Encyclopedia of Applied Electrochemistry

2014 Edition
| Editors: Gerhard Kreysa, Ken-ichiro Ota, Robert F. Savinell

Lithium-Sulfur Batteries

  • Hikari SakaebeEmail author
Reference work entry
DOI: https://doi.org/10.1007/978-1-4419-6996-5_439


Li-S battery system is advantageous due to theoretically higher energy density (2,600 Wh kg−1 assuming the redox reaction of 2Li + S⇄ Li2S), and thus research and development for sulfur electrode had started in 1960–1970s [1, 2, 3].

The difficulty in Li-S battery operated at ambient temperature lies in two points: conductivity and the solubility of partly lithiated polysulfides, LixS8. S powder is usually a yellow powder and it has poor conductivity. So the conduction pathway should be ensured. At present, preparation of composite of S and carbons has been attracting many researcher for improvement. Present status will be outlined later in the next section.

It was reported that polysulfide, Li xS 8,formed during the way of the discharge and charge of the battery and undergoes electrochemical reaction in the liquid phase in the organic solvent [ 4, 5]. This causes a worse efficiency and a poor cycleability. As shown in Fig. 1, polysulfides are thought to undergo the cycling...
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  1. 1.
    Jasinski R, Burrows B (1969) Cathodic discharge of nickel sulfide in a propylene carbonate-LiClO electrolyte. J Electrochem Soc 116:422–424CrossRefGoogle Scholar
  2. 2.
    Margaret VM, Sawyer DT (1970) Electrochemical reduction of elemental sulfur in aprotic solvents. Formation of a stable Ss- species. Inorg Chem 9:211–215CrossRefGoogle Scholar
  3. 3.
    Robert PM, Sawyer DT (1972) Electrochemical reduction of sulfur dioxide in dimethylformamide. Inorg Chem 11:2644–2647CrossRefGoogle Scholar
  4. 4.
    Dominko R, Demir-Cakan R, Morcrette M, Tarascon JM (2011) Analytical detection of soluble polysulphides in a modified Swagelok cell. Electrochem Commun 13:117–120CrossRefGoogle Scholar
  5. 5.
    Bruce PG, Freunberger SA et al (2012) Li-O-2 and Li-S batteries with high energy storage. Nat Mater 11:19CrossRefGoogle Scholar
  6. 6.
    Takeuchi T, Sakaebe H, Kageyama H, Sakai T, Tatsumi K (2008) Preparation of NiS2 using spark-plasma-sintering process and its electrochemical properties. J Electrochem Soc 155:A679–A684CrossRefGoogle Scholar
  7. 7.
    Hayashi A, Ohtsubo R, Nagao M, Tatsumisago M (2010) Characterization of Li2S-P2S5-Cu composite electrode for all-solid-state lithium secondary batteries. J Mater Sci 45:377–381CrossRefGoogle Scholar
  8. 8.
    Sakuda A, Taguchi N, Takeuchi T, Kobayashi H, Sakaebe H, Tatsumi K, Ogumi Z (2013) Amorphous TiS4 positive electrode for lithium-sulfur secondary batteries. Electrochem Commun 31:71–75CrossRefGoogle Scholar
  9. 9.
    Wang J, Yang J, Xie J, Xu N (2002) A novel conductive polymer–sulfur composite cathode material for rechargeable lithium batteries. Adv Mater 14:963–965CrossRefGoogle Scholar
  10. 10.
    Wang JL, Yang J, Xie JY, Xu NX, Li Y (2002) Sulfur–carbon nano-composite as cathode for rechargeable lithium battery based on gel electrolyte. Electrochem Commun 4:499–502CrossRefGoogle Scholar
  11. 11.
    Wang J, Chew SY, Zhao ZW, Ashraf S, Wexler D, Chen J, Ng SH, Chou SL, Liu HK (2008) Sulfur–mesoporous carbon composites in conjunction with a novel ionic liquid electrolyte for lithium rechargeable batteries. Carbon 46:229–235CrossRefGoogle Scholar
  12. 12.
    Xiulei Ji, Kyu Tae Lee, Nazar LF (2009) A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries. Nat Mater 8:500–506CrossRefGoogle Scholar
  13. 13.
    Feng Wu, Junzheng Chen, Renjie Chen, Shengxian Wu, Li Li, Shi Chen, Teng Zhao (2011) Sulfur/polythiophene with a core/shell structure: synthesis and electrochemical properties of the cathode for rechargeable lithium batteries. J Phys Chem C 115:6057–6063CrossRefGoogle Scholar
  14. 14.
    Liwen Ji, Rao M, Haimei Zheng, Liang Zhang, Yuanchang Li, Wenhui Duan, Jinghua Guo, Cairns EJ, Yuegang Zhang (2011) Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells. J Am Chem Soc 133:18522–18525CrossRefGoogle Scholar
  15. 15.
    Liang X, Wen Z, Liu Y, Zhang H, Jin J, Wu M, Wu X (2012) A composite of sulfur and polypyrrole–multi walled carbon combinatorial nanotube as cathode for Li/S battery. J Power Sources 206:409–413CrossRefGoogle Scholar
  16. 16.
    Takeuchi T, Sakaebe H, Kageyama H, Senoh H, Sakai T, Tatsumi K (2010) Preparation of electrochemically active lithium sulfide–carbon composites using spark-plasma-sintering process. J Power Sources 195:2928–2934CrossRefGoogle Scholar
  17. 17.
    Kim S, Jung Y, Park S-J (2007) Effect of imidazolium cation on cycle life characteristics of secondary lithium–sulfur cells using liquid electrolytes. Electrochim Acta 52:2116–2122CrossRefGoogle Scholar
  18. 18.
    Tachikawa N, Yamauchi K, Takashima E, Park J-W, Dokko K, Watanabe M (2011) Reversibility of electrochemical reactions of sulfur supported on inverse opal carbon in glyme–Li salt molten complex electrolyte. Chem Commun 47:8157–8159CrossRefGoogle Scholar
  19. 19.
    Liang X, Wen Z, Liu Y, Wu M, Jin J, Zhang H, Wu X (2011) Improved cycling performances of lithium sulfur batteries with LiNO3 – modified electrolyte. J Power Sources 196:9839–9843CrossRefGoogle Scholar
  20. 20.
    Mikhaylik YV, Kovalev I, Schock R, Kumaresan K, Jason Xu, Affinito J (2010) High energy rechargeable Li-S cells for EV application: status, remaining problems and solutions. ECS Trans 25:23–34CrossRefGoogle Scholar

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© Springer Science+Business Media New York 2014

Authors and Affiliations

  1. 1.Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST)IkedaJapan