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Chanoclavine-I

Reference work entry

CAS Registry Number: 2390-99-0 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Miscellaneous Alkaloids

Biological sources: Claviceps purpurea

C16H20N2O: 256.1576

Mp: 208–210°C (dec.) [1], 214–216°C [2], 220–222°C [3]; 186°C (dec., oxalate), 224°C (dec., mono Ac), 170°C (dec., di Ac) [1]

[α]D −197° (EtOH) [1], −214° (Py) [2], −240° (Py) [3]

Solubility: very sol. MeOH; insol. Me2CO, H2O [1]

UV: 224, 273 sh, 283, 292(4.51, 3.82, 3.84, 3.78) [2, 3]

IR: 3310, 3260, 3130, 1615, 1598 [1, 3]

MSm/z: 256(M+, 100), 238, 237, 183, 168, 155, 108 [2]

1H NMR: [2]

Stereochemistry: [4]

References

  1. 1.
    L.D. Vechkanova, A.N. Ban’kovskaya, A.I. Ban’kovskii, Chem. Nat. Comp. 6, 393 (1970)CrossRefGoogle Scholar
  2. 2.
    A.G. Kozlovskii, M.U. Arinbasarov, T.F. Solov’eva, V.M. Adanin, I. Grigorov, T.I. Angelov, L.S. Slokoska, M.B. Angelova, Prikl. Biokhim. Mikrobiol. 16, 569 (1980)Google Scholar
  3. 3.
    A. Hofmann, R. Brunner, H. Kobel, A. Brack, Helv. Chim. Acta 40, 1358 (1957)CrossRefGoogle Scholar
  4. 4.
    V.G. Sakharovskii, A.V. Aripovskii, M.B. Baru, A.G. Kozlovskii, Chem. Nat. Comp. 19, 626 (1983)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2013

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