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Synthesis, crystal structure, and catalytic property of oxovanadium(V) complex derived from N′-(2-hydroxynaphthylidene)-4-chlorobenzohydrazide and 1,10-phenanthroline

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Abstract

A new oxovanadium(V) complex, [VO(L)(Phen)], where L is the dianionic form of N′-(2-hydroxynaphthylidene)-4-chlorobenzohydrazide, Phen is 1,10-phenanthroline, has been synthesized and characterized by elemental analysis, FT-IR spectra, and single crystal X-ray determination. The crystal of the complex is monoclinic: space group P21/c, a = 11.2376(8), b = 13.3068(10), c = 17.5593(11) Å, β = 106.806(2)°, V = 2513.6(3) Å3, Z = 4. The V atom in the complex is in octahedral coordination, with the phenolate O, imine N, and enolate O atoms of L and one N atom of Phen define the equatorial plane, and with the other N atom of Phen and one oxo O atom located at the axial positions. The complex is a good catalyst for the oxidation of thioanisole to the corresponding sulfoxide by cumene hydroperoxide.

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References

  1. Li, X., Lah, M.S., and Pecoraro, V.L., Inorg. Chem., 1988, vol. 27, no. 25, p. 4657.

    Article  CAS  Google Scholar 

  2. Monga, V., Thompson, K.H., Yuen, V.G., et al., Inorg. Chem., 2005, vol. 44, no. 8, p. 2678.

    Article  CAS  Google Scholar 

  3. Rio, D., del Galindo, A., Tejedo, J., et al., Inorg. Chem. Commun., 2000, vol. 3, no. 1, p. 32.

    Article  Google Scholar 

  4. Grüning, C., Schmidt, H., and Rehder, D., Inorg. Chem. Commun., 1999, vol. 2, no. 1, p. 57.

    Article  Google Scholar 

  5. Grivani, G., Tahmasebi, V., Khalaji, A.D., et al., Polyhedron, 2013, vol. 51, p. 54.

    Article  CAS  Google Scholar 

  6. Orive, J., Larrea, E.S., de Luis, R.F., et al., Dalton Trans., 2013, vol. 42, no. 13, p. 4500.

    Article  CAS  Google Scholar 

  7. Kurmaev, D.A., Kolosov, N.A., Gagieva, S.C., et al., Inorg. Chim. Acta, 2013, vol. 396, p. 136.

    Article  CAS  Google Scholar 

  8. Alagesan, M., Bhuvanesh, N.S.P., and Dharmaraj, N., Dalton Trans., 2013, vol. 42, no. 19, p. 7210.

    Article  CAS  Google Scholar 

  9. Altintop, M.D., Ozdemir, A., Turan-Zitouni, G., et al., Eur. J. Med. Chem., 2012, vol. 58, p. 299.

    Article  CAS  Google Scholar 

  10. Hegazy, W.H. and Al-Motawaa, I.H., Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2011, vol. 41, no. 9, p. 1172.

    Article  CAS  Google Scholar 

  11. Maurya, M.R., Agarwal, S., Bader, C., et al., Dalton Trans., 2005, no. 3, p. 537.

    Google Scholar 

  12. Monfared, H.H., Bikas, R., and Mayer, P., Inorg. Chim. Acta, 2010, vol. 363, no. 11, p. 2574.

    Article  CAS  Google Scholar 

  13. Kwiatkowski, E., Romanowski, G., Nowicki, W., et al., Polyhedron, 2003, vol. 22, no. 7, p. 1009.

    Article  CAS  Google Scholar 

  14. SMART and SAINT, Area Detector Control and Integration Software, Madison (WI, USA): Bruker Analytical X-ray Instruments Inc., 1997.

  15. Sheldrick, G.M., SADABS, Program for Empirical Absorption Correction of Area Detector Data, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  16. North, A.C.T., Phillips, D.C., and Mathews, F.S., Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr., 1968, vol. 24, no. 3, p. 351.

    Article  Google Scholar 

  17. Sheldrick, G.M., SHELXL-97, Program for the Refinement of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  18. Sarkar, A. and Pal, S., Inorg. Chim. Acta, 2008, vol. 361, no. 8, p. 2296.

    Article  CAS  Google Scholar 

  19. Monfared, H.H., Alavi, S., Bikas, R., et al., Polyhedron, 2010, vol. 29, no. 18, p. 3355.

    Article  CAS  Google Scholar 

  20. Sarkar, A. and Pal, S., Polyhedron, 2007, vol. 26, no. 6, p. 1205.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan, Henan, 467000, P.R. China

    Y. X. Feng & L. W. Xue

  2. Coal Chemical Industry Branch of Shenhua Ningxia Coal Group, Yinchuan, Ningxia, 750411, P.R. China

    C. X. Zhang

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  1. Y. X. Feng
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  2. L. W. Xue
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  3. C. X. Zhang
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Correspondence to L. W. Xue.

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Feng, Y.X., Xue, L.W. & Zhang, C.X. Synthesis, crystal structure, and catalytic property of oxovanadium(V) complex derived from N′-(2-hydroxynaphthylidene)-4-chlorobenzohydrazide and 1,10-phenanthroline. Russ J Coord Chem 40, 337–341 (2014). https://doi.org/10.1134/S1070328414050030

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  • DOI: https://doi.org/10.1134/S1070328414050030

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