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Waste-Porous-Based Materials as Supports of TiO2 Photocatalytic Coatings for Environmental Applications

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Handbook of Ecomaterials

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Abstract

Porous materials obtained through recycling glass-waste or volcanic materials such as foams and amorphous perlite granules could be used as excellent inorganic supports for catalytic coatings. These materials have good water absorption capacity that makes them good supports for catalytic and photocatalytic coatings with surface roughness. In addition to hygroscopic characteristics, their low density (approximately 0.41–0.44 g cm−3) allows floating on water (lightweight materials). These recycled materials present a chemical composition that is approximately 74% SiO2, 15% Al2O3, and 11% alkaline oxides and alkaline earth oxides that provide a negligible contribution for photocatalytic or catalytic applications. Perlite is an expanded material extensively used in aqueous photocatalytic degradations of dyes and organic contaminants and gas-phase degradation of VOCs like ethylene benzene coupled with biofilters, achieving degradation in 3 h. Waste-glass foams present activity for green tide annihilation and solar degradation of dyes using natural solar irradiation. Both systems present negligible lixiviation and good mechanical stability during photocatalytic performance. In the present work, coatings were obtained by several synthesis methods such as sonochemical deposition or acid impregnation process using nanocrystalline-doped sol-gel TiO2 or commercial TiO2. The physiochemical characterizations by HRTEM, XRD, UV-vis-DRS, and Raman or FTIR spectroscopies are discussed and correlated with environmental applications to obtain a better understanding of these novel ecomaterial systems.

The practical active systems are a realistic strategy to scale up the systems to possible industrial applications and solve the emerging environmental pollution problems of industrialized cities.

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Abbreviations

4 CP:

4-Chlorophenol

AC:

Activated carbon

AO7:

Acid orange 7

BET:

Brunauer–Emmett–Teller

CTAB:

Cetyl trimethylammonium bromide

CVD:

Chemical vapor deposition

DCA:

Dichloroacetate

DRS:

Diffuse reflectance spectroscopy

EB:

Ethylbenzene

EC:

Elimination capacity

EDS:

Energy-dispersive X-ray spectroscopy

EP:

Expanded perlite

FG:

Foamed glass

FTIR:

Fourier transform infrared

FWG:

Foamed waste glass

FWGS:

Foamed waste-glass strips

GO:

Graphene oxide

HRTEM:

High-resolution transmission electron microscopy

LBD:

Loose bulk density

Nf:

Nafion

NO:

Nitric oxide

POSS:

Polyhedral oligomeric silsesquioxane

PVA:

Polyvinyl alcohol

RhB:

Rhodamine B

SEM:

Scanning electron microscopy/microscope

SMX:

Sulfamethoxazole

TiO2 :

Titanium dioxide

TMA:

Tetramethylammonium

UV:

Ultraviolet

UV-A:

Ultraviolet radiation A

WCF:

Waste ceramic foams

WG:

Waste glass

XPS:

X-ray photoelectron spectroscopy

XRD:

X-ray diffraction

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Authors and Affiliations

  1. División de Materiales Avanzados, IPICYT, Instituto Potosino de Investigación Científica y Tecnológica, San Luis Potosí, SLP, Mexico

    Vicente Rodríguez-González

  2. Facultad de Ciencias, Universidad Autónoma de San Luis Potosí, San Luis Potosí, SLP, Mexico

    Mariana Hinojosa-Reyes

Authors
  1. Vicente Rodríguez-González
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  2. Mariana Hinojosa-Reyes
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Corresponding author

Correspondence to Vicente Rodríguez-González .

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Editors and Affiliations

  1. Instituto de Ingeniería Civil, Universidad Autónoma de Nuevo León Instituto de Ingeniería Civil, San Nicolás de los Garza, Nuevo León, Mexico

    Leticia Myriam Torres Martínez

  2. Universidad Autónoma de Nuevo León , Monterrey, Mexico

    Oxana Vasilievna Kharissova

  3. Universidad Autónoma de Nuevo León , Monterrey, Mexico

    Boris Ildusovich Kharisov

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Rodríguez-González, V., Hinojosa-Reyes, M. (2018). Waste-Porous-Based Materials as Supports of TiO2 Photocatalytic Coatings for Environmental Applications. In: Martínez, L., Kharissova, O., Kharisov, B. (eds) Handbook of Ecomaterials. Springer, Cham. https://doi.org/10.1007/978-3-319-48281-1_163-1

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  • DOI: https://doi.org/10.1007/978-3-319-48281-1_163-1

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