Abstract
This chapter demonstrates the versatility and feasibility of coupled-column reversedphase liquid chromatography (LC/LC) for the rapid, selective, and sensitive determination of pesticides in environmental water samples. The work includes the setup and application of three different methods, covering the wide polarity range of pesticides as well as various LC/LC approaches and the important parameters and aspects to be considered in method development.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Hogendoorn, E. A. and van Zoonen, P. (2000) Recent and future developments of liquid chromatography in pesticide trace analysis. J. Chromatogr. A 892, 435–453.
Hogendoorn, E. A. (2000) High-performance liquid chromatographic methods in pesticide residue analysis, in Encyclopedia of Analytical Chemistry (Meyers, R. A., ed.), Wiley, Chichester, UK, pp. 6264–6299.
Hogendoorn, E. A., van Zoonen, P., and Herández, F. (2003) The versatility of coupledcolumn LC. LC-GC Europe 16, 44–51.
Dijkman, E., Mooibroek, D., Hoogerbrugge, R., et al. (2001) Study of matrix effects on the direct trace analysis of acidic pesticides in water using various liquid chromatographic modes coupled to tandem mass spectrometric detection J. Chromatogr. A 926, 113–125.
Choi, B. K., Hercules, D. M., and Gusev, A. I. (2001) Effect of liquid chromatography separation of complex matrices on liquid chromatography-tandem mass spectrometry signal suppression. J. Chromatogr. A 907, 337–342.
Pascoe, R., Foley, J. P., and Gusev, A. I. (2001) Reduction in matrix-related signal suppression effects in electrospray ionization mass spectrometry using on-line two-dimensional liquid chromatography. Anal. Chem. 73, 6014–6023.
Verhij E.R. (1993) Strategies for Compatibility Enhancement in Liquid Chromatography-Mass Spectrometry. PhD thesis, University of Leiden, Febodruk-Enschede.
Gort, S. M., Hogendoorn, E. A., Dijkman, E., van Zoonen, P., and Hoogerbrugge, R. (1996) The optimization of step-gradient elution conditions in liquid chromatography: application to pesticide residue analysis using coupled-column reversed-phase LC. Chromatographia 42, 17–24.
Hogendoorn, E. A., van Zoonen, P., Brinkman, U. A. T. (1991) Column-switching RPLC for the trace-level determination of ethylenethiourea in aqueous samples. Chromatographia 31, 285–292.
Hogendoorn, E. A. and van Zoonen, P. (1995) Coupled-column reversed-phase liquid chromatography in environmental analysis. J. Chromatogr. A 703, 149–166.
Parrilla, P., Kaim, P., Hogendoorn, E. A., and Baumann, R. A. (1999) An internal surface reversed phase column for the effective removal of humic acid interferences in the trace analysis of mecoprop in soils with coupled-column RPLC-UV. Fresenius J. Anal. Chem. 363, 77–82.
Hogendoorn, E. A., Huls, R., Dijkman, E., and Hoogerbrugge, R. (2001) Microwave assisted solvent extraction and coupled-column reversed-phase liquid chromatography with UV detection. Use of an analytical restricted-access-medium column for the efficient multi-residue analysis of acidic pesticides in soils. J. Chromatogr. A 938, 23–33.
Martínez Fernández, J., Martínez Vidal, J. L., Parrilla Vázquez, P., and Garrido Frenich, A. (2001) Application of restricted-access-media column in coupled-column RPLC with UV detection and electrospray mass spectrometry for determination of azole pesticides in urine. Chromatographia 53, 503–509.
Hogendoorn, E. A., Westhuis, K., Dijkman, E., et al. (1999) Semi-permeable surface analytical reversed-phase column for the improved trace analysis of acidic pesticides in water with coupled-column reversed-phase liquid chromatography with UV detection. Determination of bromoxynil and bentazone in surface water. J. Chromatogr. A 898, 45–54.
Hogendoorn, E. A., Dijkman, E., Baumann, R. A., Hidalgo, C., Sancho, J. V., and Hernández, F. (1999) Strategies in using analytical restricted access media columns for the removal of humic acid interferences in the trace analysis of acidic herbicides in water samples by coupled column liquid chromatography with UV detection. Anal. Chem. 71, 1111–1118.
Sancho, J. V., López, F. J., Hernández, F., Hogendoorn, E. A., and van Zoonen, P. (1994) Rapid determination of glufosinate in environmental water samples using 9-fluoronylmethoxycarbonyl precolumn derivatization, large-volume injection and coupledcolumn liquid chromatography J. Chromatogr. A 678, 59–67.
Sancho, J. V., Hidalgo, C., López, F. J, Hernández, F., Hogendoorn, E. A., and Dijkman, E. (1996) Rapid determination of glyphosate residues and its main metabolite AMPA in soil samples by liquid chromatography. Int. J. Environ. Anal. Chem. 62, 53–63.
Sancho, J. V., Hernández, F., López, F. J, Hogendoorn, E. A., Dijkman, E., and van Zoonen, P. (1996) Rapid determination of glufosinate, glyphosate and aminomethylphosphonic acid in environmental waters using precolumn fluorogenic labeling and coupled-column liquid chromatography. J. Chromatogr. A 737, 75–83.
Hogendoorn, E. A., Ossendrijver, F. M., Dijkman, E., and Baumann R. A. (1999) Rapid determination of glyphosate in cereal samples by means of pre-column derivatization with 9-fluorenylmethyl chloroformate and coupled-column liquid chromatography with fluorescence detection. J. Chromatogr. A 833, 67–73.
Hernández, F., Hidalgo, C., and Sancho, J. V. (2000) Determination of glyphosate residues in plants by precolumn derivatization and coupled-column liquid chromatography with fluorescence detection. J. AOAC Int. 83, 728–734.
Hidalgo, C., Rios, C., Hidalgo, M., Salvadó, V., Sancho, J. V., and Hernández, F. (2004) Improved coupled-column liquid chromatographic method for the determination of glyphosate and aminomethylphosphonic acid residues in environmental waters. J. Chromatogr. A 1035, 153–157.
Stalikas, C. D. and Konidari, C. N. (2001) Analytical methods to determine phosphonic and amino acid group-containing pesticides. J. Chromatogr. A 907, 1–19.
Hernández, F., Hidalgo, C., Sancho, J. V., and Lopez, F. J. (1998) Coupled-column liquid chromatography applied to the trace-level determination of triazine herbicides and some of their metabolites in water samples. Anal. Chem. 70, 3322–3328.
Martínez Vidal, J. L., Parrilla Vázquez, P., and Martínez Fernández, J. (2000) Coupled column liquid chromatography for the rapid determination of N-methylcarbamates and some of their main metabolites in water. Chromatographia 51, 187–192.
Van der Heeft, E., Dijkman, E., Baumann, R. A., and Hogendoorn, E. A. (2000) Comparison of various liquid chromatographic methods involving UV and atmospheric pressure chemical ionization mass spectrometric detection for the efficient trace analysis of phenylurea herbicides in various types of water. J. Chromatogr. A 870, 39–50.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2006 Humana Press Inc.
About this protocol
Cite this protocol
Hogendoorn, E., Dijkman, E. (2006). Coupled-Column Liquid Chromatography for the Determination of Pesticide Residues. In: Martínez Vidal, J.L., Frenich, A.G. (eds) Pesticide Protocols. Methods in Biotechnology, vol 19. Humana Press. https://doi.org/10.1385/1-59259-929-X:383
Download citation
DOI: https://doi.org/10.1385/1-59259-929-X:383
Publisher Name: Humana Press
Print ISBN: 978-1-58829-410-4
Online ISBN: 978-1-59259-929-5
eBook Packages: Springer Protocols