Abstract
This chapter provides an overview of powder-forming methods for ceramics and metals. Powder forming is distinct from traditional melt-forming methods in that it involves forming a component from powder and densifying it without melting, via solid state sintering. Sintering typically occurs at around 80 % of the melting point. The primary benefits of powder forming are as follows: (a) reduced forming temperature (reduced energy cost), (b) capability for engineered porosity, (c) elimination of mold component reactions caused by melt forming, and (d) suitability for mass production of small metal components and ceramics of all shapes and sizes. Almost all ceramics are manufactured by powder forming. Most metals are formed by melt casting; however, powder metallurgy has grown into a large industry. This overview begins with a review of powder characterization and powder manufacturing techniques. Powder-forming techniques are then reviewed including the two main dry-forming methods (die pressing, cold isostatic pressing) and a range of wet-forming techniques including extrusion, plastic forming, slipcasting, tapecasting, powder injection molding, direct coagulation casting, gelcasting, and thixotropic casting. The overview then discusses powder densification techniques including pressureless sintering, self-propagating high-temperature synthesis, microwave sintering, two-step sintering, hot-pressing, hot isostatic pressing, spark plasma sintering, and sinter forging. Future trends discussed include additive manufacturing (powder 3D printing), functionally graded materials, and hydrostatic shock forming.
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References
Adcock DS, McDowall IC (1957) The mechanism of filter pressing and slip casting. J Am Ceram Soc 40(10):355–360. doi:10.1111/j.1151-2916.1957.tb12552.x
Agrawal DK (1998) Microwave processing of ceramics. Curr Opin Solid State Mater Sci 3:480–485
Angelo C, Subramanian R (2008) Powder metallurgy: science, technology and applications. PHI Learning, Patparganj
ASTM Standard F2792 – 12a (1994) Standard terminology for additive manufacturing technologies. ASTM International, West Conshohocken. doi: 10.1520/F2792-12A, www.astm.org
Baader FH, Graule TJ, Gauckler LJ (1996) Direct coagulation casting – a new green shaping technique. Part I. Application to alumina. Ind Ceram 16:31–36
Balzer B, Gauckler LJ (2003) Novel colloidal forming techniques: direct coagulation casting. In: Somiaya S et al (eds) Hand book of advanced ceramics material science, vol 1. Elsevier, London, pp 453–458
Blackburn S, Wilson DI (2008) Shaping ceramics by plastic processing. J Eur Ceram Soc 28(7):1341–1351. doi:10.1016/j.jeurceramsoc.2007.12.013
Brunauer S, Emmett P, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60(2):309–319. doi:10.1021/ja01269a023
Caillard R, Garnier V, Desgardin G (2000) Sinter-forging conditions, texture and transport properties of Bi-2212 superconductors. Physica C: Superconductivity 340:101–111
Chartier T, Chaput C, Doreau F, Loiseau M (2002) Rapid prototyping of complex ceramic parts. TTP Key Engineering Materials, Euro Ceramics VII, 206–213:293–296, doi:10.4028/www.scientific.net/KEM.206-213.293
Chavara DT, Ruys AJ (2007) Development of the impeller-dry-blending process for the fabrication of metal-ceramic functionally graded materials. Ceram Eng Sci Proc 27:311–319
Chavara DT, Wang CX, Ruys AJ (2009a) Biomimetic functionally graded materials: synthesis by impeller dry blending. J Biomimet Biomater Tissue Eng 3:37–50
Chavara DT, Wang CX, Ruys AJ (2009b) Biomimetic functionally graded materials: synthesis by impeller dry blending. J Biomimet Biomater Tissue Eng 3:37–50
Chen IW, Wang XH (2000) Sintering dense nanocrystalline ceramics without final-stage grain growth. Nature 404:168–171
Chesters JH (1973) Refractories, production and properties. The Iron and Steel Institute, London
Chua CK, Leong KF, Lim CS (2003) Rapid prototyping, principles and applications, 2nd edn. World Scientific, Singapore
Danninger H, Jangg G, Tarani E, Schrey G (1990) PM grade iron powders by hydrogen reduction of oxides from pickling bath recovery plants. Metal Powder Rep 45(2):114–116
Djohari H, Derby JJ (2009) Transport mechanism and densification during sintering: II Grain boundaries. Chem Eng Sci 64:3799–3809
Dyroy A, Tveten E, Karlsen M, Scotland J (2008) Using real-time particle size analysis to optimize aluminium smelting. Powder Metal 51(4):291
Ehsani N, Ruys AJ, Sorrell CC (1995) Thixotropic casting of fecralloy fibre – reinforced hydroxyapatite. In: Metal matrix composites. Part 1: application and processing. Trans Tech Publications, Switzerland, pp 373–380
Ehsani N, Ruys AJ, Sorrell CC (1996) Thixotropic casting of monolithic nonclay ceramics. In: Symposium 4.1, second international meeting of pacific rim ceramic societies. PacRim, Australasian Ceramic Society, Sydney, pp 2–6
Francis JSC, Raj R (2012) Flash-Sinterforging of Nanograin Zirconia: field assisted sintering and superplasticity. J Am Ceram Soc 95:138–146
Froes FH, Suryanarayana C, Russell K, Ward-Close CM (1994) In Singh J, Copley SM (eds) Novel techniques in synthesis and processing of advanced materials. TMS, Warrendale, pp 1–21
Froes FH, Suryanarayana C, Russell K, Li C-G (1995) Synthesis of intermetallics by mechanical alloying. Mater Sci Eng A 192–195:612–623
German RM (2010) Coarsening in sintering: grain shape distribution, grain size distribution and grain growth kinetics in solid-pore systems. Crit Rev Solid State 35:263–305. doi:10.1080/10408436.2010.525197
German RM, Hens KF, Lin STP (1991) Key issues in powder injection molding. Am Ceram Soc Bull 70(8):1294–1302. doi:35400001258145.0040
Gingu O, Benga G, Olei A, Lupu N, Rotaru P, Tanasescu S, Mangra M, Ciupitu I, Pascu I, Sima G (2011) Wear behaviour of ceramic biocomposites based on hydroxyapatite nanopowder. Proc Inst Mech Eng E J Process Mech 225:62–71
Gu DD, Meiners W, Wissenbach K, Poprawe R (2012) Laser additive manufacturing of metallic components: materials, processes and mechanisms. Int Mater Rev 57:133–164
Guenther T, Kong C, Lu H, Svehla MJ, Lovell NH, Ruys A, Suaning GJ (2013) Pt-Al2O3 interface in cofired ceramics for use in miniaturized neuroprosthetic implants. J Biomed Mater Res, Part B: Applied Biomaterials (2014), 102B(3):500–507
Howatt GN (1952) Method of producing high-dielectric high-insulation ceramic plates, US Patent 2,582,993
Howatt GN, Breckenridge RG, Brownlow JM (1947) Fabrication of thin ceramic sheets for capacitors. J Am Ceram Soc 30:237–242
Huang Y, Ma LG, Le HR, Yang JL (2004) Improving the homogeneity and reliability of ceramic parts with complex shapes by pressure-assisted gel-casting. J Mat Let 58(30):3893–3897. doi:10.1016/j.matlet.2004.08.015
Huang Y, Zhang L, Yang J, Xie Z, Wang C, Chen R (2007) Research progress of new colloidal forming processes for advanced ceramics. Kuei Suan Jen Hsueh Pao/J Chinese Ceram Soc 35:129–136
Huisman W, Graule T, Gauckler LJ (1994) Centrifugal slip casting of zirconia (TZP). J Eur Ceram Soc 13(1):33–39. doi:10.1016/0955-2219(94)90055-8
Janney MA, Omatete OO (1989) Method for molding ceramic powders using a water-based gel casting. US Patent, Patent number: 5,145,908
Janney MA, Nunn SD, Walls CA, Omatete OO, Ogle RB, Kirby GH, McMillan AD (1998) Gelcasting. In: Rahaman MN (ed) The handbook of ceramic engineering, vol 1. Marcel Dekker, New York, pp 1–15
Kerdic JA, Ruys AJ, Sorrell CC (1996) Thixotropic casting of ceramic - metal functionally gradient materials. J Mater Sci 31:4347–4355
Langmuir I (1916) The constitution and fundamental properties of solids and liquids. Part I solids. J Am Chem Soc 38(11):2221–2295. doi:10.1021/ja02268a002
Legrand C, Da Costa F (1989) The effects of vibrations on the rheological behaviour of bentonite muds. Comparison with cement pastes. Mater Struct 22:133–137
Lewis JA (2000) Colloidal processing of ceramics. J Am Ceram Soc 83(10):2341–2359. doi:10.1111/j.1151-2916.2000.tb01560.x
Lowell S, Shields JE (1991) Powder surface area and porosity, 3rd edn. Chapman &Hall, London
Lupu N, Grigoras M, Lostun M, Chiriac H (2011) Spark plasma sintered NdFeB-based nanocomposite hard magnets with enhanced magnetic properties. In: Reddy B (ed) Advances in Nanocomposites Synthesis: Synthesis, Characterization and Industrial Applications. InTech Publishing House, ISBN 978-953-307-165-7, 23:537-560. doi: 10.5772/15459
Maleksaeedi S, Paydar MH, Ma J (2010) Centrifugal gel casting: a combined process for the consolidation of homogenous and reliable ceramics. J Am Ceram Soc 93(2):413–419. doi:10.1111/j.1551-2916.2009.03402.x
Merzhanov AG, Borovinskaya IP (1972) Self propagated high-temperature synthesis of refractory inorganic compounds. Doklady Akademii Nauk SSSR 204(2):366–369
Mistler RE (1990) Tape casting: the basic process for meeting the needs of the electronics industry. Am Ceram Soc Bull 69(6):1022–1026
Niino M (1990) Development of functionally gradient material. J Jpn Soc Powder Metall 37:241
Norton FH (1974) Elements of ceramics, 2nd edn. Addison-Wesley, London
Omatete OO, Janney MA, Nunn SD (1997) Gelcasting: from laboratory development toward industrial production. J Eur Ceram Soc 17(2–3):407–413. doi:10.1016/S0955-2219(96)00147-1
Piotter V, Finnah G, Zeep B, Ruprecht R, Hausselt J (2007) Metal and ceramic micro components made by powder injection molding. In: Yoon DY, Kang SJL, Eun KY and KimYS (eds) Materials science forum – Progress in powder metallurgy, Pts 1 and 2. vol 534–536, pp 373–376. doi: 10.4028/www.scientific.net/MSF.534-536.373
Piotter V, Beck MB, Ritzhaupt-Kleissl HJ, Ruh A, Hausselt J, Haubelt J (2008) Recent developments in micro ceramic injection molding. Int L Mat Res 99:1157–1162
Prabhakaran K, Melkeri A, Gokhale NM, Chongdar TK, Sharma SC (2009) Direct coagulation casting of YSZ powder suspensions using MgO as coagulating agent. J Ceram Soc 35(4):1487–1492. doi:10.1016/j.ceramint.2008.08.003
Rinehart JS, Pearson J (1963) Explosive working of metals. Pergamon Press, New York
Ring TA (1996) Fundamentals of ceramic powder processing and synthesis. Academic, London
Rouquerol F, Rouquerol J, Sing KSW (1999) Adsorption by powders and porous solids. Academic, San Diego
Roy R, Agrawal D, Cheng J, Gedevanishvili S (1999) Full sintering of powder metal bodies in a microwave field. Nature 399:668–670
Ruthner MJ (2012) Method for producing iron powder respectively microalloyed steel powder mainly for metallurgical applications and method for producing thereof. Patent no US 8,114,186 B2, 14 Feb 2012
Ruys AJ, Sorrell CC (1992) Production of fibre-reinforced bioceramics by thixotropic casting. In: Ceramics: adding the value. CSIRO Publications, Melbourne, pp 581–585
Ruys AJ, Sorrell CC (1994) Thixotropic casting of ceramic matrix composites. Int Ceram Monogr 1:692–700
Ruys AJ, Sorrell CC (1999) Thixotropic casting, ceramic monograph 1.4.2.5. In: Handbook of ceramics. Verlag Schmid GMBH, Freiburg, p 16
Ruys AJ, Simpson SA, Sorrell CC (1994) Thixotropic casting of fibre-reinforced ceramic matrix composites. J Mater Sci Lett 13:1323–1325
Ruys AJ, Popov EB, Sun D, Russell JJ, Murray CCJ (2001) Functionally graded electrical/thermal ceramic systems. J Eur Ceram Soc 21:2025–2029
Scott J, Gupta N, Weber C, Newsome S, Wohlers T, Caffrey T (2012) Additive manufacturing: status and opportunities. Science and Technology Policy Institute, Washington, DC
Shigeyuki S, Rustum R (2000) Hydrothermal synthesis of fine oxide powders. Bull Mater Sci 23(6):453–460. doi:10.1007/BF02903883
Sima G, Mangra M, Gingu O, Criveanu M, Olei A (2011) Influence of the reinforcing elements on the wear behavior of Al/(SiC+graphite) composites elaborated by Spark Plasma Sintering Technology. Mater Sci Forum 672:241–244
Sing KSW et al (1985) Reporting physisorption data for gas/solid systems. Pure Appl Chem 57:603–619
Stampfl J, Liu HC, Nam SW, Sakamoto K, Tsuru H, Kang SY, Cooper AG, Nickel A, Prinz FB (2002) Rapid prototyping and manufacturing by gelcasting of metallic and ceramic slurries. Mater Sci Eng A Struct Mater Prop Microstruct Process 334(1–2):187–192
Steinlage GA, Roeder RK, Trumble KP, Bowman KJ (1996) Centrifugal slip casting of components. Am Ceram Soc Bull 75(5):92–94
Stephan JG (2000) The lying stones of Marrakech. Penultimate reflections in natural history. Harmony Books, New York, http://www.wikipedia.org. Accessed 26 June 2012
Supati R, Loh NH, Khor KA, Tor SB (2000) Mixing and characterization of feedstock for powder injection molding. Mater Lett 46(2–3):109–114. doi:10.1016/S0167-577X(00)00151-8
Sushumna I, Gupta RK, Ruckenstein E (1991) Stable, highly concentrated suspensions for electronic and ceramic materials applications. J Mater Res 6:1082–1093
Suzuki K, Fujimori H, Hashimoto K (1982) Amorphous metals. Butterworths, London, p 327 (Moscow: Metallurgiya, Translated from Japanese into Russian)
Tiller FM, Tsai CD (1986) Theory of filtration of ceramics.1. Slip casting. J Am Ceram Soc 69(12):882–887. doi:10.1111/j.1151-2916.1986.tb07388.x
Tokita M (1993) Trends in advanced SPS Spark Plasma sintering systems and technology. J Soc Powder Techn Jpn 30:790–804
Tyagi R (2010) Microwave sinter-forging of zirconia ceramics. PhD thesis, presented to the Faculty of San Diego State University, USA, p 69
Vegad H (2007) “Old” technique reborn for nanoparticle size analysis with unparallel old resolution. Powder Metal 50(4):291
Wang YU (2006) Computer modeling and simulation of solid-state sintering: a phase field approach. Acta Mater 54:953–996
Yang J, Yu J, Huang Y (2011) Recent developments in gelcasting of ceramics. J Eur Ceram Soc 31(14):2569–2591. doi:10.1016/j.jeurceramsoc.2010.12.035
Ye H, Liu XY, Hong H (2008) Fabrication of metal matrix composites by metal injection molding – a review. J Mat Pro Tec 200(1–3):12–24. doi:10.1016/j.jmatprotec.2007.10.066
Yu Z, Huang Y, Wang C-A, Ouyang S (2004) A novel gel tape casting process based on gelation of sodium alginate. Ceram Int 30(4):503–507. doi:10.1016/j.ceramint.2003.08.003
Zhou WZ, Li DC, Wang H (2010) A novel aqueous ceramic suspension for ceramic stereolithography. Rapid Prototyping J 16(1):29–35. doi:10.1108/13552541011011686
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Appendices
Annex 1. ISO Standards with Relevance for Particle Characterization
Annex 1.1. ISO Technical Committee 206 (TC206) Fine Ceramics (selection)
References | Title |
---|---|
ISO 14703:2008 | Fine ceramics (advanced ceramics, advanced technical ceramics) – Sample preparation for the determination of particle size distribution of ceramic powders |
ISO 18753:2004 | Fine ceramics (advanced ceramics, advanced technical ceramics) – Determination of absolute density of ceramic powders by pycnometer |
ISO 18754:2003 | Fine ceramics (advanced ceramics, advanced technical ceramics) – Determination of density and apparent porosity |
ISO 18757:2003 | Fine ceramics (advanced ceramics, advanced technical ceramics) – Determination of specific surface area of ceramic powders by gas adsorption using the BET method |
ISO 23145–1:2007 | Fine ceramics (advanced ceramics, advanced technical ceramics) – Determination of bulk density of ceramic powders – Part 1: Tap density |
ISO 24235:2007 | Fine ceramics (advanced ceramics, advanced technical ceramics) – Determination of particle size distribution of ceramic powders by laser diffraction method |
Annex 1.2. ISO Technical Committee 229 (TC229) Nanotechnologies (selection)
References | Title |
---|---|
ISO 9276–1:1998 | Representation of results of particle size analysis – Part 1: Graphical representation |
ISO 9276–2:2001 | Representation of results of particle size analysis – Part 2: Calculation of average particle sizes/diameters and moments from particle size distributions |
ISO 9276–3:2008 | Representation of results of particle size analysis – Part 3: Adjustment of an experimental curve to a reference model |
ISO 9276–6:2008 | Representation of results of particle size analysis – Part 6: Descriptive and quantitative representation of particle shape and morphology |
ISO 9277:1995 | Determination of the specific surface area of solids by gas adsorption using the BET method |
ISO 13317–1:2001 | Determination of particle size distribution by gravitational liquid sedimentation methods – Part 1: General principles and guidelines |
ISO 13317–2:2001 | Determination of particle size distribution by gravitational liquid sedimentation methods – Part 2: Fixed pipette method |
ISO 13317–3:2001 | Determination of particle size distribution by gravitational liquid sedimentation methods – Part 3: X-ray gravitational technique |
ISO 13318–1:2001 | Determination of particle size distribution by centrifugal liquid sedimentation methods – Part 1: General principles and guidelines |
ISO 13318–2:2007 | Determination of particle size distribution by centrifugal liquid sedimentation methods – Part 2: Photocentrifuge method |
ISO 13318–3:2004 | Determination of particle size distribution by centrifugal liquid sedimentation methods – Part 3: Centrifugal X-ray method |
ISO 13319:2007 | Determination of particle size distributions – Electrical sensing zone method |
ISO 13320:2009 | Particle size analysis – Laser diffraction methods |
ISO 13321:1996 | Particle size analysis – Photon correlation spectroscopy |
ISO 13322–1:2004 | Particle size analysis – Image analysis methods – Part 1: Static image analysis methods |
ISO 13322–2:2006 | Particle size analysis – Image analysis methods – Part 2: Dynamic image analysis methods |
ISO/TS 13762:2001 | Particle size analysis – Small-angle X-ray scattering method |
ISO 14488:2007 | Particulate materials – Sampling and sample splitting for the determination of particulate properties |
ISO 14887:2000 | Sample preparation – Dispersing procedures for powders in liquids |
ISO 15900:2009 | Determination of particle size distribution – Differential electrical mobility analysis for aerosol particles |
ISO 15901–1:2005 | Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption – Part 1: Mercury porosimetry |
ISO 15901–2:2006 | Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption – Part 2: Analysis of mesopores and macropores by gas adsorption |
ISO 15901–3:2007 | Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption – Part 3: Analysis of micropores by gas adsorption |
ISO 20998–1:2006 | Measurement and characterization of particles by acoustic methods – Part 1: Concepts and procedures in ultrasonic attenuation spectroscopy |
ISO 21501–1:2009 | Determination of particle size distribution – Single particle light interaction methods – Part 1: Light scattering aerosol spectrometer |
ISO 21501–2:2007 | Determination of particle size distribution – Single particle light interaction methods – Part 2: Light scattering liquid-borne particle counter |
ISO 21501–3:2007 | Determination of particle size distribution – Single particle light interaction methods – Part 3: Light extinction liquid-borne particle counter |
ISO 21501–4:2007 | Determination of particle size distribution – Single particle light interaction methods – Part 4: Light scattering airborne particle counter for clean spaces |
ISO 22412:2008 | Particle size analysis – Dynamic light scattering (DLS) |
Annex 2. Standards for Apparent Density Determination
Type | Number | Title |
---|---|---|
ISO | ISO 3923–1:2008 | Metallic powders. Determination of apparent density. Part 1: Funnel method |
ISO 3923–2:1981 | Metallic powders. Determination of apparent density. Part 2: Scott volumeter method | |
ISO 18459–1:2009 | Metallic powders. Determination of apparent density and flow rate at elevated temperature. Part 1: determination of apparent density at elevated temperature | |
MPIF | MPIF Standard 04 2007 Edition | Method for determination of apparent density of free-flowing metal powders using the Hall apparatus |
MPIF Standard 28 2007 Edition | Method for determination of apparent density of non-free-flowing metal powders using the Carney apparatus | |
MPIF Standard 48 2007 Edition | Method for determination of apparent density of metal powders using the Arnold meter | |
ASTM | ASTM B703-10 | Standard test method for apparent density of metal powders and related compounds using the Arnold meter |
ASTM B212-09 | Standard test method for apparent density of free-flowing metal powders using the Hall flowmeter funnel | |
ASTM B329-06 | Standard test method for apparent density of metal powders and compounds using the Scott volumeter | |
ASTM B417-11 | Standard test method for apparent density of non free-flowing metal powders using the Carney funnel |
Annex 3. Standards for Tap Density Determination
Type | Number | Title |
---|---|---|
ISO | ISO 3953:2011 | Metallic powders. Determination of tap density |
MPIF | MPFI Standard 46 2007 Edition | Method for determination of tap density of metal powders |
ASTM | ASTM B527-06 | Standard test method for determination of tap density of metallic powders and compounds |
Annex 4. Standards for Flow Rate Determination
Type | Number | Title |
---|---|---|
ISO | ISO 4490:2008 | Determination of flow rate by means of a calibrated funnel (hall flow meter) |
ISO 18549–2:2009 | Metallic powders. Determination of apparent density and flow rate at elevated temperatures. Part 2: Determination of flow rate at elevated temperature | |
MPIF | MPIF Standard 03 2007 Edition | Method for determination of flow rate of free-flowing metal powders using the Hall apparatus |
ASTM | ASTM B964-09 | Standard test methods for flow rate of metal powders using the Carney funnel |
Annex 5. Standards for Powder Compressibility Determination
Type | Number | Title |
---|---|---|
ISO | ISO 3927:2011 | Metallic powders, excluding powders for hard metals. Determination of compressibility in uniaxial compression |
MPIF | MPIF Standards 452007 Edition | Method for determination of compressibility of metal powders |
ASTM | ASTM B331-10 | Standard test method for compressibility of metal powders in uniaxial compaction |
Annex 6. Standards for Powder Compressibility Determination
Type | Number | Title |
---|---|---|
ISO | ISO 3995:1985 | Determination of green strength by transverse rupture of rectangular compacts |
MPIF | MPIF Standards 152007 Edition | Method for determination of green strength of unsintered compacted powder metallurgy materials |
ASTM | ASTM B312-09 | Standard test method for green strength of specimen compacted from metal powder |
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Ruys, A., Gingu, O., Sima, G., Maleksaeedi, S. (2015). Powder Processing of Bulk Components in Manufacturing. In: Nee, A. (eds) Handbook of Manufacturing Engineering and Technology. Springer, London. https://doi.org/10.1007/978-1-4471-4670-4_48
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