Abstract
Nanoparticles of three different categories of condensed matter, namely, metal, semiconductor, and insulator, exhibit fluorescence through radiative recombination of charge carriers though the origin and mechanism of light emission is vastly different. Whereas fluorescence from metal nanoparticles, e.g., Au and Ag, falls in the visible region due to sp–d band transition of electrons, the fluorescence gets enhanced due to interaction with localized surface plasmon. Semiconductor quantum dots form a special class of fluorescent materials where the emission color can be tuned by tailoring the particle size as a manifestation of quantum confinement effect. Doped semiconductor nanoparticles offer another category of multifunctional materials with tunable emission and desired electronic/magnetic properties. Rare earth-doped insulators are conventionally used as phosphors for various display and lighting applications. Nanoparticles of various rare earth-doped complex insulators emit intense monochromatic light and can be synthesized by various techniques such as sol–gel, wet chemistry, coprecipitation, hydrothermal, etc. Synthesis and elimination of surface states by passivation/capping play an important role in arresting non-radiative pathways to augment fluorescence efficiency of nanoparticles.
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V.K. La Mer, R.H. Dinegar, J. Am. Chem. Soc. 72, 4847 (1950)
V.K. La Mer, Ind. Eng. Chem. 44, 1270 (1952)
W. Ostwald, Z. Phys. Chem. 37, 385 (1901)
E.M. Pileni, Nanocrystals Forming Mesoscopic Structures, Wiley-VCH, Weinheim, 2005
C.W. Song, S.C. Haur, A.T.S. Wee, Science at the Nanoscale, An Introductory Textbook (Pan Stanford Publishing, Singapore 2009). www.panstanford.com/nanotextbook
A.P. Alivisatos, J. Phys. Chem. 110, 13226–13239 (1996)
R. Viswanatha, D.D. Sarma, Nanomaterials chemistry, in Growth of Nanocrystals in Solution, ed. by C.N.R. Rao, A. Muller, A.K. Cheetham (Wiley-VCH, Weinheim, 2007). ISBN 978-3-527-31664-9
Y. Qian, Adv. Mater. 11, 1101 (1999)
S. Shionoya, W.M. Yen (eds.), Phosphors Handbook (CRC Press, Washington, DC, 1999), pp. 238–255
G. Blasse, B. Grabmaier, Luminescent Materials (Springer, New York, 1994)
M. Faraday, Philos. Trans. R. Soc. Lond. 147, 145–181 (1857)
A. Mie, Phys. IV 25, 377–455 (1908)
A. Moordian, Phys. Rev. Lett. 22, 185–187 (1969)
S.A. Maier, Plasmonics: Fundamentals and Applications (Springer, New York, 2007), p. 173. p. 75
J. Turkevich, P.C. Stevenson, J. Hellier, Discuss. Faraday Soc. 11, 55–75 (1951)
P.C. Lee, D.J. Meisel, J. Phys. Chem. B 86, 3391–3395 (1982)
J.A. Creighton, C.G. Blatchford, M.G. Albrecht, J. Chem. Soc. Faraday Trans. II 75, 790–798 (1979)
D.D. Evanoff Jr., G. Chumanov, J. Phys. Chem. 6, 1221–1231 (2005)
X. Lu, M. Rycenga, S.E. Skrabalak et al., Annu. Rev. Phys. Chem. 60, 167–192 (2009)
H. Zhang, Y. Li, I.A. Ivanov, Y. Qu et al., Angew. Chem. Int. Ed. 49, 2865–2868 (2010)
M. Brust, M. Walker, D. Bethell et al., J. Chem. Soc. Chem. Commun. 801 (1994). doi:10.1039/C39940000801
W.W. Weare, S.M. Reed, M.G. Warner et al., J. Am. Chem. Soc. 122, 12890 (2000)
S.W. Joo, W.J. Kim, W.S. Yoon et al., J. Raman Spectrosc. 34, 271 (2003)
T.K. Misra, L.Y. Liu, J. Nanoparticle Res. 11, 1053 (2009)
B.M. Amoli, S. Gumfekar, A. Hu et al., J. Mater. Chem. 22, 20048 (2012)
E. Dulkeith et al., Phys. Rev. B 70, 205424 (2004)
S. Link, M.A. El-Sayed, Int. Rev. Phys. Chem. 19(3), 409–453 (2000)
R.W. Boyd, Non-linear Optics (Academic, San Diego, 2003)
J.P. Wilcoxon, J.E. Martin, F. Paraspour, B. Wiedman, D.F. Kelly, J. Chem. Phys. 108, 9137 (1998)
M.B. Mohamed, V. Volkov, S. Link, M.A. El-Syed, Chem. Phys. Lett. 317, 517 (2000)
D. Basak, S. Karan, B. Mallik, Chem. Phys. Lett. 420, 115 (2006)
A.P. Zhang, J.Z. Zhang, Y. Fang, J. Lumin. 128, 1635 (2008)
O.A. Yeschenko, I.M. Dmitruk et al., Mater. Sci. Eng. B 137, 247 (2007)
Q. Darugar, W. Qian, M.A. El-Syed, M.P. Pileni, J. Phys. Chem. B 110, 143 (2006)
A. Oleg, I.M. Dmitruk et al., Phys. Rev. B 79, 235438 (2009)
A.I. Ekimov, A.A. Onushchenko, JETP Lett. 34, 345–349 (1981)
M.A. Reed, J.N. Randall, R.J. Aggarwal et al., Phys. Rev. Lett. 60(6), 535–537 (1988)
H. Weller, Adv. Mater. 5, 88 (1993)
L. Brus, J. Phys. Chem. 90, 2555 (1986) and references cited therein
Y. Wang, N. Herron, J. Phys. Chem. 95, 525 (1991) and references cited therein
W.E. Buhro, V.L. Colvin, Semiconductor nanocrystals – shape matters. Nat. Mater. 2, 138 (2003)
Y. Mo, Y. Tang, F. Gao et al., Ind. Eng. Chem. Res. 51, 5995–6000 (2012)
X. Peng, J. Wickham, A.P. Alivisatos, J. Am. Chem. Soc. 120, 5343 (1998)
M.J. Bowers II, J.R. McBride, S.J. Rosenthal et al., J. Am. Chem. Soc. 127, 15378–15379 (2005)
T.E. Rosson, S.M. Claiborne, J.R. McBride et al., J. Am. Chem. Soc. 134, 8006–8009 (2012)
U.K. Gautam, K. Sardar, F.L. Deepak et al., Pramana J. Phys. 65(4), 549–564 (2005)
L. Spanhel, H. Haase, A. Henglein, J. Am. Chem. Soc. 109, 5649 (1987)
A. Aboulaich, D. Billaud, M. Abyan, L. Balan et al., ACS Appl. Mater. Interfaces 4, 2561–2569 (2012)
A.M. Suhail, M.J. Khalifa, N.M. Saeed et al., Eur. Phys. J. Appl. Phys. 49, 30601 (2010)
Y.T. Didenko, K.S. Suslick, J. Am. Chem. Soc. 127(35), 12196–12197 (2005)
H. Zhang, B. Hu, L. Sun et al., Nano Lett. 11, 5356–5361 (2011)
C.B. Murray, D.J. Norris, M.G. Bawendi, J. Am. Chem. Soc. 115(19), 8706 (1993)
S. Neeleshwar, C. Chen et al., Phys. Rev. B 71, 201307 (2005)
C.R. Bullen, P. Mulvaney, Nano Lett. 4, 2303 (2004)
W.W. Yu, L. Qu, X. Peng, Chem. Mater. 15, 2854 (2003)
A.M. Smith, S. Nie, Acc. Chem. Res. 43, 190–200 (2010). doi: 10.1021/ar9001069
A.V. Malko, Y.S. Park, S. Sampat et al., Nano Lett. 11(12), 5213–5218 (2011)
H. Sun, H. Zhang, J. Zhang, H. Wei et al., J. Mater. Chem. 19, 6740–6744 (2009)
N. Gaponik, A.L. Rogach, Phys. Chem. Chem. Phys. 12, 8685–8693 (2010)
U. Ozgur, Y.I. Alivov, C. Liu, A. Teke, M.A. Reshchikov et al., J. Appl. Phys. 98, 041301 (2005) and references cited therein
I.Y. Jung et al., Appl. Phys. Lett. 87, 191908 (2005)
M.H. Huang, S. Mao, H. Feick et al., Science 292, 1897 (2001)
X. Fang, Y. Bando, U.K. Gautam, Crit. Rev. Solid State Mater. Sci. 34, 190–223 (2009)
X. Xu, C. Xu, Z. Shi et al., J. Appl. Phys. 111, 083521 (2012)
L. Irimpan et al., J. Appl. Phys. 102, 063524 (2007)
D. Haranath, S. Sahai, A.G. Joshi et al., Nanotechnology 20(42), 425701 E (2009)
V.A. Fonoberov, A.A. Balandin, Chapter 38, in A Handbook of Semiconductor Nanostructures and Nanodevices, ed. by A.A. Balandin, K.L. Wang, vol. 1 (American Scientific Publishers, Los Angeles 2006), pp. 1–40. ISBN 1-58883-973-X
S. Chawla, K. Jayanthi et al., Mater. Des. 31, 1666–1670 (2010)
S. Chawla, K. Jayanthi et al., J. Alloys Compd. 459, 457–460 (2008)
B. Choudhary, S. Chawla et al., Curr. Appl. Phys. 10, 807–812 (2010)
K. Jayanthi, S. Chawla et al., Appl. Surf. Sci. 255, 5869–5875 (2009)
K. Jayanthi, S. Chawla et al., J. Phys. Chem. C 114, 18429–18434 (2010)
K. Jayanthi, S.V. Manorama, S. Chawla, J. Phys. D Appl. Phys. 46, 325101 (2013)
S. Chawla, K.J. Sharda, Appl. Surface Sci. 257, 2935–2939 (2011)
J.M. Coye, M. Venkatesan, C.B. Fitzgerald, Nature 4, 17–179 (2005)
S. Chawla, K. Jayanthi, R.K. Kotnala, Phys. Rev. B 79, 125204 (2009)
S. Chawla, K. Jayanthi, R.K. Kotnala, J. Appl. Phys. 106, 113923 (2009)
S. Chawla, M. Saroha, R.K. Kotnala, Electron. Mater. Lett. 10, 73–80 (2013)
H. Li, W.Y. Shih, W.H. Shih, Nanotechnology 18, 205604 (2007)
H. Li, W.Y. Shih, W.H. Shih, Ind. Eng. Chem. Res. 49, 578–582 (2010)
B. Barman, K.C. Sarma, Chalcogenide Lett. 8, 171–176 (2011)
K. Tarasov, D. Houssein, M. Destarac et al., New J. Chem. 37, 508 (2013)
A. Mandal, A. Dandapat, G. De, Analyst 137, 765 (2012)
G.Y. Lan, Y.W. Lin, Y.F. Huanga et al., J. Mater. Chem. 17, 2661–2666 (2007)
R.N. Bhargava, D. Gallagher, X. Hong et al., Phys. Rev. Lett. 72, 416 (1994)
B. Bhattacharjee, D. Ganguli, K. Iakoubovskii et al., Bull. Mater. Sci. 25, 175 (2002)
B.Y. Geng, L.D. Zhang, G.Z. Wang et al., Appl. Phys. Lett. 84, 2157 (2004)
H.C. Warad, S.C. Ghosh, B. Hemtanon, C. Thanachayanont, J. Dutta, Sci. Technol. Adv. Mater. 6, 296–301 (2005)
A.A. Khosravi, M. Kundu, L. Jatwa et al., Appl. Phys. Lett. 67, 2702 (1995)
S. Lee, D. Song, D. Kim et al., Mater. Lett. 58, 342 (2004)
K. Jayanthi, S. Chawla, H. Chander et al., Cryst. Res. Technol. 42, 976–982 (2007)
W. Chen, J.O. Malm, V. Zwiller et al., Phys. Rev. B 61, 11021 (2000)
S.J. Xu, S.J. Chua, B. Liu et al., Appl. Phys. Lett. 73, 478 (1998)
S. Hou, Y. Yuen, H. Mao, J. Wang, Z. Zhu, J. Phys. D Appl. Phys. 42, 215105 (2009)
A. Hazarika, A. Layek, S. De et al., Phys. Rev. Lett. 110, 267401 (2013)
S. Hohng, T. Ha, J. Am. Chem. Soc. 126, 1324–1325 (2004)
X. Wang, X. Ren, K. Kahen et al., Nature 459, 686689 (2009)
F. Garcia-Santamaria, Y. Chen, J. Vela et al., Nano Lett. 9, 3482–3488 (2009)
B. Fisher, J.M. Caruge, D. Zehender et al., Phys. Rev. Lett. 94, 087403 (2005)
S.A. Ivanov, J. Nanda, A. Piryatinski et al., J. Phys. Chem. B 108, 10626–10630 (2004)
S. Gao, C. Zhang, Y. Liu et al., Opt. Express 19, 5528–5535 (2011)
J.L. Machol, F.W. Wise, R.C. Patel et al., Phys. Rev. B 48, 2819 (1993)
A. Lipovskii, E. Kolobkova, V. Petrikov et al., Appl. Phys. Lett. 71(23), 3406 (1997)
B.N. Pal, I. Robel, A. Mohite, R. Laocharoensuk et al., Adv. Funct. Mater. 22, 1741–1748 (2012)
W.K. Bae, J. Joo, L.A. Padilha et al., J. Am. Chem. Soc. 134, 20160–20168 (2012)
K. Sardar, C.N.R. Rao, Adv. Mater. 16, 425–429 (2004)
C. Chen, C. Liang, Tamkang J. Sci. Eng. 5, 223–226 (2002)
S. Cai, T. Tsuzuki, T.A. Fisher et al., J. Nanoparticle Res. 4, 367–371 (2002)
S. Gao, L. Zhu, Y. Xie, X. Qian, Eur. J. Inorg. Chem. 2004(3), 557–561 (2004)
S. Li, A. Waag, J. Appl. Phys. 111, 071101 (2012)
M. Kumar, M.K. Rajpalke, T.N. Bhat et al., Appl. Phys. 110, 114317 (2011)
H. Amano, M. Aoki, J. Appl. Phys. 19, 2395 (1980)
H. Amano, M. Kitoh, K. Hiramasu, I. Akasaki, J. Electrochem. Soc. 137, 1639 (1990)
D. Gammon, E.S. Snow, B.V. Shanabrook et al., Phys. Rev. Lett. 76(16), 3005 (1996)
X. Wang, J. Zhuang, Q. Peng et al., Nature 437, 121–124 (2005)
F. Bai, D. Wang, Z. Huo et al., Angew. Chem. Int. Ed. 46, 6650–6653 (2007)
W. Guo, Q. Peng, L. Yadong, Acc. Chem. Res. 44, 322–332 (2011)
J. Liu, Y. Li, J. Mater. Chem. 17, 1797–1803 (2007)
G. Mialon, S. Turkcan, A. Alexandron et al., J. Phys. Chem. C 113, 18699–18706 (2009)
V. Natarajan, A.R. Dhobale, C.H. Lu, J. Lumin. 129, 290–293 (2009)
H.K. Yang, J.W. Chung, B.K. Moon et al., J. Lumin. 129, 492–495 (2009)
A.F. Khan, D. Haranath, R. Yadav, S. Singh, V. Dutta, S. Chawla, Appl. Phys. Lett. 93, 073103 (2008)
A. Manavbasi, J.C. LaCombe, J. Mater. Sci. 42, 252–258 (2007)
D. Haranath, H. Chander, P. Sharma, S. Singh, Appl. Phys. Lett. 89, 173118 (2006)
H.H. Kwak, S.J. Kim, H.H. Yoon, J. Electroceram. 23, 397–401 (2009)
S. Chawla, T. Roy, K. Majumdar et al., J. Exp. Nanosci. 1–9, 714481 (2012). doi:10.1080/17458080
Y. Du, Y. Zhang, K. Huang et al., Dalton Trans. 42, 8041 (2013)
C. Feldmann, M. Roming, K. Trampert, Small 2, 1248–1250 (2006)
J.W. Li, T. Watanabe, N. Sakamoto et al., Chem. Mater. 20, 2095–2105 (2008)
M. Zeuner, P.J. Schmidt, W. Schnick, Chem. Mater. 21, 2467 (2009)
S.M. Loureiro, A. Setlur, W. Heward et al., Chem. Mater. 17, 3108–3113 (2005)
Q.Y. Zhang, C.H. Yang, Appl. Phys. Lett. 90, 021107 (2007)
F. Auzel, F.C.R. Acad. Sci. (Paris) 262(15), 1016 (1966)
V. Ovsyankin, P.P. Feofilov, JETP Lett. 3(12), 317 (1966)
J.F. Suyver et al., Opt. Mater. 27, 1111 (2005)
F. Auzel, Chem. Rev. 104, 139 (2004)
F. Wang et al., Nature 463, 1061–1065 (2010)
F. Wang, D. Banerjee, Y. Liu, X. Chen et al., Analyst 135, 1839–1854 (2010)
T. Trupke, M.A. Green, P. Wũrfel, J. Appl. Phys. 92(7), 4117 (2002)
A. Shalav, R.S. Richards, T. Trupke et al., Appl. Phys. Lett. 86, 013505–013507 (2005)
M. He et al., Adv. Funct. Mater. 21, 4470–4477 (2011)
G. Yi et al., Chem. Mater. 14, 2910–2914 (2002)
L.A. Torres et al., J. Phys. D Appl. Phys. 37, 2489–2495 (2005)
E.D. Rosa et al., Appl. Phys. Lett. 87, 241912 (2005)
V. Fiorenzo, N. Rafik, M. Venkataramanan et al., Adv. Funct. Mater. 19, 1–6 (2009)
A.F. Khan, R. Yadav, P.K. Mukhopadhya, S. Singh, C. Dwivedi, V. Dutta, S. Chawla, J. Nanoparticle Res. 13, 6837–6846 (2011)
X. Qin, T. Yokomori, Y. Ju, Appl. Phys. Lett. 90, 073104 (2007)
Y. Chen, K. Munechika, I.J. Plante, A.M. Munro, S.E. Skrabalak, Y. Xia, D.S. Ginger, Appl. Phys. Lett. 93, 053106 (2008)
K. Munechika, Y. Chen et al., Nano Lett. 10, 2598–2603 (2010)
W. Feng, L.D. Sun, C.H. Yan, Chem. Commun. 29, 4393–4385 (2009)
S. Schietinger, T. Aichele, H. Wang, T. Nann, O. Benson, Nano Lett. 10, 134–138 (2010)
Z. Buch, V. Kumar, H. Mamgain, S. Chawla, Chem. Commun. 49, 9485 (2013)
Z. Buch, V. Kumar, H. Mamgain, S. Chawla, J. Phys. Chem. Lett. 4, 3834–3838 (2013)
Acknowledgments
I thank my students Zubair Buch for the assistance in writing metal nanoparticles part; Rupali Das for literature survey, editing the manuscript, and references; and A.F. Khan for drawing Fig. 1. Effort has been made to acknowledge the sources from where information has been gathered; if some sources remain unreferred to, my sincere apology to them.
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Chawla, S. (2016). Nanoparticles and Fluorescence. In: Aliofkhazraei, M. (eds) Handbook of Nanoparticles. Springer, Cham. https://doi.org/10.1007/978-3-319-15338-4_43
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