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Kinetics and mechanism of gallium discharge and ionization in an alkaline solution of potassium fluoride

  • Applied Electrochemistry and Corrosion Protection of Metals
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Abstract

Mechanism of gallium discharge and ionization on a liquid gallium electrode in a fluoride-alkaline electrolyte was studied. The exchange currents, transfer coefficients in the cathodic and anodic processes, and the activation energy of the electrode process were determined. The conditions in which gallium(I) ion-intermediates are formed were analyzed. The coordination numbers of the gallium complexes formed in alkaline fluoride solutions were calculated.

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Authors and Affiliations

  1. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    L. F. Kozin & A. V. Gaidin

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  1. L. F. Kozin
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  2. A. V. Gaidin
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Original Russian Text © L.F. Kozin, A.V. Gaidin, 2009, published in Zhurnal Prikladnoi Khimii, 2009, vol. 82, No. 3, pp. 414–423.

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Kozin, L.F., Gaidin, A.V. Kinetics and mechanism of gallium discharge and ionization in an alkaline solution of potassium fluoride. Russ J Appl Chem 82, 406–415 (2009). https://doi.org/10.1134/S1070427209030124

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  • DOI: https://doi.org/10.1134/S1070427209030124

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