Abstract
Results of research on the development of platinum-free cathode PdM (M = Co or Fe) and anode catalysts PdM (M = Ru, Mo, Au) and RuM (M = Co, Ni, Fe), deposited onto disperse carbon material, are presented. The developed catalysts are shown to be practically feasible for membrane electrode assemblies for low-temperature hydrogen-air and ethanol-air fuel cells. A platinum-free alkaline ethanol-air fuel cell is first developed.
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Original Russian Text © A.Yu. Tsivadze, M.R. Tarasevich, V.N. Andreev, V.A. Bogdanovskaya, 2007, published in Russkii Khimicheskii Zhurnal, 2007, Vol. 50, No. 6, pp. 109–114.
Aslan Yusupovich Tsivadze, Academician, Director, Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IPCE RAS). Scientific areas of focus: coordination and supramolecular chemistry, extraction separation of isotopes.
Mikhail Romanovich Tarasevich, Dr. Sc. (Chem.), Professor, Head of Laboratory of Electrocatalysis and Fuel Cells, IPCE RAS. Scientific areas of focus: electrocatalysis, bioelectrocatalysis, fuel cells.
Vladimir Nikolaevich Andreev, Dr. Sc. (Chem.), Head of Laboratory of Interfaces and Electrocayalysis, IPCE RAS. Scientific areas of focus: structure of interfaces, electrocatalysis, composite polymeric membranes, fuel cells.
Vera Aleksandrovna Bogdanovskaya, Cand. Sc. ((Chem.), Leading Researcher, IPCE RAS. Scientific areas of focus: electrocatalysis, bioelectrocatalysis, fuel cells.
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Tsivadze, A.Y., Tarasevich, M.R., Andreev, V.N. et al. Prospects of low-temperature platinum-free fuel cells. Russ J Gen Chem 77, 783–789 (2007). https://doi.org/10.1134/S1070363207040391
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DOI: https://doi.org/10.1134/S1070363207040391