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Nanoparticle Size Effect on Some Magnetic Properties

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Handbook of Nanoparticles

Abstract

Nanoparticles exhibit, from a magnetic point of view, various anomalies and specific magnetic properties, different from those of the bulk with the same chemical composition. Knowing the new magnetic properties is very important, both from theoretical point of view and their numerous practical applications in nanotechnology (nanotechnics and, recently, in nanomedicine), which should be considered. In this chapter we shall present an overview on the following topics: saturation magnetization, magnetic anisotropy, and magnetic behavior of magnetic nanoparticles, in relation with their size and magnetic structure, single- or multi-domains. The magnetic properties of the nanoparticles are compared and discussed in relation to those of the corresponding bulk. The surface effects, in the case of surfacted nanoparticles and those embedded in different matrices, on magnetic properties are presented and discussed in the core–shell model (core of the nanoparticle, where the magnetic moments are aligned under the exchange interaction, and the shell, where the magnetic moments are in a disordered structure).

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References

  1. H. Kachkachi, J. Magn. Magn. Mater. 316, 248 (2007)

    Article  Google Scholar 

  2. T. Kim, M. Shima, J. Appl. Phys., 101, 09 M516 (2007)

    Google Scholar 

  3. R.H. Kodama, J. Magn. Magn. Mater. 200, 359 (1999)

    Article  Google Scholar 

  4. L. Zhang, G.C. Papaefthymiou, R.F. Ziolo, J.Y. Ying, Nano Struct Mater 9, 185 (1997)

    Article  Google Scholar 

  5. C. Caizer, M. Stefanescu, J. Phys. D Appl. Phys. 35, 3035 (2002)

    Article  Google Scholar 

  6. C. Caizer, Mater Sci. Eng. B 100, 63 (2003)

    Article  Google Scholar 

  7. A.E. Berkowitz, W.J. Schuele, P.J. Flanders, J. Appl. Phys. 39, 1261 (1968)

    Article  Google Scholar 

  8. J.M.D. Coey, Phys. Rev. Lett. 27, 1140 (1971)

    Article  Google Scholar 

  9. A.E. Berkowitz, J.A. Lahut, I.S. Iacobs, L.M. Levinson, D.W. Forester, Phys. Rev. Lett. 34, 594 (1975)

    Article  Google Scholar 

  10. A.E. Berkowitz, J.A. Lahut, C.E. VanBuren, IEEE Trans. Magn. MAG-16, 184 (1980)

    Article  Google Scholar 

  11. R.H. Kodama, A.E. Berkowitz, E.J. McNiff, S. Foner, Phys. Rev. Lett. 77, 394 (1996)

    Article  Google Scholar 

  12. C. Cannas, G. Concas, A. Musinu, G. Piccaluga, G. Spano, Z. Naturforsch 54 a, 513 (1999)

    Google Scholar 

  13. E. Tronc, A. Ezzir, R. Cherkaoui, C. Chanéac, M. Noguès, H. Kachkachi, D. Fiorani, A.M. Testa, J.M. Grenèche, J.P. Jolivet, J. Magn. Magn. Mater. 221, 63 (2000)

    Article  Google Scholar 

  14. A.H. Morrisch, K. Haneda, J. Appl. Phys. 52, 2496 (1981)

    Article  Google Scholar 

  15. D. Lin, A.C. Nunes, C.F. Majkrzak, A.E. Berkowitz, J. Magn. Magn. Mater. 145, 343 (1995)

    Article  Google Scholar 

  16. R.V. Upadhyay, D. Srinivas, R.V. Mehta, J. Magn. Magn. Mater. 214, 105 (2000)

    Article  Google Scholar 

  17. C. Cannas, D. Gatteschi, A. Musinu, G. Piccalunga, C. Sangregorio, J. Phys. Chem. B 102, 7721 (1998)

    Article  Google Scholar 

  18. C. Caizer, J. Magn. Magn. Mater. 320, 1056 (2008)

    Article  Google Scholar 

  19. I. Hrianca, C. Caizer, Z. Schlett, J. Appl. Phys. 92, 2125 (2002)

    Article  Google Scholar 

  20. C. Caizer, M. Popovici, C. Savii, Acta Mater. 51, 3607 (2003)

    Article  Google Scholar 

  21. A.E. Berkowitz, R.H. Kodama, S.A. Makhlouf, F.T. Parker, F.E. Spada, E.J. McNiff Jr., S. Foner, J. Magn. Magn. Mater. 196–197, 591 (1999)

    Article  Google Scholar 

  22. P. Mollard, P. Germi, A. Rousset, Physica B 86–88, 1393 (1977)

    Article  Google Scholar 

  23. B. Martinez, A. Roig, E. Molins, T. GonzĂ¡lez-Carreño, C.J. Serna, J. Appl. Phys. 83, 3256 (1998)

    Article  Google Scholar 

  24. Y.T. Jeon, J.Y. Moon, G.H. Lee, Int. J. Mod. Phys. B 20, 4390 (2006)

    Article  Google Scholar 

  25. A. Millan, A. Urtizberea, N.J.O. Silva, F. Palacio, V.S. Amaral, E. Snoeck, V. Serin, J. Magn. Magn. Mater. 312, L5 (2007)

    Article  Google Scholar 

  26. P. Guardia, B. Batlle-Brugal, A.G. Roca, O. Iglesias, M.P. Morales, C.J. Serna, A. Labarta, X. Batlle, J. Magn. Magn. Mater. 316, e756 (2007)

    Article  Google Scholar 

  27. Y. Ichiyanagi, T. Uehashi, S. Yamada, Y. Kanazawa, T. Yamada, J. Therm. Anal. Calorim. 81, 541 (2005)

    Article  Google Scholar 

  28. D.T.T. Nguyet, N.P. Duong, L.T. Hung, T.D. Hien, T. Satoh, J. Alloys Compd. 509, 6621 (2011)

    Article  Google Scholar 

  29. S. Arajs, L.C. Nanna, D.H. Rasmussen, R.L. Bush, J. Appl. Phys. 67, 4499 (1990)

    Article  Google Scholar 

  30. J.P. Chen, C.M. Sorensen, K.J. Klabunde, G.C. Hadjipanayis, E. Devlin, A. Kostikas, Phys. Rev. B 54, 9288 (1996)

    Article  Google Scholar 

  31. C. Rocchiccioli-Deltcheff, R. Franck, V. Cabuil and R. Massart, J. Chem. Res. (S) 5, 126 (1987)

    Google Scholar 

  32. R.E. Rosensweig, Ferrohydrodynamics (Cambridge University Press, Cambridge, 1985)

    Google Scholar 

  33. Yu.L. Raikher, M.I. Shliomis, Adv. Chem. Phys., 87, 8 (1994)

    Google Scholar 

  34. C. Caizer, J. Magn. Magn. Mater. 251, 304 (2002)

    Article  Google Scholar 

  35. C. Caizer, I. Hrianca, Ann. Phys. 12, 115 (2003)

    Article  Google Scholar 

  36. C. Caizer, I. Hrianca, Eur. Phys. J. B. 31, 391 (2003)

    Article  Google Scholar 

  37. H. Jacobsen, K. Lefmann, E. Brok, C. Frandsen, S. Mørup, J. Magn. Magn. Mater, 324, 3218 (2012)

    Google Scholar 

  38. C. VĂ¡zquez-VĂ¡zquez, M.A. LĂ³pez-Quintela, M.C. BujĂ¡n-NĂºÅˆez, J. Rivas, J. Nanopart. Res. 13, 1663 (2011)

    Article  Google Scholar 

  39. K. Mandal, S. Mitra, P.A. Kumar, Europhys. Lett. 75, 618 (2006)

    Article  Google Scholar 

  40. C. Caizer, Appl. Phys. A 80, 1745 (2005)

    Article  Google Scholar 

  41. S. Mørup, B.R. Hansen, Phys. Rev. B 72, 024418 (2005)

    Article  Google Scholar 

  42. M.D. Kuz’min, A.M. Tishin, Phys. Lett. A 341, 240 (2005)

    Article  Google Scholar 

  43. G.F. Goya, T.S. BerquĂ³, F.C. Fonseca, J. Appl. Phys. 94, 3520 (2003)

    Article  Google Scholar 

  44. J. Wang, W. Wu, F. Zhao, G. Zhao, Appl. Phys. Lett. 98, 083107 (2011)

    Article  Google Scholar 

  45. H.M. Lu, Z.H. Cao, C.L. Zhao, P.Y. Li, X.K. Meng, J. Appl. Phys. 103, 123526 (2008)

    Article  Google Scholar 

  46. W. Wu, X. Lin, H. Duan, J. Wang, Int. J. Mod. Phys. B 26, 1250073 (2012)

    Article  Google Scholar 

  47. Xe. He, H. Shi, Particuology, 10, 497 (2012)

    Google Scholar 

  48. H. Mayama, T. Naito, Physica E 41, 1878 (2009)

    Article  Google Scholar 

  49. N.S. Gajbhiye, G. Balaji, M. Ghafari, Phys. Status Solidi A 189, 357 (2002)

    Article  Google Scholar 

  50. M.E. Fisher, A.E. Ferdinand, Phys. Rev. Lett. 19, 169 (1967)

    Article  Google Scholar 

  51. F. Huang, G.J. Mankey, M.T. Kief, R.F. Willis, J. Appl. Phys. 73, 6760 (1993)

    Article  Google Scholar 

  52. K. Chen, A.M. Ferrenberg, D.P. Landau, Phys. Rev. B 48, 3249 (1993)

    Article  Google Scholar 

  53. J. Mazo-Zuluaga, J. Restrepo, J. Mejia-Lopez, J. Phys. Condens. Matter 20, 195213 (2008)

    Article  Google Scholar 

  54. F. Bloch, Z Phys 61, 206 (1930)

    Article  Google Scholar 

  55. A.H. Eschenfelder, in: Landolt-Börnstein, Magnetic properties I (Springer, Berlin, 1962)

    Google Scholar 

  56. A.T. Aldred, P.H. Frohle, Int. J. Magnet. 2, 195 (1972)

    Google Scholar 

  57. A.T. Aldred, Phys. Rev. B 11, 2597 (1975)

    Article  Google Scholar 

  58. J.F. Dillon, in Landolt-Börnstein, Magnetic properties I (Springer, Berlin, 1962)

    Google Scholar 

  59. P.V. Hendriksen, S. Linderoth, P.A. Lindgard, J. Magn. Magn. Mater. 104–107, 1577 (1992)

    Article  Google Scholar 

  60. S. Linderoth, L. Balcells, A. Labarta, J. Tejada, P.V. Hendriksen, S.A. Sethi, J. Magn. Magn. Mater. 124, 269 (1993)

    Article  Google Scholar 

  61. P.V. Hendriksen, S. Linderoth, P.A. Lindgard, Phys. Rev. B 48, 7259 (1993)

    Article  Google Scholar 

  62. C. Caizer, Habil. Thesis (2013)

    Google Scholar 

  63. C. Caizer, Solid State Commun. 124, 53 (2002)

    Article  Google Scholar 

  64. A.H. Eschenfelder, J. Appl. Phys. 29, 378 (1958)

    Article  Google Scholar 

  65. B. Berkovsky, V. Bashtovoy, Magnetic Fluids and Applications Handbook (Begell House, New York, 1996)

    Google Scholar 

  66. M. Xu, P.J. Ridler, J. Appl. Phys. 82, 326 (1997)

    Article  Google Scholar 

  67. Yu.I. Raikher, M.I. Shliomis, Adv. Chem. Phys., 87, 3 (1994)

    Google Scholar 

  68. R.V. Upadhyay, D. Srinivas, R.V. Mehta, J. Magn. Magn. Mater. 214, 105 (2000)

    Article  Google Scholar 

  69. M.D. Sastry, Y. Babu, P.S. Goyal, R.V. Mehta, R.V. Upadhyay, D. Srinivas, J. Magn. Magn. Mater. 149, 64 (1995)

    Article  Google Scholar 

  70. E. Tronc, A. Ezzir, R. Cherkaoui, C. Chanéac, M. Noguès, H. Kachkachi, D. Fiorani, A.M. Testa, J.M. Grenèche, J.P. Jolivet, J. Magn. Magn. Mater. 221, 63 (2000)

    Article  Google Scholar 

  71. C. Caizer, J. Phys. Condens. Matter 15, 765 (2003)

    Article  Google Scholar 

  72. K. Honda, S. Kaya, Sci. Rep. Tohoku Univ. 15, 721 (1926)

    Google Scholar 

  73. S. Kaya, Sci. Rep. Tohoku Univ. 17, 639 (1928)

    Google Scholar 

  74. S. Kaya, Sci. Rep. Tohoku Univ. 17, 1157 (1928)

    Google Scholar 

  75. E. Kneller, Ferromagnetismus (Springer, Berlin, 1962)

    Book  Google Scholar 

  76. H.C. Akulov, Zs. Phys. 52, 389 (1928)

    Article  Google Scholar 

  77. G. Aubert, J. Appl. Phys. 39, 504 (1968)

    Article  Google Scholar 

  78. W.J. Carr, Handbook of Phys., XVIII, 274 (1960)

    Google Scholar 

  79. C. Kittel, J.H. van Vleck, Phys. Rev. 118, 1231 (1960)

    Article  Google Scholar 

  80. L. Neel, Compt. Rend. 237, 1613 (1953)

    Google Scholar 

  81. L. Neel, J. Phys. Radium 15, 225 (1954)

    Article  Google Scholar 

  82. F. Bødker, S. Mørup, S. Linderoth, Phys. Rev. Lett. 72, 282 (1994)

    Article  Google Scholar 

  83. C. Papusoi, J. Magn. Magn. Mater. 195, 708 (1999)

    Article  Google Scholar 

  84. C. Caizer, Magnetic Nanofluids (in Romanian) (Eurobit Publishing House, Timisoara, 2004)

    Google Scholar 

  85. F. Gazeau, J.C. Bacri, F. Gendron, R. Perzynski, L. Raikher Yu, V.I. Stepanov, E. Dubois, J. Magn. Magn. Mater. 186, 175 (1998)

    Article  Google Scholar 

  86. A. van Broese Groenou, J.A. Schulkes, D.A. Annis, J. Appl. Phys 38, 1133 (1967)

    Article  Google Scholar 

  87. J.K. Vassiliou, V. Mehrotra, M.W. Russell, E.P. Giannelis, J. Appl. Phys. 73, 5109 (1993)

    Article  Google Scholar 

  88. J.M.D. Coey, D. Khalafalla, Phys. Status Solidi A 11, 229 (1972)

    Article  Google Scholar 

  89. A.H. Morrish, E.P. Valstyn, J. Phys. Soc. Jpn. 17, 392 (1962)

    Google Scholar 

  90. S. Mørup, J. Magn. Magn. Mater. 37, 39 (1983)

    Article  Google Scholar 

  91. V. Skumryev, S. Stoyanov, Y. Zhang, G. Hadjipanayis, D. Givord, J. Nogués, Nature 423, 850 (2003)

    Article  Google Scholar 

  92. R.H. Kodama, A.E. Berkowitz, Phys. Rev. B 50, 0321 (1999)

    Google Scholar 

  93. H. Kachkachi, M. Dimian, Phys. Rev. B 66, 174419 (2002)

    Article  Google Scholar 

  94. H. Kachkachi, E. Bonet, Phys. Rev. B 73, 224402 (2006)

    Article  Google Scholar 

  95. M. Jamet, W. Wernsdorfer, C. Thirion, V. Dupuis, P. MĂ©linon, A. PĂ©rez, D. Mailly, Phys. Rev. B 69, 024401 (2004)

    Article  Google Scholar 

  96. E. De Biasi, R.D. Zysler, C.A. Ramos, H. Romero, D. Fiorani, Phys. Rev. B 71, 104408 (2005)

    Article  Google Scholar 

  97. J. Mazo-Zuluaga, J. Restrepo, J. MejĂ­a-LĂ³pez, J. Appl. Phys. 103, 113906 (2008)

    Article  Google Scholar 

  98. A. Hubert, R. Schäfer, Magnetic Domains (Springer, Berlin, 1998)

    Google Scholar 

  99. E. Becker, H. Polley, Ann. Phys. 37, 534 (1940)

    Article  Google Scholar 

  100. R. Grossinger, Phys. Status Solidi A 66, 665 (1981)

    Article  Google Scholar 

  101. C. Caizer, V. Tura, J. Magn. Magn. Mater. 301, 513 (2006)

    Article  Google Scholar 

  102. H. Kojima, in Ferromagnetic Materials ed. by E.P. Wohlfarth (North-Holland, Amsterdam, 1982)

    Google Scholar 

  103. C. Kittel, Phys. Rev. 70, 965 (1946)

    Article  Google Scholar 

  104. L. Neel, Compt. Rend. Acad. Sci. Paris, 224, 1488 and 1550 (1947)

    Google Scholar 

  105. C. Kittel, Rev. Mod. Phys. 21, 541 (1949)

    Article  Google Scholar 

  106. C. Caizer, M. Stefanescu, Physica B 327, 129 (2003)

    Article  Google Scholar 

  107. L. Landau, E. Lifshitz, Phys. Z. S. 8, 153 (1935)

    Google Scholar 

  108. E.C. Stoner, E.P. Wohlfarth, Philos. Trans. R. Soc. Lond. A, 240, 599 (1948)

    Google Scholar 

  109. J.C. Slonkzewski, Research Memo., IBM Research Center, N.Y. (1956, unpublished)

    Google Scholar 

  110. D.O. Smith, J. Appl. Phys. 29, 264 (1958)

    Article  Google Scholar 

  111. W. Wernsdorfer, C. Thirion, N. Demoncy, H. Pascard, D. Mailly, J. Magn. Magn. Mater. 242–245, 132 (2002)

    Article  Google Scholar 

  112. A. Stancu, L. Spinu, IEEE Trans. Magn. 34, 3867 (1998)

    Article  Google Scholar 

  113. A. Stancu, I. Chiorescu, IEEE Trans. Magn. 33, 2573 (1997)

    Article  Google Scholar 

  114. B.D. Cullity, Introduction to Magnetic Materials (Addison-Wesley, Reading, 1972)

    Google Scholar 

  115. W. Wernsdorfer et al., Phys. Rev. Lett. 79, 4014 (1997)

    Article  Google Scholar 

  116. E.M. Chudnovsky, L. Gunther, Phys. Rev. Lett. 60, 661 (1988)

    Article  Google Scholar 

  117. E.M. Chudnovsky, J. Tejada, Macroscopic Quantum Tunneling of the Magnetic Moment (Cambridge University Press, Cambridge, 1998)

    Book  Google Scholar 

  118. L. Neel, C. R. Acad. Sci. Paris, 224, 1488 and 1550 (1947)

    Google Scholar 

  119. C.P. Bean, J. Appl. Phys. 26, 1381 (1955)

    Article  Google Scholar 

  120. R.B. Campbell, J. Appl. Phys. 28, 381 (1957)

    Article  Google Scholar 

  121. B. Barbara, Magnetization Reversal of Nano-particles (Springer, Berlin-Heidelberg, 2001) (in: E. Beaurepaire, F. Scheurer, G. Krill and J.P. Kappler (Eds.): LNP 565, 157 (2001))

    Google Scholar 

  122. L. NĂ©el, Ann. Geophys. 5, 99 (1949)

    Google Scholar 

  123. L. NĂ©el, Adv. Phys. 4, 191 (1955)

    Article  Google Scholar 

  124. W.F. Brown, J. Appl. Phys. 30, 130S (1959)

    Article  Google Scholar 

  125. A. Aharoni, Phys. Rev. A 135, 447 (1964)

    Article  Google Scholar 

  126. C.H. Back, D. Weller, J. Heidmann, D. Mauri, D. Guarisco, E.L. Garwin, H.C. Siegmann, Phys. Rev. Lett. 81, 3251 (1998)

    Article  Google Scholar 

  127. J.L. Dormann, F. D’Orazio, F. Lucari, E. Tronc, P. Prené, J.P. Jolivet, D. Fiorani, R. Cherkaoui, M. Nogués, Phys. Rev. B 53, 14291 (1996)

    Article  Google Scholar 

  128. J.L. Dormann, L. Spinu, E. Tronc, J.P. Jolivet, F. Lucari, F. D’Orazio, D. Fiorani, J. Magn. Magn. Mater. 183, L255 (1998)

    Article  Google Scholar 

  129. C.P. Bean, L.D. Livingston, J. Appl. Phys. 30, 120S (1959)

    Article  Google Scholar 

  130. C. Caizer, J. Phys. Condens. Matter 17, 2019 (2005)

    Article  Google Scholar 

  131. C.L. Dennis, R.P. Borges, L.D. Buda, U. Ebels, J.F. Gregg, M. Hehn, E. Jouguelet, K. Qunadjela, I. Petej, I.L. Prejbeanu, M.J. Thornton, J. Phys. Condens. Matter 14, R1175 (2002)

    Article  Google Scholar 

  132. F. Kneller, F.E. Luborsky, J. Appl. Phys. 34, 656 (1963)

    Article  Google Scholar 

  133. H. Pleifer, Phys. Status Solidi A 118, 295 (1990)

    Article  Google Scholar 

  134. G.I. Frolov, O.I. Bachina, M.M. Zav’yalova, S.I. Ravochkin, Tech. Phys. 53, 1059 (2008)

    Article  Google Scholar 

  135. F.C. Fonseca, G.F. Goya, R.F. Jardim, R. Muccillo, N.L.V. Carreño, E. Longo, E.R. Leite, Phys. Rev. B 66, 104406 (2002)

    Article  Google Scholar 

  136. J.M. Vargas, W.C. Nunes, L.M. Socolovsky, M. Knobel, D. Zanchet, Phys. Rev. B 72, 184428 (2005)

    Article  Google Scholar 

  137. S.V. Vonsovskii, Magnetism (Wiley, New York, 1974)

    Google Scholar 

  138. P. Langevin, Ann. Chem. Phys. 5, 70 (1905)

    Google Scholar 

  139. I.S. Jacobs, C.P. Bean, in: Magnetism III, ed by G.T. Rado, H. Suhl (Academic Press, New York, 1963)

    Google Scholar 

  140. K. O’Grady, A. Bradbury, J. Magn. Magn. Mater. 39, 91 (1994)

    Article  Google Scholar 

  141. I.I. Yaacob, A.C. Nunes, A. Bose, J. Colloid Interface Sci. 171, 73 (1995)

    Article  Google Scholar 

  142. N. Moumen, M.P. Pileni, Chem. Mater. 8, 11128 (1996)

    Article  Google Scholar 

  143. J.C. Bacri, R. Perzinski, D. Salin, V. Cabuil, R. Massart, J. Magn. Magn. Mater. 62, 36 (1986)

    Article  Google Scholar 

  144. R.W. Chantrell, J. Popplewel, S.W. Charles, IEEE Trans. Magn. MAG-14, 975 (1978)

    Article  Google Scholar 

  145. M. Stefanescu, C. Caizer, M. Stoia, O. Stefanescu, Acta Mater. 54, 1249 (2006)

    Article  Google Scholar 

  146. A.F. Pshenichnikov, W.V. Mekhonoshin, A.V. Lebedev, J. Magn. Magn. Mater. 161, 94 (1996)

    Article  Google Scholar 

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Caizer, C. (2016). Nanoparticle Size Effect on Some Magnetic Properties. In: Aliofkhazraei, M. (eds) Handbook of Nanoparticles. Springer, Cham. https://doi.org/10.1007/978-3-319-15338-4_24

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