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Plastic Composites

  • Katri SuuronenEmail author
  • Maria Pesonen
Reference work entry

Abstract

A composite is a blend of two or more materials that are mixed in order to gain properties superior to those of the original components. Plastic composites (PCs), also called reinforced plastics, are combinations of a polymer (plastic) matrix and a reinforcing material. Due to their enhanced properties and versatility, PCs are used in nearly all fields of industry. PC may cause both allergic and irritant contact dermatitis. Allergic contact dermatitis is most often caused by thermoset plastic matrices such as epoxy resins. Irritant contact dermatitis is typically caused by reinforcement materials such as glass fiber. Other skin contactants in PC work are, for example, plastic additives, solvents, peroxides, and protective clothing. Clinical investigation of PC-related dermatitis requires careful assessment of the workplace exposures (chemicals and materials) and patch testing the patient accordingly with plastic chemicals additives and, when possible, own materials from work.

Keywords

Plastic composite Composite Reinforced plastics Prepreg Epoxy resin Hardener Polyester resin Vinyl ester Phenol-formaldehyde resin Polyurethane Acrylate Cobalt Glass fiber Carbon fiber Lamination Boat building Wind turbine Contact dermatitis Contact allergy Irritant 

References

  1. Aalto-Korte K, Suuronen K (2016) Occupational contact allergy to components of polyester resin systems. Contact Dermatitis 75(1):14–19PubMedGoogle Scholar
  2. Aalto-Korte K, Suuronen K (2017) Screening allergic reactions to resol resin based on phenol and formaldehyde in a clinic of occupational dermatology. Contact Dermatitis 77(4):208–213Google Scholar
  3. Aalto-Korte K, Jolanki R, Estlander T (2003) Formaldehyde-negative allergic contact dermatitis from melamine-formaldehyde resin. Contact Dermatitis 49(4):194–196Google Scholar
  4. Aalto-Korte K, Jungewelter S, Henriks-Eckerman ML, Kuuliala O, Jolanki R (2009) Contact allergy to epoxy (meth)acrylates. Contact Dermatitis 61(1):9–21PubMedCrossRefGoogle Scholar
  5. Aalto-Korte K, Suuronen K, Kuuliala O, Henriks-Eckerman ML, Jolanki R (2012) Occupational contact allergy to monomeric isocyanates. Contact Dermatitis 67(2):78–88PubMedCrossRefGoogle Scholar
  6. Aalto-Korte K, Suuronen K, Kuuliala O, Henriks-Eckerman ML, Jolanki R (2014a) Contact allergy to epoxy hardeners. Contact Dermatitis 71(3):145–153PubMedCrossRefGoogle Scholar
  7. Aalto-Korte K, Suuronen K, Kuuliala O, Henriks-Eckerman ML, Jolanki R (2014b) Screening occupational contact allergy to bisphenol F epoxy resin. Contact Dermatitis 71(3):138–144PubMedCrossRefGoogle Scholar
  8. Aalto-Korte K, Pesonen M, Suuronen K (2015a) Occupational allergic contact dermatitis caused by epoxy chemicals: occupations, sensitizing products, and diagnosis. Contact Dermatitis 73(6):336–342PubMedCrossRefGoogle Scholar
  9. Aalto-Korte K, Kuuliala O, Henriks-Eckerman ML, Suuronen K (2015b) Contact allergy to reactive diluents and related aliphatic epoxy resins. Contact Dermatitis 72(6):387–397PubMedCrossRefGoogle Scholar
  10. Aalto-Korte K, Bäck B, Henriks-Eckerman M, Jungewelter S, Mäkelä E, Pesonen M, Suuronen K, Ylinen K (2017) EPOXY FOLDER – chemical safety in construction coating work, 2017. Available online: www.ttl.fi/epoxyfolder. Accessed 25 Apr 2017
  11. Adam N, Avar G, Blankenheim H, Friedrichs W, Giersig M, Weigang E, Halfman M, Wittbecker F, Larimer D, Maier U, Meyer-Ahrens S, Noble K, Wussow H (2012) Polyurethanes, Ullman’s encyclopedia of industrial chemistry[eBook]. Wiley-VCH, WeinheimGoogle Scholar
  12. Anveden Berglind I, Lind ML, Liden C (2012) Epoxy pipe relining – an emerging contact allergy risk for workers. Contact Dermatitis 67(2):59–65PubMedCrossRefGoogle Scholar
  13. BASF (2016) Fiber-reinforced composites made of polyurethane systems, 2016. Available online: http://www.polyurethanes.basf.de/pu/solutions/de_DE/function/conversions:/publish/content/group/News_und_Medien/Polyurethan/Composites_Lightweight_EN.pdf. Accessed 25 Apr 2017
  14. Behera D (2011) Hydroxyethyl acrylate treated jute–esoa composite laminate: a new development for structural materials. Int J Plast Technol 15(Suppl 1):86–92CrossRefGoogle Scholar
  15. Bell HK, King CM (2002) Allergic contact dermatitis from urea-formaldehyde resin in medium-density fibreboard (MDF). Contact Dermatitis 46(4):247PubMedCrossRefGoogle Scholar
  16. Bourne LB, Milner FJ (1963) Polyester resin hazards. Br J Ind Med 20:100–109PubMedPubMedCentralGoogle Scholar
  17. Bruze M, Almgren G (1988) Occupational dermatoses in workers exposed to resins based on phenol and formaldehyde. Contact Dermatitis 19(4):272–277PubMedPubMedCentralCrossRefGoogle Scholar
  18. Bruze M, Edenholm M, Engstrom K, Svensson G (1996) Occupational dermatoses in a Swedish aircraft plant. Contact Dermatitis 34(5):336–340PubMedCrossRefGoogle Scholar
  19. Compton B, Lewis J (2014) 3D-printing of lightweight cellular composites. Adv Mater 26:5930–5935PubMedCrossRefGoogle Scholar
  20. Diem H, Matthias G, Wagner R (2012) Amino resins, Ullman’s encyclopedia of industrial chemistry[eBook]. Wiley-VCH, WeinheimGoogle Scholar
  21. Ehrenstein G, Kabelka J (2012) Reinforced plastics, Ullman’s encyclopedia of industrial chemistry[eBook]. Wiley-VCH, WeinheimGoogle Scholar
  22. Elias H, Mulhaupt R (2015) Plastic, general survey, Chapter 4. In: Plastic composites, Ullman’s encyclopedia of industrial chemistry, 7th edn [eBook]. Wiley-VCH, Weinheim, pp 1–17Google Scholar
  23. Fillenham G, Liden C, Anveden Berglind I (2012) Skin exposure to epoxy in the pipe relining trade – an observational study. Contact Dermatitis 67(2):66–72PubMedCrossRefGoogle Scholar
  24. Finch TM, Prais L, Foulds IS (1999) Allergic contact dermatitis from medium-density fibreboard containing melamine-formaldehyde resin. Contact Dermatitis 41(5):291PubMedCrossRefGoogle Scholar
  25. Frick M, Isaksson M, Bjorkner B, Hindsen M, Ponten A, Bruze M (2003) Occupational allergic contact dermatitis in a company manufacturing boards coated with isocyanate lacquer. Contact Dermatitis 48(5):255–260PubMedCrossRefGoogle Scholar
  26. Goon AT, Isaksson M, Zimerson E, Goh CL, Bruze M (2006) Contact allergy to (meth)acrylates in the dental series in southern Sweden: simultaneous positive patch test reaction patterns and possible screening allergens. Contact Dermatitis 55(4):219–226PubMedCrossRefGoogle Scholar
  27. Helaskoski E, Kuuliala O, Aalto-Korte K (2009) Occupational contact urticaria caused by cyclic acid anhydrides. Contact Dermatitis 60(4):214–221CrossRefGoogle Scholar
  28. Isaksson M, Zimerson E, Bruze M (1999) Occupational dermatoses in composite production. J Occup Environ Med 41(4):261–266CrossRefGoogle Scholar
  29. Jolanki R, Tarvainen K, Tatar T, Estlander T, Henriks-Eckerman ML, Mustakallio KK, Kanerva L (1996) Occupational dermatoses from exposure to epoxy resin compounds in a ski factory. Contact Dermatitis 34(6):390–396PubMedCrossRefGoogle Scholar
  30. Jolanki R, Makinen I, Suuronen K, Alanko K, Estlander T (2002) Occupational irritant contact dermatitis from synthetic mineral fibres according to Finnish statistics. Contact Dermatitis 47(6):329–333PubMedCrossRefGoogle Scholar
  31. Kanerva L, Estlander T, Jolanki R, Tarvainen K (1993) Occupational allergic contact dermatitis caused by exposure to acrylates during work with dental prostheses. Contact Dermatitis 28(5):268–275PubMedCrossRefGoogle Scholar
  32. Kanerva L, Estlander T, Jolanki R (1997) Occupational allergic contact dermatitis caused by acrylic tri-cure glass ionomer. Contact Dermatitis 37(1):49–50PubMedCrossRefGoogle Scholar
  33. Kanerva L, Jolanki R, Estlander T, Henriks-Eckerman M, Tuomi M, Tarvainen K (2000) Airborne occupational allergic contact dermatitis from triglycidyl-p-aminophenol and tetraglycidyl-4,4′-methylene dianiline in preimpregnated epoxy products in the aircraft industry. Dermatology 201(1):29–33PubMedCrossRefGoogle Scholar
  34. Kasal B, Friebel S, Gunschera J, Salthammer T, Schirp A, Schwab H, Volken T (2015) Wood-based materials, Ullman’s encyclopedia of industrial chemistry[eBook]. Wiley-VCH, WeinheimGoogle Scholar
  35. Minamoto K, Nagano M, Inaoka T, Futatsuka M (2002) Occupational dermatoses among fibreglass-reinforced plastics factory workers. Contact Dermatitis 46(6):339–347PubMedCrossRefGoogle Scholar
  36. Owen CM, Beck MH (2001) Occupational allergic contact dermatitis from phenol-formaldehyde resins. Contact Dermatitis 45(5):294–295PubMedPubMedCentralCrossRefGoogle Scholar
  37. Pesonen M, Suuronen K, Jolanki R, Aalto-Korte K, Kuuliala O, Henriks-Eckerman ML, Valtanen I, Alanko K (2015) Occupational contact dermatitis caused by aniline epoxy resins in the aircraft industry. Contact Dermatitis 73(2):113–118PubMedCrossRefGoogle Scholar
  38. Pfaffli P, Jolanki R, Estlander T, Tarvainen K, Kanerva L (2002) Identification of sensitizing diethyleneglycol maleate in a two-component polyester cement. Contact Dermatitis 46(3):170–173PubMedCrossRefGoogle Scholar
  39. Ponten A, Carstensen O, Rasmussen K, Gruvberger B, Isaksson M, Bruze M (2004) Epoxy-based production of wind turbine rotor blades: occupational dermatoses. Contact Dermatitis 50(6):329–338PubMedCrossRefGoogle Scholar
  40. Rasmussen K, Carstensen O, Ponten A, Gruvberger B, Isaksson M, Bruze M (2005) Risk of contact allergy and dermatitis at a wind turbine plant using epoxy resin-based plastics. Int Arch Occup Environ Health 78(3):211–217PubMedCrossRefGoogle Scholar
  41. Saba N, Jawaid M, Alothman O, Paridah M, Hassan A (2016) Recent advances in epoxy resin, natural fiber-reinforced epoxy composites and their applications. Reinf Plast Compos 35(6):447–470CrossRefGoogle Scholar
  42. Syed M, Chopra R, Sachdev V (2015) Allergic reactions to dental materials-a systematic review. J Clin Diagn Res 9(10):ZE04–ZE09PubMedPubMedCentralGoogle Scholar
  43. Tarvainen K, Jolanki R, Forsman-Gronholm L, Estlander T, Pfaffli P, Juntunen J, Kanerva L (1993) Exposure, skin protection and occupational skin diseases in the glass-fibre-reinforced plastics industry. Contact Dermatitis 29(3):119–127PubMedCrossRefGoogle Scholar
  44. Thomas S, Abraham J, Parambil A, Krishnan A, Maria H, Ilschner B, Lees J, Dhingra A, McCullough R (2016) Composite materials, Ullman’s encyclopedia of industrial chemistry[eBook]. Wiley-VCH, Weinheim, pp 2–39Google Scholar
  45. Vaishya R, Chauhan M, Vaish A (2013) Bone cement. J Clin Orthop Trauma 4(4):157–163PubMedPubMedCentralCrossRefGoogle Scholar
  46. Wehle U (1966) Occupational eczema cased by polyester. Allerg Asthma (Leipz), German, 12(2):84–6Google Scholar
  47. Wolf R, Kaul B (2000) Plastics, additives, Ullman’s encyclopedia of industrial chemistry[eBook]. Wiley-VCH, Weinheim, pp 1–89Google Scholar

Copyright information

© Springer Nature Switzerland AG 2020

Authors and Affiliations

  1. 1.Occupational MedicineFinnish Institute of Occupational HealthHelsinkiFinland

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