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Matrine N-Oxide

Reference work entry

CAS Registry Number: 16837-52-8 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Quinolizidine Alkaloids

Biological sources: Ammothamnus lehmannii, A. songoricus, Sophora alopecuroides, S. flavescens, S. pachycarpa

C15H24N2O2: 264.1836

Mp: 208°C (Me2CO) 216°C (picrate), 240°C (dec., perchlorate), 285°C (dec., methiodide), 163°C (hydrate) [1]

[α]D +30° [1]

MSm/z: 264(M+), 248, 247, 245, 231, 218, 205, 190, 176, 162, 150, 148(100), 138, 122, 110, 98, 96, 84, 80, 67, 55 [2]

13 C NMR: [ 3]

Table 1

C-2

68.8

C-7

43.3

C-12

26.8

 3

19.4

 8

29.2

 13

17.9

 4

25.3

 9

17.9

 14

33.7

 5

35.2

 10

68.4

 15

169.5

 6

66.3

 11

53.8

 17

43.5

References

  1. 1.
    S.Yu. Yunusov, Alkaloids [in Russian] (Fan, Tashkent, 1981), p. 220Google Scholar
  2. 2.
    V.G. Zaikin, Z.S. Ziyavidinova, N.S. Vul’fson, Izv. AN SSSR, Ser. Khim. 8, 1734 (1974)Google Scholar
  3. 3.
    A. S. Sadykov, Izv. AN SSSR, Ser. Khim. (11), 2432 (1983)Google Scholar
  4. 4.
    A. Ueno, K. Morinaga, S. Fukushima, S. Okuda, Chem. Pharm. Bull. 26, 1832 (1978)CrossRefGoogle Scholar
  5. 5.
    X. Chen, C.Q. Yi, X.Q. Yang, X. Wang, J. Chromatogr. B 812, 149 (2004)Google Scholar

Copyright information

© Springer Science+Business Media New York 2013

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