Abstract
Thermal analysis and calorimetry offer versatile possibilities to study different physical and chemical changes in materials. Calorimetry gives accurate and valuable information on phase transitions of nanostructured materials and is therefore very useful in studies of mesoporous materials. The use of calorimetry in porous silicon research focusing on drug delivery applications and pore morphology determination is reviewed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Baird JA, Taylor LS (2012) Evaluation of amorphous solid dispersion properties using thermal analysis techniques. Adv Drug Deliv Rev 64(5):396–421. doi:10.1016/j.addr.2011.07.009
Becker CR, Currano LJ, Churaman WA, Stoldt CR (2010) Thermal analysis of the exothermic reaction between galvanic porous silicon and sodium perchlorate. ACS Appl Mater Interfaces 2(11):2998–3003. doi:10.1021/am100975u
Budaguan BG, Aivazov AA, Sazonov AY (1996) Calorimetric investigation of structural processes in porous silicon. J Non-Cryst Solids 204(2):169–171. doi:10.1016/s0022-3093(96)00403-6
Canham LT, Groszek AJ (1992) Characterization of microporous Si by flow calorimetry – comparison with a hydrophobic SiO2 molecular sieve. J Appl Phys 72(4):1558–1565
Faivre C, Bellet D, Dolino G (1999a) Phase transitions of fluids confined in porous silicon: a differential calorimetry investigation. Eur Phys J B 7(1):19–36. doi:10.1007/s100510050586
Faivre C, Bellet D, Dolino G (1999b) Phase transitions of fluids confined in porous silicon: a differential calorimetry investigation. Eur Phys J B Condens Matter Phys 7(1):19–36
Garbett NC, Chaires JB (2012) Thermodynamic studies for drug design and screening. Expert Opin Drug Discov 7(4):299–314. doi:10.1517/17460441.2012.666235
Hemminger W, Sarge SM (1998) Chapter 1 Definitions, nomenclature, terms and literature. In: Michael EB (ed) Handbook of thermal analysis and calorimetry, vol 1. Elsevier Science B.V., Burlington, pp 1–73
Landry MR (2005) Thermoporometry by differential scanning calorimetry: experimental considerations and applications. Thermochim Acta 433(1–2):27–50. doi:10.1016/j.tca.2005.02.015
Lehto VP, Vaha-Heikkila K, Paski J, Salonen J (2005) Use of thermoanalytical methods in quantification of drug load in mesoporous silicon microparticles. J Therm Anal Calorim 80(2):393–397
Plummer A, Cao H, Dawson R, Lowe R, Shapter J, Voelcker NH (2008) The influence of pore size and oxidising agent on the energetic properties of porous silicon. In: Voelcker NH, Thissen HW (eds) Smart materials V. Proceedings of SPIE. Spie-international society for optical engineeringBellingham, vol 7267. 72670 p, doi: 10.1117/12.810453
Riikonen J, Makila E, Salonen J, Lehto VP (2009) Determination of the physical state of drug molecules in mesoporous silicon with different surface chemistries. Langmuir 25(11):6137–6142. doi:10.1021/la804055s
Riikonen J, Salomaki M, van Wonderen J, Kemell M, Xu W, Korhonen O, Ritala M, MacMillan F, Salonen J, Lehto VP (2012) Surface chemistry, reactivity, and pore structure of porous silicon oxidized by various methods. Langmuir 28(28):10573–10583. doi:10.1021/la301642w
Salonen J, Lehto VP, Laine E (1997a) The room temperature oxidation of porous silicon. Appl Surf Sci 120(3–4):191–198
Salonen J, Lehto VP, Laine E (1997b) Thermal oxidation of free-standing porous silicon films. Appl Phys Lett 70(5):637–639
Salonen J, Lehto VP, Bjorkqvist M, Laine E (1999a) A role of illumination during etching to porous silicon oxidation. Appl Phys Lett 75(6):826–828
Salonen J, Lehto VP, Laine E (1999b) Photo-oxidation studies of porous silicon using a microcalorimetric method. J Appl Phys 86(10):5888–5893
Salonen J, Lehto V, Bjorkqvist M, Laine E, Niinisto L (2001) Chemical stability of thermally-carbonized porous silicon. Mat Res Soc Symp Proc F14.19. 638:11–16
Salonen J, Laine E, Niinisto L (2002) Thermal carbonization of porous silicon surface by acetylene. J Appl Phys 91(1):456–461
Salonen J, Laine E, Niinisto L (2003) Thermal analysis of hydrosilylation of 1-dodecene on porous silicon surface. Phys Status Solidi A 197(1):246–250
Salonen J, Laitinen L, Kaukonen AM, Tuura J, Bjorkqvist M, Heikkila T, Vaha-Heikkila K, Hirvonen J, Lehto VP (2005a) Mesoporous silicon microparticles for oral drug delivery: loading and release of five model drugs. J Control Release 108(2–3):362–374
Salonen J, Paski J, Vaha-Heikkila K, Heikkila T, Bjorkqvist M, Lehto VP (2005b) Determination of drug load in porous silicon microparticles by calorimetry. Phys Status Solidi A-Appl Mater Sci 202(8):1629–1633
Salonen J, Kaukonen AM, Hirvonen J, Lehto VP (2008) Mesoporous silicon in drug delivery applications. J Pharm Sci 97(2):632–653
Wang F, Hui H, Barnes TJ, Barnett C, Prestidge CA (2010) Oxidized mesoporous silicon microparticles for improved oral delivery of poorly soluble drugs. Mol Pharm 7(1):227–236. doi:10.1021/mp900221e
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer International Publishing Switzerland
About this entry
Cite this entry
Salonen, J. (2014). Characterization of Porous Silicon by Calorimetry. In: Canham, L. (eds) Handbook of Porous Silicon. Springer, Cham. https://doi.org/10.1007/978-3-319-05744-6_45
Download citation
DOI: https://doi.org/10.1007/978-3-319-05744-6_45
Received:
Accepted:
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-05743-9
Online ISBN: 978-3-319-05744-6
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics