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Electrokinetics in the Removal of Chlorinated Organics from Soils

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Chlorinated Organic Compounds

The term chlorinated organic compounds (COCs) refers to the substitution of one or more hydrogen atoms in an organic molecule by one or more chlorine atoms. Chlorinated organic compounds include aliphatic, cyclic, and aromatic structures. Typical chlorinated organics are the following: trichloroethylene (TCE), vinyl chloride (VC), and carbon tetrachloride (CT) in the aliphatic group; lindane (hexachlorocyclohexane) and DDT with a cyclic structure; and pentachlorophenol (PCP) and polychlorinated biphenyls (PCBs) in the aromatic group. Chlorinated organics have been used extensively in many industrial processes including the chemical industry, medicine, electronics, and pesticides. The main uses include solvents, pesticides, preservative agents, and intermediates in the synthesis of pharmaceuticals and dyes. This kind of compounds can be found in many industrial fields and in many products in the market. Such a wide family of chemical compounds shows...

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References

  1. Athmer C (2004) In-situ remediation of TCE in clayey soils. Soil and Sediment Contam 13(5):479–488

    CAS  Google Scholar 

  2. Cameselle C, Reddy KR (2012) Development and enhancement of electro-osmotic flow for the removal of contaminants from soils. Electrochimica Acta 86:10–22

    Google Scholar 

  3. Chang J-H, Qiang Z, Huang C-P (2006) Remediation and stimulation of selected chlorinated organic solvents in unsaturated soil by a specific enhanced electrokinetics. Colloids Surf A Physicochem Engin Aspects 287(1–3):86–93

    CAS  Google Scholar 

  4. Chen J-L, Al-Abed SR, Ryan JA, Li Z (2002) Groundwater and soil remediation using electrical fields. ACS Symp Ser 806:434–448

    CAS  Google Scholar 

  5. Bruell CJ, Segall BA, Walsh MT (1992) Electroosmotic removal of gasoline hydrocarbons and TCE from clay. J Environ Eng 118:68–83

    CAS  Google Scholar 

  6. Fraser A (2009) Remediation of contaminated site using electric resistive heating. First use in the UK. EREM 2009. Lisbon (Portugal) 47–48

    Google Scholar 

  7. Godschalk MS, Lageman R (2005) Electrokinetic biofence, remediation of VOCs with solar energy and bacteria engineering. Geology 77(3–4 SPEC. ISS):225–231

    Google Scholar 

  8. Gomes HI, Dias-Ferreira C, Ribeiro AB (2012) Electrokinetic remediation of organochlorines in soil: enhancement techniques and integration with other remediation technologies. Chemosphere 87(10):1077–1090

    CAS  Google Scholar 

  9. Huang Y-C, Cheng Y-W (2012) Electrokinetic-enhanced nanoscale iron reactive barrier of trichloroethylene solubilized by Triton X-100 from groundwater. Electrochimica Acta 86:177–184

    CAS  Google Scholar 

  10. Reddy KR, Darko-Kagya K, Cameselle C (2011) Electrokinetic-enhanced transport of lactate-modified nanoscale iron particles for degradation of dinitrotoluene in clayey soils. Sep Purif Technol 79(2):230–237

    CAS  Google Scholar 

  11. Lageman R, Godschalk MS (2007) Electro-bioreclamation. A combination of in situ remediation techniques proves successful at a site in Zeist, the Netherlands. Electrochim Acta 52(10 SPEC. ISS):3449–3453

    CAS  Google Scholar 

  12. Oonnittan A, Shrestha RA, Sillanpää M (2008) Remediation of hexachlorobenzene in soil by enhanced electrokinetic fenton process. J Environ Sci Health A Tox Hazard Subst Environ Eng 43(8):894–900

    CAS  Google Scholar 

  13. Oonnittan A, Shrestha RA, Sillanpää M (2009) Removal of hexachlorobenzene from soil by electrokinetically enhanced chemical oxidation. J Hazard Mater 162(2–3):989–993

    CAS  Google Scholar 

  14. Pham TD, Shrestha RA, Sillanpää M (2010) Removal of hexachlorobenzene and phenanthrene from clayey soil by surfactant- and ultrasound-assisted electrokinetics. J Environ Eng 136(7):739–742

    CAS  Google Scholar 

  15. Reddy KR, Ala PR, Sharma S, Kumar SN (2006) Enhanced electrokinetic remediation of contaminated manufactured gas plant soil Engineering. Geology 85(1–2):132–146

    Google Scholar 

  16. Reddy KR, Darko-Kagya K, Al-Hamdan AZ (2011) Electrokinetic remediation of pentachlorophenol contaminated clay soil. Water Air Soil Pollut 221(1–4):35–44

    CAS  Google Scholar 

  17. Saichek RE, Reddy KR (2005) Electrokinetically enhanced remediation of hydrophobic organic compounds in soils: a review. Crit Rev Env Sci Tec 35(2):115–192

    CAS  Google Scholar 

  18. Sale T C, Gilbert D M, Petersen M A (2005) “Cost and performance report: electrically induced redox barriers for treatment of groundwater.” ESTCP Project CU0112

    Google Scholar 

  19. Semkiw ES, Barcelona MJ (2011) Field study of enhanced TCE reductive dechlorination by a full-scale whey PRB. Ground Water Monit Remed 31(1):68–78

    CAS  Google Scholar 

  20. Wan J, Li Z, Lu X, Yuan S (2010) Remediation of a hexachlorobenzene-contaminated soil by surfactant-enhanced electrokinetics coupled with microscale Pd/Fe PRB. J Hazard Mater 184(1–3):184–190

    CAS  Google Scholar 

  21. Wan J, Yuan S, Chen J, Li T, Lin L, Lu X (2009) Solubility-enhanced electrokinetic movement of hexachlorobenzene in sediments: a comparison of cosolvent and cyclodextrin. J Hazard Mater 166(1):221–226

    CAS  Google Scholar 

  22. Warner SD, Bablitch D, Frappa RH (2012) PRB treatment for contaminated groundwater. Mil Eng 104(675):53–54

    Google Scholar 

  23. Weng C-H, Yuan C, Tu H-H (2003) Removal of trichloroethylene from clay soil by series-electrokinetic process. Pract Periodical Hazard Tox Radioactive Waste Manag 7(1):25–30

    Google Scholar 

  24. Yang GCC, Liu C-Y (2001) Remediation of TCE contaminated soils by in situ EK-fenton process. J Hazard Mater 85(3):317–331

    CAS  Google Scholar 

  25. Yang GCC, Yeh C-F (2011) Enhanced nano-Fe 3O 4/S 2O 8 2- oxidation of trichloroethylene in a clayey soil by electrokinetics. Sep Purif Technol 79(2):264–271

    CAS  Google Scholar 

  26. Yuan S, Tian M, Lu X (2006) Electrokinetic movement of hexachlorobenzene in clayed soils enhanced by Tween 80 and β-cyclodextrin. J Hazard Mater 137(2):1218–1225

    CAS  Google Scholar 

  27. Zheng Z, Yuan S, Liu Y, Lu X, Wan J, Wu X, Chen J (2009) Reductive dechlorination of hexachlorobenzene by Cu/Fe bimetal in the presence of nonionic surfactant. J Hazard Mater 170(2–3):895–901

    CAS  Google Scholar 

  28. Reddy KR, Cameselle C (2009) Electrochemical remediation technologies for polluted soils, sediments and groundwater. Wiley, New York

    Google Scholar 

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Correspondence to Claudio Cameselle .

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Cameselle, C. (2014). Electrokinetics in the Removal of Chlorinated Organics from Soils. In: Kreysa, G., Ota, Ki., Savinell, R.F. (eds) Encyclopedia of Applied Electrochemistry. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-6996-5_86

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