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Acutumine

Reference work entry

CAS Registry Number: 17088-50-5 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Miscellaneous Alkaloids

Biological sources: Menispermum dauricum

C19H24NO6Cl: 397.1292/399.1263

Mp: 241°C (dec., EtOH–EtOAc) [1]

[α]D −120° (Py) [1]

Solubility: sol. CHCl3, Py; sp. sol. Et2O, EtOH [1]

IR: 1690, 1670, 1625, 1605 [2]

MSm/z: 397(M+), 362, 209(100), 194, 181, 166, 150 [2]

1H NMR(Py-d5): 2.27(3H, s, NCH3), 3.72, 3.79, 4.04(each 3H, s, 3 × OCH3), 5.01, 5.59(each 1H, d, J = 0.8, CH = C–CH–OH), 5.18(1H, q, J = 7.5, CH2–CHCl) [2]

References

  1. 1.
    T.N. Il’inskaya, Aptech. Delo (6), 10 (1958)Google Scholar
  2. 2.
    M. Tomita, Y. Okamoto, T. Kikuchi, K. Osaki, M. Nishikawa, K. Kamiya, Y. Sasaki, K. Matoba, K. Goto, Tetrahedron Lett. 8, 2421 (1967)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2013

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