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Sparteine

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CAS Registry Number: 90-39-1

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Quinolizidine Alkaloids

Biological sources: Ammopiptanthus mongolicus, Cytisus ratisbonensis, C. ruthenicus, Piptanthus nanus

C15H26N2: 234.2096

Mp: 188°C (18 mm Hg) [1], 173°C (perchlorate), 208°C (dipicrate), 235°C (hydroiodide), 258°C (dihydroiodide) [1, 2]

[α]D −17° (EtOH), −13° (EtOH)

UV: 214(3.70) [3]

IR: 1471, 1449, 1398, 1378, 1355, 1341, 1328, 1307, 1294, 1271, 1258, 1249, 1234, 1196, 1184, 1149, 1129, 1116, 1084, 1076, 1060, 1049, 1039, 1018, 976, 948, 939, 922, 905, 883, 870, 853, 846, 839, 828, 786, 736 [3]

MS m/z: 234(M+, 17), 193(24), 150(12), 137(87), 110(23), 98(100), 97(41), 84(22), 55(23), 41(39), [4]

1 H NMR: 0.90(1H, J = 11, 2, 2, Ha-8), 1.30(1H, H-9), 1.65(1H, H-7), 1.87(2H, J = 10, Ha-2, Ha-15), 1.90(1H, J = 10.5, 2.5, Ha-10), 2.02(1H, J = 11, He-8), 2.22(1H, J = 10.6, 2, Ha-17), 2.42(1H, J = 10, He-10), 2.50(1H, J = 10.6, 10, He-17), 2.56(2H, J = 10, He-2, He-15)...

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References

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(2013). Sparteine. In: Azimova, S.S., Yunusov, M.S. (eds) Natural Compounds. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0560-3_1265

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