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Determination of Petroleum Hydrocarbon Compounds from Soils and Sediments Using Ultrasonic Extraction

  • Frédéric CoulonEmail author
  • Guozhong Wu
Protocol
Part of the Springer Protocols Handbooks book series (SPH)

Abstract

An ultrasonic extraction method for contaminated soils with petroleum hydrocarbons is presented. The method covers the determination of extractable total petroleum hydrocarbons (TPH) between nC8 and nC35 and sub-ranges of hydrocarbons including kerosene range organic (KRO) compounds (nC8–nC14), diesel range organic (DRO) compounds (nC10–nC24) and mineral oil range organic (MRO) compounds (nC22–nC34) in soils or sediments. Further modifications to the carbon banding may be made as requested for risk assessment. The aliphatic and aromatic fractions (Ali/Aro split) are separated and reported separately. This is achieved by passing the sample extract through a silica gel column and eluting the aliphatic and aromatic fractions from the column separately. These split extracts are then quantified separately by gas chromatography equipped with flame ionisation detector (GC-FID). This method may be useful as a rapid tool to determine those samples which may require further, more detailed analysis or interpretation. The method should not be used to analyse samples containing volatile hydrocarbons in the carbon band range below C8. The method can be routinely used for measuring hydrocarbons down to 10 mg kg−1 in soil. The results can be expressed either as total petroleum hydrocarbons or as a carbon range depending upon the range of hydrocarbons included in the integration. With an extraction efficiency and recovery comprise between ≥95 and 99%, this method can be easily positioned as a good alternative to Soxhlet extraction and shows a good potential for implementation as a standard method potentially providing further insight to the contaminated land sector.

Keywords:

Hydrocarbon banding Risk assessment Total petroleum hydrocarbons Ultrasonic solvent extraction 

References

  1. 1.
    Brassington KJ, Hough RL, Paton GI, Semple KT, Risdon GC, Crossley J, Hay I, Askari K, Pollard SJT (2007) Weathered hydrocarbon wastes – a risk management primer. Crit Rev Environ Sci Technol 37:199–232CrossRefGoogle Scholar
  2. 2.
    TPHCWG (1999) Total Petroleum Hydrocarbon Working Group Series Volume 5: Human health risk-based evaluation of petroleum release sites: implementing the working group approach. Amherst Scientific, Amherst, MassachusettsGoogle Scholar
  3. 3.
    Brown DG, Knightes CD, Peters CA (1999) Risk assessment for polycyclic aromatic hydrocarbon NAPLs using component fractions. Environ Sci Technol 33:4357–4363CrossRefGoogle Scholar
  4. 4.
    Risdon G, Pollard SJT, Brassington KJ, McEwan JN, Paton G, Semple K, Coulon F (2008) Development of an analytical procedure for weathered hydrocarbon contaminated soils within a UK risk-based framework. Anal Chem 80:7090–7096CrossRefPubMedGoogle Scholar
  5. 5.
    Wu G, Li X, Kechavarzi C, Sakrabani R, Sui H, Coulon F (2014) Influence and interactions of multi-factors on the bioavailability of PAHs in compost amended contaminated soils. Chemosphere 107:43–50CrossRefPubMedGoogle Scholar
  6. 6.
    Hatzinger PB, Alexander M (1997) Biodegradation of organic compounds sequestered in organic solids or in nanopores within silica particles. Environ Tox Chem 16:2215–2221CrossRefGoogle Scholar
  7. 7.
    Heyes E, Augustijn D, Rao PSC, Delfino JJ (2002) Nonaqueous phase liquid dissolution and soil organic matter sorption in porous media: review of system similarities. Crit Rev Environ Sci Technol 32:337–397CrossRefGoogle Scholar
  8. 8.
    Wu G, Kechavarzi C, Li X, Sui H, Pollard SJT, Coulon F (2012) Influence of mature compost amendment on total and bioavailable polycyclic aromatic hydrocarbons in contaminated soils. Chemosphere 90:2240–2246CrossRefPubMedGoogle Scholar
  9. 9.
    Coulon F, Whelan MJ, Paton GI, Semple KT, Villa R, Pollard SJT (2010) Multimedia fate of total petroleum hydrocarbon fractions in the soil:oil matrix of constructed biopiles. Chemosphere 81:1454–1462CrossRefPubMedGoogle Scholar
  10. 10.
    Towell MG, Bellarby J, Paton GI, Coulon F, Pollard SJT, Semple KT (2011) Mineralisation of target hydrocarbons in three contaminated soils from former refinery facilities. Environ Pollut 159:515–523CrossRefPubMedGoogle Scholar
  11. 11.
    Coulon F, Brassington KJ, Bazin R, Linnet PE, Thomas KA, Mitchell TR, Lethbridge G, Smith JWN, Pollard SJT (2012) Effect of fertiliser formulation and bioaugmentation on biodegradation and leaching of crude oils and refined products in soils. Environ Technol 33:1879–1893CrossRefPubMedGoogle Scholar
  12. 12.
    Nathanail CP, McCaffrey C, Ashmore M, Cheng Y, Gillet A, Hooker P, Ogden RC (2007) Generic assessment criteria for human health risk assessment. Land Quality Press, Nottingham. ISBN ISN 0-9547474-3-7Google Scholar
  13. 13.
    Foster KL, Mackay D, Parkerton TF, Webster E, Milford L (2005) Five-stage environmental exposure assessment strategy for mixtures: gasoline as a case study. Environ Sci Technol 39:2711–2718CrossRefPubMedGoogle Scholar
  14. 14.
    USEPA (1996) Ultrasonic extraction, Organic extraction and sample preparation Method 3550B U.S. EPA, Washington, DCGoogle Scholar
  15. 15.
    USEPA (2007) Ultrasonic extraction, Organic extraction and sample preparation Method 3550C, revision 3, Feb 2007, U.S. EPA, Washington, DCGoogle Scholar
  16. 16.
    Texas Natural Resource Conservation Commission (TNRRC) (2000) Regulatory guidance development of human health PCLs for total petroleum hydrocarbon mixtures. RG-366/TRRP, June 2000. http://www.cirrusassociates.com/TRRP/TRRP27.pdf, p 21
  17. 17.
    Wang Z, Fingas M (2003) Development of oil hydrocarbon fingerprinting and identification techniques. Mar Pollut Bull 47:423–452CrossRefPubMedGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  1. 1.Department of Environmental Science and TechnologySchool of Applied Science, Cranfield UniversityCranfieldUK
  2. 2.Division of Ocean Science and TechnologyGraduate School at Shenzhen, Tsinghua UniversityShenzhenChina

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