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Hippeastrine (Trispherine)

  • Reference work entry
Natural Compounds

  • 61 Accesses

CAS Registry Number: 477-17-8

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Amaryllidaceae Alkaloids

Biological sources: Clivia miniata, Crinum amabile, C. giganteum, Galanthus nivalis, Hippeastrum equestre, Hymenocallis littoralis, Pancratium trianthum, Ungernia ferganica, U. sewertzowii, U.spiralis, U. tadshicorum, U. trisphaera, U. victoris, U. vvedenskyi

C17H17NO5: 315.1107

Mp: 209–210°C (MeOH) [1]

[α]D +122° (EtOH) [1], 267° (hydrobromide) [1], 218° (methiodide) [1], 258° (perchlorate) [1], 271° (nitrate) [1], 281° (hydrochloride) [1], 243° (picrate) [1]

Solubility: sol.MeOH, EtOH, CHCl3; spar. sol. Me2CO, Et2O; insol. H2O [1]

UV: 227, 267, 308 [2]

IR: 3600, 3015, 2960, 2920, 2860, 2790, 1715, 1618, 1508, 1484, 1453, 1400, 1387, 1354, 1338, 1318, 1293, 1252, 1190, 1152, 1121, 1058, 1041, 998, 983, 955, 943, 905, 888, 864, 841, 824 [2]

MS m/z: 315(M+, 0.7), 298(1), 297(2.3), 125(100), 124(13), 96(19) [3]

1 H NMR: 5.65 (H-4), 4.58 (H-5a), 4.38 (H-5), 7.43...

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References

  1. Kh. Allayarov, Kh.A. Abduazimov, S.Yu. Yunusov, DAN UzSSR (10), 25 (1961)

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  2. J. Holubek, O. Strouf, Spectral Data and Physical Constants of Alkaloids (Prague Publishing House, Czechoslovak Academy of Sciences, Heyden & Son Ltd., London, 1966), 2, No. 339

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  6. U.B. Zakirov, N.V. Abdumalikova, I.K. Kamilov, The Pharmacology and Pharmacotherapy of Alkaloids and Glycosides [in Russian] (Fan, Tashkent, 1966), p. 40

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Editor information

Editors and Affiliations

  1. S.Yu. Yunusov Institute of the Chemistry of Plant Substances of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan

    Shakhnoza S. Azimova

  2. S.Yu. Yunusov Institute of the Chemistry of Plant Substances of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, Republic of Uzbekistan

    Marat S. Yunusov

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(2013). Hippeastrine (Trispherine). In: Azimova, S.S., Yunusov, M.S. (eds) Natural Compounds. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0560-3_61

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