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Reference work entry

CAS Registry Number: 2122-29-4 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Quinolizidine Alkaloids

Biological sources: Genista aethnensis

C15H26N2O: 250.2045

Mp: 167–168°C (EtOH), 278°C (dec., hydrochloride), 217°C (dec., methiodide), 175°C (dipicrate) [1]

[α]D +45° (EtOH) [1]

Solubility: very sol. EtOH, Et2O, CHCl3, C6H6; spar. sol. H2O [1]

UV: [1]

IR: 3510, 3010, 2940, 2855, 2810, 2770, 2760, 1473, 1450, 1378, 1360, 1350, 1324, 1304, 1270, 1188, 1155, 1148, 1125, 1115, 1079, 1066, 1034, 1028, 1011, 994, 961, 935, 911, 896, 879, 854, 840, 829, 824 [2]

MSm/z: 250(M+), 232, 207(15), 175(10), 150, 135(18), 134(24), 98(100), 97(28), 96(21), 84(17) [3]

13 C NMR: [ 4]

Table 1

C-2

56.2

C-7

33.0

C-12

70.7

 3

25.8

 8

28.4

 13

31.4

 4

24.6

 9

32.7

 14

19.8

 5

29.3

 10

62.3

 15

55.0

 6

66.3

 11

67.7

 17

52.9

References

  1. 1.
    A.I. Ban’kovskii, V.I. Frolova, E.S. Zheleznova, Trudy VILAR 11, 99 (1959)Google Scholar
  2. 2.
    F. Bohlmann, H. Overwien, D. Schumann, Chem. Ber. 98, 659 (1965)CrossRefGoogle Scholar
  3. 3.
    N. Neuner-Jehle, D. Schumann, G. Spiteller, Monatsh. Chem. 98, 836 (1967)CrossRefGoogle Scholar
  4. 4.
    M. Shamma, D.M. Hindenlang, Carbon-13 NMR Shift Assignments of Amines and Alkaloids (Plenum Press, NewYork/London, 1979), No. 201CrossRefGoogle Scholar
  5. 5.
    K.H. Shin, L. Fonzes, L. Marion, Can. J. Chem. 43, 2012 (1965)CrossRefGoogle Scholar
  6. 6.
    F.S. Sadritdinov, A.G. Kurmukov, The Pharmacology of the Plant Alkaloids and Their Use in Medicine [in Russian] (UzSSR, Tashkent, 1980), p. 144Google Scholar

Copyright information

© Springer Science+Business Media New York 2013

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