Glossary
- Biofuel:
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Combustible fuel derived from biomass.
- Biomass:
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Nonfossil organic matter.
- Biorefinery:
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A collection of processes for the production of fuels and chemical products from biological sources.
- Deep eutectic solvent:
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A liquid composed by mixing a salt with a strong hydrogen bond donor molecule.
- Ionic liquid:
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A liquid composed of solely of ions when pure.
- Lignocellulose:
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A biological matrix consisting of the polymers cellulose, hemicellulose, and lignin.
- Platform chemical:
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A chemical that can be used as a precursor to many others as the basis of a chemicals industry.
- Pretreatment:
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The initial step in the deconstruction of lignocellulose biomass.
Definition of the Subject
A biorefinery is a refinery that produces chemicals, fuels, and materials to meet human needs for transportation, technology, etc., that uses renewable feedstocks such as lignocellulosic biomass to produce chemical compounds. It is thought to be an alternative to existing refineries based on fossil resources...
References
Mikkola J, Sklavounos E, King AWT, Virtanen P (2015) Chemistry. The biorefinery and green chemistry. The Royal Society of Chemistry, Cambridge, pp 1–37
Future OC (1987) Our common future, Chapter 2: Towards sustainable development. http://www.un-documents.net/ocf-02.htm
McKendry P (2002) Energy production from biomass (part 2): conversion technologies. Bioresour Technol 83:47–54
Dutta T, Shi J, Sun J, Zhang XIN, Cheng G, Simmons BA, Singh S (2015) Ionic liquid pretreatment of lignocellulosic biomass for biofuels and chemicals. Ionic liquids in the biorefinery concept, Royal Society of Chemistry, Cambridge, pp 65–94. https://doi.org/10.1039/9781849739764-00065
van Eijck J, Batidzirai B, Faaij A (2014) Current and future economic performance of first and second generation biofuels in developing countries. Appl Energy 135:115–141
Himmel ME, Ding SY, Johnson DK, Adney WS, Nimlos MR, Brady JW, Foust TD (2007) Biomass recalcitrance: engineering plants and enzymes for biofuels production. Science (80-.) 315:804–807
Li C, Knierim B, Manisseri C, Arora R, Scheller HV, Auer M, Vogel KP, Simmons BA, Singh S (2010) Comparison of dilute acid and ionic liquid pretreatment of switchgrass: biomass recalcitrance, delignification and enzymatic saccharification. Bioresour Technol 101:4900–4906
Cheng H, Wang L (2013) Lignocelluloses feedstock biorefinery as petrorefinery substitutes. In: Biomass now – sustainable growth and use. Intech Open, London, pp 347–388
De Jong E, Jungmeier G (2015) Biorefinery concepts in comparison to petrochemical refineries. Industrial biorefineries and white biotechnology, Elsevier
Jungmeier G (Joanneum RF mbH), van Ree R, van Zeeland AUF and BR (2014) IEA Bioenergy Task 42 Biorefining: definition biorefining & classification biorefining
Kumar P, Barrett DM, Barrett DM, Delwiche MJ, Delwiche MJ, Stroeve P, Stroeve P (2009) Methods for pretreatment of lignocellulosic biomass for efficient hydrolysis and biofuel production. Ind Eng Chem Anal Ed 48:3713–3729
Danner H, Braun R (1999) Biotechnology for the production of commodity chemicals from biomass. Chem Soc Rev 28:395–405
Wu L, Moteki T, Gokhale AA, Flaherty DW, Toste FD (2016) Production of fuels and chemicals from biomass: condensation reactions and beyond. Chem 1:32–58
Ragauskas AJ, Beckham GT, Biddy MJ, Chandra R, Chen F, Davis MF, Davison BH, Dixon RA, Gilna P, Keller M, Langan P, Naskar AK, Saddler JN, Tschaplinski TJ, Tuskan GA, Wyman CE (2014) Lignin valorization: improving lignin processing in the biorefinery. Science (80-) 344:709
Winkler R (2005) Valuation of ecosystem goods and services Part 1: an integrated dynamic approach. Synthesis (Stuttg) 59:82–93
Biermann CJ (1996) Handbook of pulping and papermaking. Academic, San Diego
Pimentel D, Patzek T (2005) Ethanol production using corn, switchgrass, and ưood; Biodiesel production using soybean and sunflower. Nat Resour Res 14:65–76
Axelsson L, Franzén M, Ostwald M, Berndes G, Lakshmi G, Ravindranath NH (2012) Perspective: Jatropha cultivation in southern India: assessing farmers’ experiences. Biofuels Bioprod Biorefin 6:246–256
Bridgwater AV, Toft AJ, Brammer JG (2002) A techno-economic comparison of power production by biomass fast pyrolysis with gasification and combustion. Renew Sustain Energy Rev 6:181–248
Prado R, Weber CC (2016) Applications of ionic liquids. In: Application, purification, and recovery of ionic liquids. Elsevier, pp 1–58
Welton T (1999) Room-temperature ionic liquids. Solvents for synthesis and catalysis. Chem Rev 99:2071–2084
Wasserscheid P, Welton T (2006) Ionic liquids in synthesis. Wiley-VCH, Weinheim
Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry. Chem Soc Rev 37:123–150
Stark A (2011) Ionic liquids in the biorefinery: a critical assessment of their potential. Energy Environ Sci 4:19–32
Brandt A, Gräsvik J, Hallett JP, Welton T (2013) Deconstruction of lignocellulosic biomass with ionic liquids. Green Chem 15:550–583
Xia S, Baker G, Li H, Ravula S, Zhao H (2014) Aqueous ionic liquids and deep eutectic solvents for cellulosic biomass pretreatment and saccharification. RSC Adv 4:10586–10596
Fink H-P, Weigel P, Purz H, Ganster J (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26:1473–1524
Zhang Y-HP, Cui J, Lynd LR, Kuang LR (2006) A transition from cellulose swelling to cellulose dissolution by o -phosphoric acid: evidence from enzymatic hydrolysis and supramolecular structure. Biomacromolecules 7:644–648
Graenacher C (1934) Cellulose solution. US Patent 4,446,331, pp 1–4
Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellose with ionic liquids. J Am Chem Soc 124:4974–4975
Zhang H, Wu J, Zhang J, He J (2005) 1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: a new and powerful nonderivatizing solvent for cellulose. Macromolecules 38:8272–8277
Gupta KM, Jiang J (2015) Cellulose dissolution and regeneration in ionic liquids: a computational perspective. Chem Eng Sci 121:180–189
Cao Y, Zhang R, Cheng T, Guo J, Xian M, Liu H (2017) Imidazolium-based ionic liquids for cellulose pretreatment: recent progresses and future perspectives. Appl Microbiol Biotechnol 101:521–532
Xu A, Wang J, Wang H (2010) Effects of anionic structure and lithium salts addition on the dissolution of cellulose in 1-butyl-3-methylimidazolium-based ionic liquid solvent systems. Green Chem 12:268–275
Lu B, Xu A, Wang J (2014) Cation does matter: how cationic structure affects the dissolution of cellulose in ionic liquids. Green Chem 16:1326–1335
Liu Y-R, Thomsen K, Nie Y, Zhang S-J, Meyer AS (2016) Predictive screening of ionic liquids for dissolving cellulose and experimental verification. Green Chem 18:6246–6254
Zhao Y, Liu X, Wang J, Zhang S (2012) Effects of cationic structure on cellulose dissolution in ionic liquids: a molecular dynamics study. ChemPhysChem 13:3126–3133
Liu D, Xia K, Cai W, Yang R, Wang L, Wang B (2012) Investigations about dissolution of cellulose in the 1-allyl-3-alkylimidazolium chloride ionic liquids. Carbohydr Polym 87:1058–1064
Payal RS, Balasubramanian S (2014) Dissolution of cellulose in ionic liquids: an ab initio molecular dynamics simulation study. Phys Chem Chem Phys 16:17458
Payal RS, Bejagam KK, Mondal A, Balasubramanian S (2015) Dissolution of cellulose in room temperature ionic liquids: anion dependence. J Phys Chem B 119:1654–1659
Gericke M, Liebert T, El SOA, Heinze T (2011) Tailored media for homogeneous cellulose chemistry: ionic liquid/co-solvent mixtures. Macromol Mater Eng 296:483–493
Gericke M, Liebert T, Heinze T (2009) Interaction of ionic liquids with polysaccharides, 8 – synthesis of cellulose sulfates suitable for polyelectrolyte complex formation. Macromol Biosci 9:343–353
Xu A, Zhang Y, Zhao Y, Wang J (2013) Cellulose dissolution at ambient temperature: role of preferential solvation of cations of ionic liquids by a cosolvent. Carbohydr Polym 92:540–544
Zhao Y, Liu X, Wang J, Zhang S (2013) Insight into the cosolvent effect of cellulose dissolution in imidazolium-based ionic liquid systems. J Phys Chem B 117:9042–9049
Andanson J-M, Bordes E, Devémy J, Leroux F, Pádua AAH, Gomes MFC (2014) Understanding the role of co-solvents in the dissolution of cellulose in ionic liquids. Green Chem 16:2528
Huo F, Liu Z, Wang W (2013) Cosolvent or antisolvent? A molecular view of the interface between ionic liquids and cellulose upon addition of another molecular solvent. J Phys Chem B 117:11780–11792
Zhu S, Wu Y, Chen Q, Yu Z, Wang C, Jin S, Ding Y, Wu G (2006) Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem 8:325
Pinkert A, Marsh KN, Pang S, Staiger MP (2009) Ionic liquids and their interaction with cellulose. Chem Rev 109:6712–6728
Lindman B, Karlström G, Stigsson L (2010) On the mechanism of dissolution of cellulose. J Mol Liq 156:76–81
Wang H, Gurau G, Rogers RD (2012) Ionic liquid processing of cellulose. Chem Soc Rev 41:1519
Yuan X, Cheng G (2015) From cellulose fibrils to single chains: understanding cellulose dissolution in ionic liquids. Phys Chem Chem Phys 17:31592–31607
Remsing RC, Swatloski RP, Rogers RD, Moyna G (2006) Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems. Chem Commun 12:1271
Liu H, Sale KL, Holmes BM, Simmons BA, Singh S (2010) Understanding the interactions of cellulose with ionic liquids: a molecular dynamics study. J Phys Chem B 114:4293–4301
Zhang J, Zhang H, Wu J, Zhang J, He J, Xiang J (2010) NMR spectroscopic studies of cellobiose solvation in EmimAc aimed to understand the dissolution mechanism of cellulose in ionic liquids. Phys Chem Chem Phys 12:1941–1947
Feng L, Chen Z (2008) Research progress on dissolution and functional modification of cellulose in ionic liquids. J Mol Liq 142:1–5
Rabideau BD, Agarwal A, Ismail AE (2013) Observed mechanism for the breakup of small bundles of cellulose Iα and Iβ in ionic liquids from molecular dynamics simulations. J Phys Chem B 117:3469–3479
Mazza M, Catana DA, Vaca-Garcia C, Cecutti C (2009) Influence of water on the dissolution of cellulose in selected ionic liquids. Cellulose 16:207–215
Fort DA, Remsing RC, Swatloski RP, Moyna P, Moyna G, Rogers RD (2007) Can ionic liquids dissolve wood? Processing and analysis of lignocellulosic materials with 1-n-butyl-3-methylimidazolium chloride. Green Chem 9:63–69
Kilpeläinen I, Xie H, King A, Granstrom M, Heikkinen S, Argyropoulos DS (2007) Dissolution of wood in ionic liquids. J Agric Food Chem 55:9142–9148
Rosatella AA, Afonso CAM (2015) Chapter 2. The dissolution of biomass in ionic liquids towards pre-treatment approach. The Royal Society of Chemistry, Cambridge, pp 38–64
Sun N, Rahman M, Qin Y, Maxim ML, Rodríguez H, Rogers RD (2009) Complete dissolution and partial delignification of wood in the ionic liquid 1-ethyl-3-methylimidazolium acetate. Green Chem 11:646
Zhang J, Wang Y, Zhang L, Zhang R, Liu G, Cheng G (2014) Understanding changes in cellulose crystalline structure of lignocellulosic biomass during ionic liquid pretreatment by XRD. Bioresour Technol 151:402–405
Cheng G, Varanasi P, Arora R, Stavila V, Simmons BA, Kent MS, Singh S (2012) Impact of ionic liquid pretreatment conditions on cellulose crystalline structure using 1-ethyl-3-methylimidazolium acetate. J Phys Chem B 116:10049–10054
Cheng G, Varanasi P, Li C, Liu H, Melnichenko YB, Simmons BA, Kent MS, Singh S (2011) Transition of cellulose crystalline structure and surface morphology of biomass as a function of ionic liquid pretreatment and its relation to enzymatic hydrolysis. Biomacromolecules 12:933–941
Trinh LTP, Lee YJ, Lee J-W, Lee H-J (2015) Characterization of ionic liquid pretreatment and the bioconversion of pretreated mixed softwood biomass. Biomass Bioenergy 81:1–8
Singh S, Simmons BA, Vogel KP (2009) Visualization of biomass solubilization and cellulose regeneration during ionic liquid pretreatment of switchgrass. Biotechnol Bioeng 104:68–75
Doherty TV, Mora-Pale M, Foley SE, Linhardt RJ, Dordick JS (2010) Ionic liquid solvent properties as predictors of lignocellulose pretreatment efficacy. Green Chem 12:1967
da Costa Lopes AM, João KG, Morais ARC, Bogel-Łukasik E, Bogel-Łukasik R (2013) Ionic liquids as a tool for lignocellulosic biomass fractionation. Sustain Chem Process 1:3
Zavrel M, Bross D, Funke M, Büchs J, Spiess AC (2009) High-throughput screening for ionic liquids dissolving (ligno-)cellulose. Bioresour Technol 100:2580–2587
Weerachanchai P, Kwak SK, Lee J-M (2014) Effects of solubility properties of solvents and biomass on biomass pretreatment. Bioresour Technol 170:160–166
Muhammad N, Man Z, Bustam Khalil MA (2012) Ionic liquid – a future solvent for the enhanced uses of wood biomass. Eur J Wood Wood Prod 70:125–133
Domínguez de María P (2014) Recent trends in (ligno)cellulose dissolution using neoteric solvents: switchable, distillable and bio-based ionic liquids. J Chem Technol Biotechnol 89:11–18
Miyafuji H (2015) Application of ionic liquids for effective use of woody biomass. J Wood Sci 61:343–350
Hart WES, Harper JB, Aldous L (2015) The effect of changing the components of an ionic liquid upon the solubility of lignin. Green Chem 17:214–218
Wang Y, Wei L, Li K, Ma Y, Ma N, Ding S, Wang L, Zhao D, Yan B, Wan W, Zhang Q, Wang X, Wang J, Li H (2014) Lignin dissolution in dialkylimidazolium-based ionic liquid–water mixtures. Bioresour Technol 170:499–505
Akiba T, Tsurumaki A, Ohno H (2017) Induction of lignin solubility for a series of polar ionic liquids by the addition of a small amount of water. Green Chem 19:2260–2265
Mäki-Arvela P, Anugwom I, Virtanen P, Sjöholm R, Mikkola JP (2010) Dissolution of lignocellulosic materials and its constituents using ionic liquids – a review. Ind Crop Prod 32:175–201
Hossain MM, Aldous L (2012) Ionic liquids for lignin processing: dissolution, isolation, and conversion. Aust J Chem 65:1465
Mai NL, Ha SH, Koo Y-M (2014) Efficient pretreatment of lignocellulose in ionic liquids/co-solvent for enzymatic hydrolysis enhancement into fermentable sugars. Process Biochem 49:1144–1151
Lynam JG, Coronella CJ (2014) Glycerol as an ionic liquid co-solvent for pretreatment of rice hulls to enhance glucose and xylose yield. Bioresour Technol 166:471–478
Shi J, Balamurugan K, Parthasarathi R, Sathitsuksanoh N, Zhang S, Stavila V, Subramanian V, Simmons B, Singh S (2014) Understanding the role of water during ionic liquid pretreatment of lignocellulose: co-solvent or anti-solvent? Green Chem 16:3830–3840
Upfal J, MacFarlane DR, Forsyth SA (2005) Solvents for use in the treatment of lignin-containing materials. patent number EP1654415A1, pp 1–40
Varanasi S, Schall CA, Dadi AP, Anderson J, Rao K, Kumar G, Paripati P (2011) Biomass Pretreatment, US Patent 8,030,030 B2
George A, Brandt A, Tran K, Zahari SMSNS, Klein-Marcuschamer D, Sun N, Sathitsuksanoh N, Shi J, Stavila V, Parthasarathi R, Singh S, Holmes BM, Welton T, Simmons BA, Hallett JP (2015) Design of low-cost ionic liquids for lignocellulosic biomass pretreatment. Green Chem 17:1728–1734. https://doi.org/10.1039/C4GC01208A
Konda N, Shi J, Singh S, Blanch HW, Simmons BA, Klein-Marcuschamer D (2014) Understanding cost drivers and economic potential of two variants of ionic liquid pretreatment for cellulosic biofuel production. Biotechnol Biofuels 7:86
Lee SH, Doherty TV, Linhardt RJ, Dordick JS (2009) Ionic liquid-mediated selective extraction of lignin from wood leading to enhanced enzymatic cellulose hydrolysis. Biotechnol Bioeng 102:1368–1376
Tan SSY, MacFarlane DR, Upfal J, Edye LA, Doherty WOS, Patti AF, Pringle JM, Scott JL (2009) Extraction of lignin from lignocellulose at atmospheric pressure using alkylbenzenesulfonate ionic liquid. Green Chem 11:339. https://doi.org/10.1039/b815310h
Arora R, Manisseri C, Li C, Ong MD, Scheller HV, Vogel K, Simmons BA, Singh S (2010) Monitoring and analyzing process streams towards understanding ionic liquid pretreatment of switchgrass (Panicum virgatum L.). BioEnergy Res 3:134–145. https://doi.org/10.1007/s12155-010-9087-1
Ab Rani MA, Brant A, Crowhurst L, Dolan A, Lui M, Hassan NH, Hallett JP, Hunt PA, Niedermeyer H, Perez-Arlandis JM, Schrems M, Welton T, Wilding R (2011) Understanding the polarity of ionic liquids. Phys Chem Chem Phys 13:16831. https://doi.org/10.1039/c1cp21262a
van Osch DJGP, Kollau LJBM, van den Bruinhorst A, Asikainen S, Rocha MAA, Kroon MC (2017) Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation. Phys Chem Chem Phys 19:2636–2665
Achinivu EC, Howard RM, Li G, Gracz H, Henderson WA (2014) Lignin extraction from biomass with protic ionic liquids. Green Chem 16:1114–1119
Brandt A, Ray MJ, To TQ, Leak DJ, Murphy RJ, Welton T (2011) Ionic liquid pretreatment of lignocellulosic biomass with ionic liquid-water mixtures. Green Chem 13:2489–2499
Verdía P, Brandt A, Hallett JP, Ray MJ, Welton T (2014) Fractionation of lignocellulosic biomass with the ionic liquid 1-butylimidazolium hydrogen sulfate. Green Chem 16:1617
Weigand L, Mostame S, Brandt-Talbot A, Welton T, Hallett JP (2017) Effect of pretreatment severity on the cellulose and lignin isolated from Salix using ionoSolv pretreatment. Faraday Discuss 0:1–19
Brandt-Talbot A, Gschwend FJV, Fennell PS, Lammens TM, Tan B, Weale J, Hallett JP (2017) An economically viable ionic liquid for the fractionation of lignocellulosic biomass. Green Chem 19:3078–3102
Chen L, Sharifzadeh M, Mac Dowell N, Welton T, Shah N, Hallett JP (2014) Inexpensive ionic liquids: [HSO4]−-based solvent production at bulk scale. Green Chem 16:3098–3106
Pinkert A, Goeke DF, Marsh KN, Pang S (2011) Extracting wood lignin without dissolving or degrading cellulose: investigations on the use of food additive-derived ionic liquids. Green Chem 13:3124
Yan P, Xu Z, Zhang C, Liu X, Xu W, Zhang ZC (2015) Fractionation of lignin from eucalyptus bark using amine-sulfonate functionalized ionic liquids. Green Chem 17:4913–4920
Muhammad N, Man Z, Bustam MA, Mutalib MIA, Rafiq S (2013) Investigations of novel nitrile-based ionic liquids as pre-treatment solvent for extraction of lignin from bamboo biomass. J Ind Eng Chem 19:207–214
Costa SPF, Azevedo AMO, Pinto PCAG, Saraiva MLMFS (2017) Environmental impact of ionic liquids: recent advances in (Eco)toxicology and (Bio)degradability. ChemSusChem 10:2321–2347
Hou X-D, Smith TJ, Li N, Zong M-H (2012) Novel renewable ionic liquids as highly effective solvents for pretreatment of rice straw biomass by selective removal of lignin. Biotechnol Bioeng 109:2484–2493
Hou X-D, Li N, Zong M-H (2013) Renewable bio ionic liquids-water mixtures-mediated selective removal of lignin from rice straw: visualization of changes in composition and cell wall structure. Biotechnol Bioeng 110:1895–1902
Liu Q-P, Hou X-D, Li N, Zong M-H (2012) Ionic liquids from renewable biomaterials: synthesis, characterization and application in the pretreatment of biomass. Green Chem 14:304–307
Ninomiya K, Yamauchi T, Kobayashi M, Ogino C, Shimizu N, Takahashi K (2013) Cholinium carboxylate ionic liquids for pretreatment of lignocellulosic materials to enhance subsequent enzymatic saccharification. Biochem Eng J 71:25–29
Ninomiya K, Kohori A, Tatsumi M, Osawa K, Endo T, Kakuchi R, Ogino C, Shimizu N, Takahashi K (2015) Ionic liquid/ultrasound pretreatment and in situ enzymatic saccharification of bagasse using biocompatible cholinium ionic liquid. Bioresour Technol 176:169–174
Hou XD, Li N, Zong MH (2013) Significantly enhancing enzymatic hydrolysis of rice straw after pretreatment using renewable ionic liquid-water mixtures. Bioresour Technol 136:469–474
Anugwom I, Mäki-Arvela P, Virtanen P, Willför S, Damlin P, Hedenström M, Mikkola J-P (2012) Treating birch wood with a switchable 1,8-diazabicyclo-[5.4.0]-undec-7-ene-glycerol carbonate ionic liquid. Holzforschung 66:809–815
Eta V, Mikkola J-P (2016) Deconstruction of Nordic hardwood in switchable ionic liquids and acylation of the dissolved cellulose. Carbohydr Polym 136:459–465
Anugwom I, Eta V, Virtanen P, Mäki-Arvela P, Hedenström M, Hummel M, Sixta H, Mikkola J-P (2014) Switchable ionic liquids as delignification solvents for lignocellulosic materials. ChemSusChem 7:1170–1176
Brandt A, Chen L, van Dongen BE, Welton T, Hallett JP (2015) Structural changes in lignins isolated using an acidic ionic liquid water mixture. Green Chem 17:5019–5034
Klein-Marcuschamer D, Simmons BA, Blanch HW (2011) Techno-economic analysis of a lignocellulosic ethanol biorefinery with ionic liquid pre-treatment. Biofuels Bioprod Biorefin 5:562–569
Li C, Zhao ZK (2007) Efficient acid-catalyzed hydrolysis of cellulose in ionic liquid. Adv Synth Catal 349:1847–1850
Shill K, Miller K, Clark DS, Blanch HW (2012) A model for optimizing the enzymatic hydrolysis of ionic liquid-pretreated lignocellulose. Bioresour Technol 126:290–297. Elsevier Ltd
Shi J, Gladden JM, Sathitsuksanoh N, Kambam P, Sandoval L, Mitra D, Zhang S, George A, Singer SW, Simmons BA, Singh S (2013) One-pot ionic liquid pretreatment and saccharification of switchgrass. Green Chem 15:2579
Park JI, Steen EJ, Burd H, Evans SS, Redding-Johnson AM, Batth T, Benke PI, D’haeseleer P, Sun N, Sale KL, Keasling JD, Lee TS, Petzold CJ, Mukhopadhyay A, Singer SW, Simmons BA, Gladden JM (2012) A thermophilic ionic liquid-tolerant cellulase cocktail for the production of cellulosic biofuels. PLoS One 7:1–10
Erbeldinger M, Mesiano AJ, Russell AJ (2000) Enzymatic catalysis of formation of Z -aspartame in ionic liquid – an alternative to enzymatic catalysis in organic solvents. Biotechnol Prog 16(6):1129–1131
Rinaldi R, Schüth F (2009) Acid hydrolysis of cellulose as the entry point into biorefinery schemes. ChemSusChem 2:1096–1107
Li C, Wang Q, Zhao ZK (2008) Acid in ionic liquid: an efficient system for hydrolysis of lignocellulose. Green Chem 10:177–182
Zhou N, Zhang Y, Gong X, Wang Q, Ma Y (2012) Ionic liquids-based hydrolysis of Chlorella biomass for fermentable sugars. Bioresour Technol 118:512–517
de HFN O, Fares C, Rinaldi R (2015) Beyond a solvent: the roles of 1-butyl-3-methylimidazolium chloride in the acid-catalysis for cellulose depolymerisation. Chem Sci 6:5215–5224
Binder JB, Raines RT (2010) Fermentable sugars by chemical hydrolysis of biomass. Proc Natl Acad Sci 107:4516–4521
Zhang Z, Zhao ZK (2009) Solid acid and microwave-assisted hydrolysis of cellulose in ionic liquid. Carbohydr Res 344:2069–2072
Morales-delaRosa S, Campos-Martin JM, Fierro JLG (2012) High glucose yields from the hydrolysis of cellulose dissolved in ionic liquids. Chem Eng J 181–182:538–541
Yang Q, Wei Z, Xing H, Ren Q (2008) Brönsted acidic ionic liquids as novel catalysts for the hydrolyzation of soybean isoflavone glycosides. Catal Commun 9:1307–1311
Amarasekara AS, Wiredu B (2014) Sulfonic acid group functionalized ionic liquid catalyzed hydrolysis of cellulose in water: structure activity relationships. Sustain Energy 2:102–107
Hernoux-Villière A, Lévêque JM, Kärkkäinen J, Papaiconomou N, Lajunen M, Lassi U (2014) Task-specific ionic liquid for the depolymerisation of starch-based industrial waste into high reducing sugars. Catal Today 223:11–17. Elsevier B.V.
Amarasekara AS, Owereh OS (2010) Synthesis of a sulfonic acid functionalized acidic ionic liquid modified silica catalyst and applications in the hydrolysis of cellulose. Catal Commun 11:1072–1075
Hsu WH, Lee YY, Peng WH, Wu KCW (2011) Cellulosic conversion in ionic liquids (ILs): effects of H 2O/cellulose molar ratios, temperatures, times, and different ILs on the production of monosaccharides and 5-hydroxymethylfurfural (HMF). Catal Today 174:65–69. Elsevier B.V.
Hu L, Sun Y, Lin L (2012) Efficient conversion of glucose into 5-hydroxymethylfurfural by chromium(III) chloride in inexpensive ionic liquid. Ind Eng Chem Res 51:1099–1104
Li C, Zhao ZK, Wang A, Zheng M, Zhang T (2010) Production of 5-hydroxymethylfurfural in ionic liquids under high fructose concentration conditions. Carbohydr Res 345:1846–1850
Zhao H, Holladay JE, Brown H, Zhang ZC ((2007)) Metal chlorides in ionic liquid solvents convert sugar to 5-hydroxymethyfurfural. Science (80-) 316:1597–1600
Tao F, Song H, Chou L (2011) Hydrolysis of cellulose in SO3H-functionalized ionic liquids. Bioresour Technol 102:9000–9006
Zhang L, Yu H, Wang P (2013) Solid acids as catalysts for the conversion of d-xylose, xylan and lignocellulosics into furfural in ionic liquid. Bioresour Technol 136:515–521
Zhou P, Zhang Z (2016) One-pot catalytic conversion of carbohydrates into furfural and 5-hydroxymethylfurfural. Catal Sci Technol 6:3694–3712
Qu Y, Huang C, Zhang J, Chen B (2012) Efficient dehydration of fructose to 5-hydroxymethylfurfural catalyzed by a recyclable sulfonated organic heteropolyacid salt. Bioresour Technol 106:170–172
Peleteiro S, Da C, Lopes AM, Garrote G, Parajó JC, Bogel-Łukasik R (2015) Simple and efficient furfural production from xylose in media containing 1-butyl-3-methylimidazolium hydrogen sulfate. Ind Eng Chem Res 54:8368–8373
Qu Y, Li L, Wei Q, Huang C, Oleskowicz-Popiel P, Xu J (2016) One-pot conversion of disaccharide into 5-hydroxymethylfurfural catalyzed by imidazole ionic liquid. Sci Rep 6:1–7
Ren H, Zhou Y, Liu L (2013) Selective conversion of cellulose to levulinic acid via microwave-assisted synthesis in ionic liquids. Bioresour Technol 129:616–619
Ferreira AM, Morais ES, Leite AC, Mohamadou A, Holmbom B, Holmbom T, Neves BM, Coutinho JAP, Freire MG, Silvestre AJD, Paracchini S, Lecchini S (2017) Enhanced extraction and biological activity of 7-hydroxymatairesinol obtained from Norway spruce knots using aqueous solutions of ionic liquids. Green Chem 19:2626–2635
Du FY, Xiao XH, Li GK (2007) Application of ionic liquids in the microwave-assisted extraction of trans-resveratrol from Rhizma Polygoni Cuspidati. J Chromatogr A 1140:56–62
Zhang L, Geng Y, Duan W, Wang D, Fu M, Wang X (2009) Ionic liquid-based ultrasound-assisted extraction of fangchinoline and tetrandrine from Stephaniae tetrandrae. J Sep Sci 32:3550–3554
Lu C, Wang H, Lv W, Ma C, Lou Z, Xie J, Liu B (2012) Ionic liquid-based ultrasonic/microwave-assisted extraction combined with UPLC-MS-MS for the determination of tannins in Galla chinensis. Nat Prod Res 26:1842–1847
Cao X, Ye X, Lu Y, Yu Y, Mo W (2009) Ionic liquid-based ultrasonic-assisted extraction of piperine from white pepper. Anal Chim Acta 640:47–51
Tian M, Yan H, Row KH (2009) Solid-phase extraction of tanshinones from Salvia Miltiorrhiza Bunge using ionic liquid-modified silica sorbents. J Chromatogr B Anal Technol Biomed Life Sci 877:738–742
Tian M, Row KH (2011) SPE of tanshinones from salvia miltiorrhiza bunge by using imprinted functionalized ionic liquid-modified silica. Chromatographia 73:25–31
Wang M, Wang J, Zhang Y, Xia Q, Bi W, Yang X, Chen DDY (2016) Fast environment-friendly ball mill-assisted deep eutectic solvent-based extraction of natural products. J Chromatogr A 1443:262–266
Tian M, Bi W, Row KH (2009) Solid-phase extraction of liquiritin and glycyrrhizic acid from licorice using ionic liquid-based silica sorbent. J Sep Sci 32:4033–4039
Bi W, Zhou J, Row KH (2012) Solid phase extraction of three phenolic acids from Saliconia Herbacel L. by different ionic liquids. J Liq Chromatogr Relat Technol 35:723–736
Bi W, Tian M, Row KH (2012) Selective extraction and separation of oxymatrine from Sophora flavescens Ait. extract by silica-confined ionic liquid. J Chromatogr B Analyt Technol Biomed Life Sci 880:108–113
Bi W, Tian M, Row KH (2010) Solid-phase extraction of matrine and oxymatrine from Sophora flavescens ait using amino-imidazolium polymer. J Sep Sci 33:1739–1745
Tian M, Yan H, Row KH (2010) Solid-phase extraction of caffeine and theophylline from green tea by a new ionic liquid-modified functional polymer sorbent. Anal Lett 43:110–118
Li S, He C, Liu H, Li K, Liu F (2005) Ionic liquid-based aqueous two-phase system, a sample pretreatment procedure prior to high-performance liquid chromatography of opium alkaloids. J Chromatogr B Analyt Technol Biomed Life Sci 826:58–62
Freire MG, Neves CMSS, Marrucho IM, Canongia Lopes JN, Rebelo LPN, Coutinho JAP (2010) High-performance extraction of alkaloids using aqueous two-phase systems with ionic liquids. Green Chem 12:1715
Cláudio AFM, Ferreira AM, Freire MG, Coutinho JAP (2013) Enhanced extraction of caffeine from guaraná seeds using aqueous solutions of ionic liquids. Green Chem 15:2002
Tan Z j, Li F f, Xu X l, Xing J m (2012) Simultaneous extraction and purification of aloe polysaccharides and proteins using ionic liquid based aqueous two-phase system coupled with dialysis membrane. Desalination 286:389–393
Chowdhury SA, Vijayaraghavan R, MacFarlane DR (2010) Distillable ionic liquid extraction of tannins from plant materials. Green Chem 12:1023–1028
Vijayaraghavan R, Macfarlane DR (2014) CO2-based alkyl carbamate ionic liquids asdistillable extraction solvents. ACS Sustain Chem Eng 2:1724–1728
Prado R, Erdocia X, De Gregorio GF, Labidi J, Welton T (2016) Willow lignin pxidation and depolymerization under low cost ionic liquid. ACS Sustain Chem Eng 4. https://doi.org/10.1021/acssuschemeng.6b00642
George A, Tran K, Morgan TJ, Benke PI, Berrueco C, Lorente E, Wu BC, Keasling JD, Simmons BA, Holmes BM (2011) The effect of ionic liquid cation and anion combinations on the macromolecular structure of lignins. Green Chem 13:3375
Cox BJ, Ekerdt JG (2012) Depolymerization of oak wood lignin under mild conditions using the acidic ionic liquid 1-H-3-methylimidazolium chloride as both solvent and catalyst. Bioresour Technol 118:584–588
Hong S, Lian H, Pan M, Chen L (2017) Structural changes of lignin after ionic liquid pretreatment. Bioresources 12:3017–3029
Wen J-L, Sun S-L, Xue B-L, Sun R-C (2013) Quantitative structures and thermal properties of birch lignins after ionic liquid pretreatment. J Agric Food Chem 61:635–645
Prado R, Brandt A, Erdocia X, Hallet J, Welton T, Labidi J (2016) Lignin oxidation and depolymerisation in ionic liquids. Green Chem 18:834–841
De Gregorio GF, Prado R, Vriamont C, Erdocia X, Labidi J, Hallett JPJP, Welton T (2016) Oxidative depolymerization of lignin using a novel polyoxometalate-protic ionic liquid system. ACS Sustain Chem Eng 4:6031–6036
Sun N, Jiang X, Maxim ML, Metlen A, Rogers RD (2011) Use of polyoxometalate catalysts in ionic liquids to enhance the dissolution and delignification of woody biomass. ChemSusChem 4:65–73
Yinghuai Z, Yuanting KT, Hosmane NS (2013) Applications of ionic liquids in lignin chemistry. In: Canning J, Bandyopadhyay S, Biswas P, Aslund M (eds) Ionic liquids – new aspects for the future. Intech Open, London
Zhu Y, Chuanzhao L, Sudarmadji M, Hui Min N, Biying AO, Maguire JA, Hosmane NS (2012) An efficient and recyclable catalytic system comprising Nanopalladium(0) and a Pyridinium salt of Iron Bis(dicarbollide) for Oxidation of substituted benzyl alcohol and lignin. ChemistryOpen 1:67–70
Denicourt-Nowicki A, Léger B, Roucoux A (2011) N-Donor ligands based on bipyridine and ionic liquids: an efficient partnership to stabilize rhodium colloids. Focus on oxygen-containing compounds hydrogenation. Phys Chem Chem Phys 13:13510–13517
Jiang N, Ragauskas AJ (2007) Selective aerobic oxidation of activated alcohols into acids or aldehydes in ionic liquids. J Org Chem 72:7030–7033
Zakzeski J, Jongerius AL, Weckhuysen BM (2010) Transition metal catalyzed oxidation of Alcell lignin, soda lignin, and lignin model compounds in ionic liquids. Green Chem 12:1225
Fukaya Y, Sugimoto A, Ohno H (2006) Superior solubility of polysaccharides in low viscosity, polar and halogen-free 1,3-dialkylimidazolium formates. Biomacromolecules 7:3295–3297
Liu Q, Janssen MHA, van Rantwijk F, Sheldon RA (2005) Room-temperature ionic liquids that dissolve carbohydrates in high concentrations. Green Chem 7:39
Wu Y, Sasaki T, Irie S, Sakurai K (2008) A novel biomass-ionic liquid platform for the utilization of native chitin. Polymer (Guildf) 49:2321–2327
Idris A, Vijayaraghavan R, Patti AF, Macfarlane DR (2014) Distillable protic ionic liquids for keratin dissolution and recovery. ACS Sustain Chem Eng 2:1888–1894
Aaltonen O, Jauhiainen O (2009) The preparation of lignocellulosic aerogels from ionic liquid solutions. Carbohydr Polym 75:125–129
Yamazaki S, Takegawa A, Kaneko Y, ichi KJ, Yamagata M, Ishikawa M (2009) An acidic cellulose-chitin hybrid gel as novel electrolyte for an electric double layer capacitor. Electrochem Commun 11:68–70
Xie H, Zhang S, Li S (2006) Chitin and chitosan dissolved in ionic liquids as reversible sorbents of CO2. Green Chem 8:630–633
Zhang H, Wang Z, Zhang Z, Wu J, Zhang J, He J (2007) Regenerated-cellulose/multiwalled-carbon-nanotube composite fibers with enhanced mechanical properties prepared with the ionic liquid 1-allyl-3-methylimidazolium chloride. Adv Mater 19:698–704
Wu RL, Wang XL, Li F, Li HZ, Wang YZ (2009) Green composite films prepared from cellulose, starch and lignin in room-temperature ionic liquid. Bioresour Technol 100:2569–2574
Abdulkhani A, Hojati Marvast E, Ashori A, Karimi AN (2013) Effects of dissolution of some lignocellulosic materials with ionic liquids as green solvents on mechanical and physical properties of composite films. Carbohydr Polym 95:57–63
Xia G, Wan J, Zhang J, Zhang X, Xu L, Wu J, He J, Zhang J (2016) Cellulose-based films prepared directly from waste newspapers via an ionic liquid. Carbohydr Polym 151:223–229
Pang J, Wu M, Zhang Q, Tan X, Xu F, Zhang X, Sun R (2015) Comparison of physical properties of regenerated cellulose films fabricated with different cellulose feedstocks in ionic liquid. Carbohydr Polym 121:71–78
Ma Y, Asaadi S, Johansson LS, Ahvenainen P, Reza M, Alekhina M, Rautkari L, Michud A, Hauru L, Hummel M, Sixta H (2015) High-strength composite fibers from cellulose-lignin blends regenerated from ionic liquid solution. ChemSusChem 8:4030–4039
Mu L, Shi Y, Guo X, Ji T, Chen L, Yuan R, Brisbin L, Wang H, Zhu J (2015) Non-corrosive green lubricants: strengthened lignin–[choline][amino acid] ionic liquids interaction via reciprocal hydrogen bonding. RSC Adv 5:66067–66072
Younesi-Kordkheili H, Pizzi A (2016) A comparison between lignin modified by ionic liquids and glyoxalated lignin as modifiers of urea-formaldehyde resin. J Adhes 0:1–11
Wu J, Zhang J, Zhang H, He J, Ren Q, Guo M (2004) Homogeneous acetylation of cellulose in a new ionic liquid. Biomacromolecules 5:266–268
Clough MT (2017) Organic electrolyte solutions as versatile media for the dissolution and regeneration of cellulose. Green Chem 19:4754–4768
Xu F, Sun J, Konda NVSNM, Shi J, Dutta T, Scown CD, Simmons BA, Singh S (2016) Transforming biomass conversion with ionic liquids: process intensification and the development of a high-gravity, one-pot process for the production of cellulosic ethanol. Energy Environ Sci 9:1042–1049
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Prado, R., Weigand, L., Welton, T. (2018). Use of Ionic Liquids for the Biorefinery. In: Meyers, R. (eds) Encyclopedia of Sustainability Science and Technology. Springer, New York, NY. https://doi.org/10.1007/978-1-4939-2493-6_1003-1
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