumina prepared by sol–gel technique in the reduction of NOX by propene. J Catal. 1998;179:339–42.

    Article  Google Scholar 

  • Seker E, Gulari E. Activity and N2 selectivity of sol–gel prepared Pt/alumina catalysts for selective NOX reduction. J Catal. 2000;194:4–13.

    Article  Google Scholar 

  • Seker E, Gulari E. Single step sol–gel made gold on alumina catalyst for selective reduction of NOX under oxidizing conditions: effect of gold precursor and reaction conditions. Appl Catal A Gen. 2002;232:203–17.

    Article  Google Scholar 

  • Seker E, Yasyerli N, Gulari E, Lambert C, Hammerle RNO. reduction by urea under lean conditions over single-step sol–gel Cu/alumina catalyst. J Catal. 2002;208:15–20.

    Article  Google Scholar 

  • Shannon DD, Pask J. Kinetics of the anatase–rutile transformation. J Am Ceram Soc. 1965;48:391–8.

    Article  Google Scholar 

  • Shibata K, Kiyoura T, Kitagawa J, Sumiyoshi T, Tanabe K. Acid properties of binary metal oxides. Bull Chern Soc Jpn. 1973;46:2985–8.

    Article  Google Scholar 

  • Sodesawa T, Nagacho M, Onodera A, Nozaki F. Dehydrogenation of methanol to methyl formate over Cu-SiO2 catalysts prepared by ion exchange method. J Catal. 1986;102:460–3.

    Article  Google Scholar 

  • Sodesawa T, Shibasaki M, Sato S, Nozaki F. Active promotion effects of La2O3 addition to Cu-SiO2 catalyst prepared by alkoxide method on steam reforming of methanol. First conference on advanced catalytic science and technology (TOCAT); 1990 July 1–5; Tokyo: Kodansya Ltd. 1991; vol. 1, pp. 467–468.

    Google Scholar 

  • Sodesawa T., Sato S., Nozaki F. Proceedings of 10th International Congress on Catalysis, July 19–24, 1992, Budapest. p. 82.

    Google Scholar 

  • Takahashi R, Sato S, Sodesawa T, Yabuki M. Silica–alumina catalyst with bimodal pore structure prepared by phase separation in sol–gel process. J Catal. 2001;200:197–202.

    Article  Google Scholar 

  • Tamagawa H, Oyama K, Yamaguchi T, Tanaka H, Tsuiki H, Ueno A. Control of Ni metal particle size in Ni/SiO2 catalysts by calcinations and reduction temperatures. J Chem Soc Faraday Trans. 1987;1(83):3189–97.

    Article  Google Scholar 

  • Tanaka S, Mizukami F, Niwa S, Toba M, Tasi G, Kunimori K. Highly selective formation of aldehydes in the hydrogenation of the corresponding acid chlorides with silica-supported palladium catalysts prepared by a complexing agent-assisted sol–gel method. Appl Catal A Gen. 2002;229:175–80.

    Article  Google Scholar 

  • Tanev PT, Chibwe M, Pinnavia TJ. Titanium-containing mesoporous molecular-sieves for catalytic-oxidation of aromatic-compounds. Nature. 1994;368:321–3.

    Article  Google Scholar 

  • Teichner SJ, Nicolaon GA, Vicarini MA, Gardes GEE. Inorganic oxide aerogels. Adv Colloid Interf Sci. 1976;5:245–73.

    Article  Google Scholar 

  • Tohji K, Udagawa Y, Tanabe S, Ueno A. Catalyst preparation procedure probed by EXAFS spectroscopy: 1 nickel on silica. J Am Chem Soc. 1984;106:612–7.

    Article  Google Scholar 

  • Ueno A, Suzuki H, Kotera Y. Particle-size distribution of nickel dispersed on silica and its effects on hydrogenation of propionaldehyde. J Chem Soc Faraday Trans. 1983;1(79):127–36.

    Article  Google Scholar 

  • Wang Z, Liu Q, Yu J, Wu T, Wang G. Surface structure and catalytic behavior of silica-supported copper catalysts prepared by impregnation and sol–gel methods. Appl Catal A Gen. 2003;239:87–94.

    Article  Google Scholar 

  • Watson RB, Ozkan USK. Mo catalysts supported over sol–gel silica–titania mixed oxides in the oxidative dehydrogenation of propane. J Catal. 2000;191:12–29.

    Article  Google Scholar 

  • Yoda K, Kimoto K, Toda T. Ester exchange reaction between dimethyl terephthalate and ethylene glycol using metal compounds as catalalysts. Kogyou Kagaku Zasshi. 1964;67:909–14. (in Japanese).

    Article  Google Scholar 

  • Yoldas BE. A transparent porous alumina. Am Ceram Soc Bull. 1975a;54:286–8.

    Google Scholar 

  • Yoldas BE. Alumina sol preparation from alkoxide. Am Ceram Soc Bull. 1975b;54:289–90.

    Google Scholar 

  • Yoldas BE, Partlow DP. Formation of continuous beta alumina films and coating at low temperatures. Am Ceram Soc Bull. 1980;59:640–2.

    Google Scholar 

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Ueno, A. (2018). Processing of High Performance Catalysts. In: Klein, L., Aparicio, M., Jitianu, A. (eds) Handbook of Sol-Gel Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-19454-7_24-1

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  • DOI: https://doi.org/10.1007/978-3-319-19454-7_24-1

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