Encyclopedia of Ionic Liquids

Living Edition
| Editors: Suojiang Zhang

Functional Ionic Liquid in Multicomponent Reaction, a Powerful Tool for C–C Bond Formation

  • Qing-Wen SongEmail author
Living reference work entry
DOI: https://doi.org/10.1007/978-981-10-6739-6_42-1

Synonyms

Introduction

Definition

Functional Ionic Liquids (FILs)

Ionic liquids (ILs) are kind of unconventional ionic salts also including cation and anion (Fig. 1a), which present as liquid form generally under 100  oC or lower temperature such as room temperature (room temperature ionic liquid, RTIL) [ 1]. Functional ionic liquids (FILs) (Fig. 1b), also being called task-specific ionic liquids (TSILs), possess specific structure with some functional sites introduced on the anion or cation and show special features and functions.
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References

  1. 1.
    Yue C, Fang D, Liu L, Yi T-F (2011) Synthesis and application of task-specific ionic liquids used as catalysts and/or solvents in organic unit reactions. J Mol Liq 163:99–121CrossRefGoogle Scholar
  2. 2.
    Bao S, Chen L, Ji Y, Yang J (2010) Efficient procedure for oxathioacetalization using the novel ionic liquid. Chin J Chem 28:2119–2122CrossRefGoogle Scholar
  3. 3.
    Martins MAP, Frizzo CP, Tier AZ, Moreira DN, Zanatta N, Bonacorso HG (2014) Update 1 of: ionic liquids in heterocyclic synthesis. Chem Rev 114:PR1–PR70CrossRefGoogle Scholar
  4. 4.
    Sridhar R, Perumal PT (2005) A new protocol to synthesize 1,4-dihydropyridines by using 3,4,5-trifluorobenzeneboronic acid as a catalyst in ionic liquid: synthesis of novel 4-(3-carboxyl-1H-pyrazol-4-yl)-1,4-dihydropyridines. Tetrahedron 61:2465–2470CrossRefGoogle Scholar
  5. 5.
    Yadav JS, Reddy BVS, Eshwaraiah B, Srinivas M, Vishnumurthy P (2003) Three-component coupling reactions in ionic liquids: a facile synthesis of α-aminonitriles. New J Chem 27:462–465CrossRefGoogle Scholar
  6. 6.
    Yadav JS, Reddy BVS, Basak AK, Narsaiah AV (2003) Three-component coupling reactions in ionic liquids: an improved protocol for the synthesis of 1,4-dihydropyridines. Green Chem 5:60–63CrossRefGoogle Scholar
  7. 7.
    Karthikeyan G, Perumal PT (2005) Ionic liquid promoted simple and efficient synthesis of β-enamino esters and β-enaminones from 1,3-dicarbonyl compounds. One-pot, three-component reaction for the synthesis of substituted pyridines. Can J Chem 83:1746–1751CrossRefGoogle Scholar
  8. 8.
    Peng J, Deng Y (2001) Ionic liquids catalyzed Biginelli reaction under solvent-free conditions. Tetrahedron Lett 42:5917–5919CrossRefGoogle Scholar
  9. 9.
    Yadav JS, Reddy BVS, Shubashree S, Sadashiv K, Naidu JJ (2004) Ionic liquids-promoted multicomponent reaction: green approach for highly substituted 2-aminofuran derivatives. Synthesis:2376–2380Google Scholar
  10. 10.
    Davoodnia A, Bakavoli M, Moloudi R, Tavakoli-Hoseini N, Khashi M (2010) Highly efficient, one-pot, solvent-free synthesis of 2,4,6-triarylpyridines using a Brønsted-acidic ionic liquid as reusable catalyst. Monatsh Chem 141:867–870CrossRefGoogle Scholar
  11. 11.
    Sapkal SB, Shelke KF, Shingate BB, Shingare MS (2010) An efficient one-pot strategies for the synthesis of [1,3] oxazine derivatives. J Korean Chem Soc 54:437–442CrossRefGoogle Scholar
  12. 12.
    Salahi S, Maghsoodlou MT, Hazeri N, Lashkari M, Torbati NA, Kazemian MA, Garcıa-Granda S, Torre-Fernandez L (2016) Brønsted acidic ionic liquid catalyzed synthesis of poly-substituted hydroquinolines through diastereoselective, one-pot and pseudo-eight-component reaction. J Saudi Chem Soc 20:349–356CrossRefGoogle Scholar
  13. 13.
    Gong K, Wang H-L, Fang D, Liu Z-L (2008) Basic ionic liquid as catalyst for the rapid and green synthesis of substituted 2-amino-2-chromenes in aqueous media. Catal Commun 9:650–653CrossRefGoogle Scholar
  14. 14.
    Ranu BC, Banerjee S (2005) Ionic liquid as catalyst and reaction medium. The dramatic influence of a task-specific ionic liquid, [bmIm]OH, in Michael addition of active methylene compounds to conjugated ketones, carboxylic esters, and nitriles. Org Lett 7:3049–3052CrossRefGoogle Scholar
  15. 15.
    Chen X, Peng Y (2008) Chloroferrate(III) ionic liquid: efficient and recyclable catalyst for solvent-free synthesis of 3,4-dihydropyrimidin-2(1H)-ones. Catal Lett 122:310–313CrossRefGoogle Scholar
  16. 16.
    Damavandi S (2012) Immobilized ionic liquid-catalyzed synthesis of pyrano[3,2-b]indole derivatives. E-J Chem 9:1490–1493CrossRefGoogle Scholar
  17. 17.
    Wang ZT, Wang SC, Xu LW (2005) Polymer-supported ionic-liquid-catalyzed synthesis of 1,2,3,4-tetrahydro-2-oxopyrimidine-5-carboxylates via Biginelli reaction. Helv Chim Acta 88:986–989CrossRefGoogle Scholar
  18. 18.
    Shaterian HR, Mohammadnia M (2012) Mild basic ionic liquids catalyzed new four-component synthesis of 1H-pyrazolo[1,2-b]phthalazine-5,10-diones. J Mol Liq 173:55–61CrossRefGoogle Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2019

Authors and Affiliations

  1. 1.State Key Laboratory of Coal Conversion, Institute of Coal ChemistryChinese Academy of SciencesTaiyuanChina

Section editors and affiliations

  • Liang-Nian He
    • 1
  • Bhalchandra Bhanage
    • 2
  1. 1.State Key Laboratory and Institute of Elemento-Organic Chemistry, College of ChemistryNankai UniversityTianjinPeople’s Republic of China
  2. 2.Department of ChemistryInstitute of Chemical TechnologyMumbaiIndia