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Sparteine

Reference work entry

CAS Registry Number: 90-39-1 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Quinolizidine Alkaloids

Biological sources: Ammopiptanthus mongolicus, Cytisus ratisbonensis, C. ruthenicus, Piptanthus nanus

C15H26N2: 234.2096

Mp: 188°C (18 mm Hg) [1], 173°C (perchlorate), 208°C (dipicrate), 235°C (hydroiodide), 258°C (dihydroiodide) [1, 2]

[α]D −17° (EtOH), −13° (EtOH)

UV: 214(3.70) [3]

IR: 1471, 1449, 1398, 1378, 1355, 1341, 1328, 1307, 1294, 1271, 1258, 1249, 1234, 1196, 1184, 1149, 1129, 1116, 1084, 1076, 1060, 1049, 1039, 1018, 976, 948, 939, 922, 905, 883, 870, 853, 846, 839, 828, 786, 736 [3]

MSm/z: 234(M+, 17), 193(24), 150(12), 137(87), 110(23), 98(100), 97(41), 84(22), 55(23), 41(39), [4]

1H NMR: 0.90(1H, J = 11, 2, 2, Ha-8), 1.30(1H, H-9), 1.65(1H, H-7), 1.87(2H, J = 10, Ha-2, Ha-15), 1.90(1H, J = 10.5, 2.5, Ha-10), 2.02(1H, J = 11, He-8), 2.22(1H, J = 10.6, 2, Ha-17), 2.42(1H, J = 10, He-10), 2.50(1H, J = 10.6, 10, He-17),...

References

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    A.S. Sadykov, Kh.A. Aslanov, Yu.K. Kushmuradov, Alkaloids of the Quinolizidine Series [in Russian] (Nauka, Moscow, 1975), p. 217Google Scholar
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    J. Holubek, O. Strouf, Spectral Data and Physical Constants of Alkaloids (Prague Publishing House, Czechoslovak Academy of Sciences, Heyden & Son Ltd, London, 1966), 2, No. 391Google Scholar
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    S.W. Pelletier (ed.), Alkaloids, Chemical and Biological Perspectives, vol. 2 (Wiley, New York, 1984), p. 105Google Scholar
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    M. Shamma, D.M. Hindenlang, Carbon-13 NMR Shift Assignments of Amines and Alkaloids (Plenum Press, NewYork/London, 1979). No. 197CrossRefGoogle Scholar
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    F.S. Sadritdinov, A.G. Kurmukov, The Pharmacology of the Plant Alkaloids and Their Use in Medicine [in Russian] (UzSSR, Tashkent, 1980), p. 145Google Scholar
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    M.D. Mashkovskii, Drugs [in Russian], vol. 1 (Meditsina, Moscow, 1978), 1, p. 245Google Scholar

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